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101.
Lu Y Beeman RW Campbell JF Park Y Aikins MJ Mori K Akasaka K Tamogami S Phillips TW 《Die Naturwissenschaften》2011,98(9):755-761
We report that the abdominal epidermis and associated tissues are the predominant sources of male-produced pheromones in the
red flour beetle, Tribolium castaneum and, for the first time, describe the stereoisomeric composition of the natural blend of isomers of the aggregation pheromone
4,8-dimethyldecanal (DMD) in this important pest species. Quantitative analyses via gas chromatography–mass spectrometry showed
that the average amount of DMD released daily by single feeding males of T. castaneum was 878 ± 72 ng (SE). Analysis of different body parts identified the abdominal epidermis as the major source of aggregation
pheromone; the thorax was a minor source, while no DMD was detectable in the head. No internal organs or obvious male-specific
glands were associated with pheromone deposition. Complete separation of all four stereoisomers of DMD was achieved following
oxidation to the corresponding acid, derivatization with (1R, 2R)- and (1S, 2S)-2-(anthracene-2,3-dicarboximido)cyclohexanol to diastereomeric esters, and their separation on reversed-phase high-performance
liquid chromatography at −54°C. Analysis of the hexane eluate from Porapak-Q-collected volatiles from feeding males revealed
the presence of all four isomers (4R,8R)/(4R,8S)/(4S,8R)/(4S,8S) at a ratio of approximately 4:4:1:1. A walking orientation bioassay in a wind tunnel with various blends of the four synthetic
isomers further indicated that the attractive potency of the reconstituted natural blend of 4:4:1:1 was equivalent to that
of the natural pheromone and greater than that of the 1:1 blend of (4R,8R)/(4R,8S) used in commercial lures. 相似文献
102.
A postanal tail is a major synapomorphy of the phylum Chordata, which is composed of three subphyla: Vertebrata, Cephalochordata,
and Tunicata (Urochordata). Among tunicates, appendicularians are the only group that retains the tail in the adult, and the
adult tail functions in locomotion and feeding in combination with a cellulose-based house structure. Given the phylogenetic
position of tunicates, the appendicularian adult tail may possess ancestral features of the chordate tail. We assess the ultrastructural
development of the tail epidermis of the appendicularian Oikopleura dioica. The epidermis of the larval tail is enclosed by the larval envelope, which is a thin sheet similar to the outer tunic layer
of ascidian larvae. The epidermis of the adult tail seems to bear no tunic-like cellulosic integuments, and the tail fin is
a simple folding of the epidermis. Every epidermal cell, except for the triangular cells at the edge of the tail fin, has
a conspicuous matrix layer of fibrous content in the apical cytoplasm without enclosing membranes. The epidermis of the larval
tail does not have a fibrous matrix layer, suggesting the production of the layer during larval development and metamorphosis.
Zonulae adhaerentes firmly bind the epidermal cells of the adult tail to one another, and the dense microfilaments lining
the cell borders constitute a mechanical support for the cell membranes. The intracellular matrix, cell junctions, and cytoskeletons
probably make the tail epidermis a tough, flexible shell supporting the active beating of the oikopleuran adult tail. 相似文献
103.
A recent fieldwork in the Ka??zman-Tuzluca Basin in northeastern Turkey led us to the discovery of three vertebrate localities which yielded some limb bones of the giant rhino Paraceratherium, a crocodile tooth, and some small mammals, respectively. These discoveries allowed, for the first time to date some parts of the sedimentary units of this basin. This study also shows that the dispersal area of Paraceratherium is wider than it was known before. Eastern Turkey has several Cenozoic sedimentary basins formed during the collision of the Arabian and Eurasian plates. They are poorly documented for vertebrate paleontology. Consequently, the timing of tectonic activities, which led to the formation of the East Anatolian accretionary complex, is not constrained enough with a solid chronological framework. This study provides the first biostratigraphic evidences for the infill under the control of the compressive tectonic regime, which built the East Anatolian Plateau. 相似文献
104.
