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881.
Common shrimp, Crangon crangon (L.), were exposed to inorganic arsenic (arsenate), trimethylarsine oxide, or arsenobetaine in sea water (100 μg As l−1) or in food (1 mg As g−1 wet wt) for up to 24 d, followed by 16 d depuration in clean sea water with undosed food, in order to determine the efficiency
of uptake and retention of the compounds. Accumulation of arsenic in the tail muscle, gills, midgut gland, exoskeleton, and
remaining tissues was found to depend on the chemical form of the arsenic and the route of exposure. No arsenic was accumulated
by C. crangon exposed to arsenate or trimethylarsine oxide in sea water. Shrimps exposed to waterborne arsenobetaine initially accumulated
a small amount of arsenic in their tail muscle and gills. After 16 d, C. crangon fed arsenate, trimethylarsine oxide, or arsenobetaine had accumulated arsenic in their tail muscle to levels ∼2-, 2-, or
40-times, respectively, that of the control group. A roughly linear rate of accumulation was shown by shrimps fed trimethylarsine
oxide or arsenobetaine, but C. crangon fed arsenate accumulated arsenic for 16 d, then lost arsenic such that their concentration on Day 24 was not significantly
different from that of the control group. Patterns of arsenic accumulation in the gills of shrimps fed the compounds were
similar to those seen in the tail muscle. On a whole animal basis, C. crangon retained ∼1.2% of the arsenate, 1.6% of the trimethylarsine oxide, and 42% of the arsenobetaine consumed over the first 16 d
of exposure, with roughly half present in the tail muscle in each case. Data obtained support the view that the direct uptake
of arsenobetaine from sea water does not make a significant contribution to the relatively high concentrations of this compound
in marine crustaceans, and that food is the primary source. Naturally occurring arsenic compounds in C. crangon and possible transformations of the administered arsenic compounds were examined by high performance liquid chromatography
using an inductively coupled plasma mass spectrometer as the arsenic-specific detector. Control C. crangon contained arsenobetaine as the major arsenic compound (>95% of total arsenic); tetramethylarsonium ion (0.7%) and an unknown
arsenic compound (1.7%) were also present as minor constituents. Shrimp ingesting arsenobetaine accumulated it unchanged.
Shrimp ingesting arsenate did not form methylated arsenic compounds; they appeared to contain their accumulated arsenic as
unchanged arsenate only, although the possibility that some of the arsenic was reduced to arsenite could not be excluded.
C. crangon ingesting trimethylarsine oxide biotransformed the compound predominantly to dimethylarsinate.
Received: 9 October 1997 / Accepted: 11 February 1998 相似文献
882.
Binding affinity of metanil yellow and its breakdown product p‐aminodiphenylamine to serum proteins has been studied employing chromatographic separation on Sephadex G‐200 and by paper and polyacrylamide gel electrophoresis. Metanil yellow has more affinity towards albumin than to globulins. The complexing is presumably through electrostatic forces. p‐Aminodiphenylamine on the other hand, preferably binds to globulin fractions of serum protein. However, a stable binding with BSA alone was also observed. The binding was quite stable and was accompanied by a shift in absorbance from 430 nm to 500 nm. Aspartic acid moiety of protein was found to be one of the units involved in the binding of p‐ADPA to proteins. 相似文献
883.
Rose N. L. Shilland E. Yang H. Berg T. Camarero L. Harriman R. Koinig K. Lien L. Nickus U. Stuchlík E. Thies H. Ventura M. 《Water, Air, & Soil Pollution: Focus》2002,2(2):251-260
Spheroidal carbonaceous particles(SCPs) are produced only from high temperaturecombustion of fossil-fuels. In mountain lakesystems, they provide an unambiguous indicator ofatmospheric deposition. In order to comparedepositional fluxes of SCPs between mountainareas experiencing various pollutant regimes,intensive bulk deposition sampling was undertakenat five sites across Europe. Catchment soil coresand lake sediment cores were also taken at eachsite to compare SCP storage over the post-industrial period. Atmospheric, sediment and soilSCP data showed similar patterns. Highestcontamination was found in Scotland, Slovakia andSpain with the Austrian site intermediate and themid-Norwegian site least contaminated. A highproportion of accumulated SCPs were found to bestored in catchment soils at each site.Therefore, a significant increase in soilerosion, possibly as a result of future climatechange, could lead to the input of largequantities of catchment stored SCPs and, byimplication, other atmospherically depositedcontaminants to the lake ecosystem. 相似文献
884.