为了解北京城区大气干沉降中水溶性离子的化学组成与时间变化特征,连续进行了4年多的干沉降采样与分析.结果表明,在222个有效干沉降样品中,存在不同程度的阴离子缺失. SO42-与Ca2+分别是含量最丰富的阴、阳离子组分,其次是NO3-和NH4+. SO42-、NO3-和NH4+呈现相似的季节变化特征,即其浓度在夏季最高,冬季最低. 干沉降基本呈中性,其pH值月变化幅度小,但季节变化明显,夏季低而春季高. 相似文献
105.
In this work we present the results of a 2-year survey of indoor radon variations in four cities of Lahijan, Ardabil, Sar-Ein and Namin in North and Northwest Iran. We used both passive and active measurements by solid state nuclear track detectors (SSNTDs) with CR-39 polycarbonate and PRASSI Portable radon Gas Surveyor. A total of 1124 samplers in Lahijan, Ardabil, Sar-Ein and Namin were installed. Sampling frequency was seasonal and sampling locations were randomly chosen based on dwelling structures, floors, geological formations, elevation and temperature variation parameters. For quality assurance, 281 active measurements and double sampling were carried out. Based on our results and the results of previous surveys, Ardabil and Lahijan have the second and third highest radon concentration in Iran, respectively (Ramsar is first). The average radon concentration during the year in Lahijan, Ardabil, Sar-Ein and Namin were 163, 240, 160 and 144 Bq/m(3) with medians of 160, 168, 124 and 133 Bq/m(3), respectively. These concentrations give rise to annual effective doses of 3.43 mSv/y for Lahijan and 5.00 mSv/y for Ardabil. The maximum recorded concentration was 2386 Bq/m(3) during winter in Ardabil and the minimum concentration was 55 Bq/m(3) during spring in Lahijan. Relationships between radon concentration and building materials and room ventilation were also studied. The dosimetry calculations showed that these four cities could be categorized as average natural radiation zones. The correlation coefficients relating warm and cold season radon variation data were obtained. 相似文献
106.
Humic substances (HS) and natural organic matter (NOM) are natural organic compounds ubiquitous in the environment. However, some studies indicate that both HS and NOM can act as xenobiotics, e.g. induce hormone-like effects in fish, amphibians and invertebrates. Molecules of these substances contain a number of aromatic rings and conjugated double bonds--the so called chromophores. Irradiation of dissolved HS and NOM can lead to a series of photochemical reactions which can act on these substances itself, or on other substances present in aquatic environment along with HS and NOM such as e.g. xenobiotics. In our previous study, we have found significant interactions of five humic acids (HA) with cytosolic aryl hydrocarbon receptor (AhR) in an in vitro bioassay based on H4IIE-luc cells. In the present study, we have studied the changes in AhR-mediated activities both of HS and NOM after irradiation that simulated natural solar light. Nine different HS and two NOM samples were irradiated in Pyrex tubes with a medium-pressure mercury lamp for a duration of 0 to 52 h (which corresponds to 0-52 d natural solar radiation). Original concentrations of the samples were 50 mg L(-1), and the greatest concentration of HS and NOM photoproducts subsequently tested in the bioassay was 17 mg L(-1), which is an environmentally relevant concentration. After irradiation the absorbances of all the samples were less than the original materials. The AhR-mediated activity of the HA-Fluka and HA Sodium Salt were partially decreased by irradiation. The activities of other HS and NOM, that were either AhR-active or -inactive were not changed by irradiation. The results of the study demonstrate that AhR-mediated activities of two active HA is caused by both photo-stable and photo-labile AhR activators, while the other three active HA contain only photo-stable AhR activators. Potential mechanisms of the observed irradiation-induced changes in AhR-mediated activities are discussed. 相似文献
107.
El Samad O Zahraman K Baydoun R Nasreddine M 《Journal of environmental radioactivity》2007,92(2):72-79
Fallout from the Chernobyl reactor accident due to the transport of a radioactive cloud over Lebanon in the beginning of May 1986 was studied 12 years after the accident for determining the level of (137)Cs concentration in soil. Gamma spectroscopy measurements were performed by using coaxial high sensitivity HPGe detectors. More than 90 soil samples were collected from points uniformly distributed throughout the land of Lebanon in order to evaluate their radioactivity. The data obtained showed a relatively high (137)Cs activity per surface area contamination, up to 6545Bqm(-2) in the top soil layer 0-3cm. The average activity of (137)Cs in the top soil layer 0-3cm in depth was 59.7Bqkg(-1) dry soil ranging from 15 to 119Bqkg(-1) dry soil. The horizontal variability was found to be about 45% between the sampling sites. The depth distribution of total (137)Cs activity in soil showed an exponential decrease. Estimation of the annual effective dose due to external radiation from (137)Cs contaminated soil for selected sites gave values ranging from 19.3 to 91.6 micro Svy(-1). 相似文献
108.
Meeta Lavani Priyangshu M. Sarm Ajoy K. Man Simrita Cheem Banwari La 《环境科学学报(英文版)》2011,23(8):1394-1402
We compared the efficacy of a natural biocide with four chemical tetrakishydroxymethyl phosphonium sulfonate, benzyl trimethyl
ammonium chloride, and formaldehyde, glutaraldehyde, to control microbial induced corrosion in oil pipelines. The efficacy of biocides
were monitored against Desulfovibrio vulgaris and Desulfovibrio gigas in experimental pipes by measuring cell counts, H2S production,
Fe(II) production, production of extracellular polymeric substances and structure of biofilm. The treatment with cow urine had minimum
planktonic cell counts of 3 102 CFU/mL as well as biofilm cell counts of 9 101 CFU/mL as compared with tetrakishydroxyl methyl
phosphonium sulfonate, benzyl trimethyl ammonium chloride, formaldehyde and glutaraldehyde. Sulfide production was the lowest
with cow urine (0.08 mmol/L), followed by tetrakishydroxymethyl phosphonium sulfonate 0.72 mmol/L. On day 90 of treatment,
Fe(II) production was also found to be the lowest with cow urine. The scanning electron microscopic studies indicated that the biofilm
bacteria were killed by cow urine. These results demonstrate the cow urine mediated control of microbially induced corrosion, and this
is indicative of its potential as a viable substitute of toxic biocides. To the best of our knowledge, this seems to be the first report which
screens possible biocidal activity by cow urine as compared to the most common biocides which oil industry is currently using. 相似文献
109.
110.
Aim of the present study was to synthesize titanium dioxide nanoparticles (YiO2 NPs) from marine actinobacteria and to develop an eco-friendly azo-dye degradation method. A total of five actinobacterial isolates were isolated from Chennai marine sediments, Tamilnadu, India and analyzed for the synthesis of TiO2 NPs using titanium hydroxide. Among these, the isolate PSV 3 showed positive results for the synthesis of TiO2 NPs, which was confirmed by UV analysis. Further characterization of the synthesized TiO2 NPs was done using XRD, AFM and FI'-IR analysis. Actinobacterial crude extract and synthesized TiO2 NPs was found efficient in degrading azo dye such as Acid Red 79 (AR-79) and Acid Red 80 (AR-80). Degradation percentage was found to be 81% for AR-79, 83% for AR-80 using actinobacterial crude extract and 84% for AR-79, 85% for AR-80 using TiO2 NPs. Immobilized actinobacterial ceils showed 88% for AR-79 and 81% for AR- 80, dye degrading capacity. Degraded components were characterized by FT-IR and GC-MS analysis. The phytotoxicity test with 500 μg/mL of untreated dye showed remarkable phenotypic as well as cellular damage to Tagetes erecta plant. Comparatively no such damage was observed on plants by degraded dye components. In biotoxicity assay, treated dyes showed less toxic effect as compared to the untreated dyes. 相似文献