E. Blondeel M. Chys V. Depuydt K. Folens G. Du laing A. Verliefde S.W.H. Van Hulle 《Waste management (New York, N.Y.)》2014,34(12):2674-2686
Scrap material recovery and recycling companies are confronted with waste water that has a highly fluctuating flow rate and composition. Common pollutants, such as COD, nutrients and suspended solids, potentially toxic metals, polyaromatic hydrocarbons and poly chlorinated biphenyls can exceed the discharge limits. An analysis of the leaching behaviour of different scrap materials and scrap yard sweepings was performed at full-scale, pilot-scale and lab-scale in order to find possible preventive solutions for this waste water problem. The results of these leaching tests (with concentrations that frequently exceeded the Flemish discharge limits) showed the importance of regular sweeping campaigns at the company, leak proof or covered storage of specific scrap materials and oil/water separation on particular leachates. The particulate versus dissolved fraction was also studied for the pollutants. For example, up to 98% of the polyaromatic hydrocarbons, poly chlorinated biphenyls and some metals were in the particulate form. This confirms the (potential) applicability of sedimentation and filtration techniques for the treatment of the majority of the leachates, and as such the rainwater run-off as a whole. 相似文献
885.
Ivan S. Ristić Ljiljana Tanasić Ljubiša B. Nikolić Suzana M. Cakić Olivera Z. Ilić Radmila Ž. Radičević Jaroslava K. Budinski-Simendić 《Journal of Polymers and the Environment》2011,19(2):419-430
Different synthesis methods were applied to determine optimal conditions for polymerization of (3S)-cis-3,6-dimethyl-1,4-dioxane-2,5-dione (l-lactide), in order to obtain poly(l-lactide) (PLLA). Bulk polymerizations (in vacuum sealed vessel, high pressure reactor and in microwave field) were performed
with tin(II) 2-ethylhexanoate as the initiator. Synthesis in the vacuum sealed vessel was carried out at the temperature of
150 °C. To reduce the reaction time second polymerization process was carried out in the high pressure reactor at 100 °C and
at the pressure of 138 kPa. The third type of rapid synthesis was done in the microwave reactor at 100 °C, using frequency
of 2.45 GHz and power of 150 W at the temperature of 100 °C. The temperature in this method was controlled via infrared system
for in-bulk measuring. The solution polymerization (with trifluoromethanesulfonic acid as initiator) was possible even at
the temperature of 40 °C, yielding PLLA with narrow molecular weight distribution in a very short period of time (less than
6 h). The obtained polymers had the number-average molecular weights ranging from 43,000 to 178,000 g mol−1 (polydispersity index ranging from 1 to 3) according to the gel permeation chromatography measurements. The polymer structure
was characterized by Fourier transform infrared and NMR spectroscopy. Thermal properties of the obtained polymers were investigated
using thermogravimetry and differential scanning calorimetry. 相似文献
886.
Charles M. Farmer Author Vitae JoAnn K. Wells Author Vitae 《Journal of Safety Research》2010,41(1):53-57
Objective
Enhanced seat belt reminders in automobiles have been shown to increase belt use rates by approximately 3 percentage points. The objective of this study was to estimate the effect of enhanced seat belt reminders on driver fatality risk.Method
Data included all passenger vehicle driver deaths and vehicle registration counts in the United States for calendar years 2000-2007. Driver fatality rates per vehicle registration per year were compared for otherwise identical vehicle models with and without enhanced seat belt reminders.Results
Driver fatality rates were 6% lower for vehicles with enhanced seat belt reminders compared with vehicles without enhanced belt reminders. After adjusting for vehicle age differences, the estimated effect of enhanced belt reminders on driver fatality risk ranged from a 9% reduction for General Motors vehicles to a 2% increase for Honda vehicles. Combining all manufacturers, enhanced belt reminders reduced fatality risk by approximately 2%. Although not statistically significant, the 2% reduction in fatality risk agrees with what should be expected from a 3 percentage point increase in seat belt use rates.Conclusions
Enhanced seat belt reminders have raised driver belt use rates and reduced fatality rates, but more aggressive systems may be needed for some drivers. It can be inferred that nonfatal injury rates also have been reduced.Impact on Industry
Manufacturers should be encouraged to put enhanced seat belt reminders on all vehicles as soon as possible. 相似文献887.
Minimizing atmospheric emissions of soil fumigants is critical for protecting human and environmental health. Covering the soil surface with a plastic tarp is a common approach to restrict fumigant emissions. The mass transfer of the fumigant vapors through the tarp is often the rate-limiting factor in fumigant emissions. An approach for standardizing measurements of film permeability is proposed that is based on determining the resistance (R) of films to diffusion of fumigants. Using this approach, values were determined for more than 200 film-chemical combinations under a range of temperature, relative humidity, and film handling conditions. Resistance to diffusion was specific for each fumigant/film combination, with the largest range of values observed for the fumigant chloropicrin. For each fumigant, decreased with increasing temperature. Changes in film permeability due to increases in temperature or field installation were generally less than a factor of five. For one film, values determined under conditions of very high relative humidity (approximately 100%) were at least 100 times lower than when humidity was very low (approximately 2%). This approach simplifies the selection of appropriate films for soil fumigation by providing rapid, reproducible, and precise measurements of their permeability to specific fumigants and application conditions. 相似文献
888.
K. G. Willis Malcolm Newson Sonja Boehmer‐Christiansen 《Journal of Environmental Planning and Management》1994,37(2):243-247
Cost Benefit Analysis of Environmental Change
Per‐Olov Johansson
Cambridge, Cambridge University Press, 1993, 232 pp., £13.95
Computerised Environmental Modelling: A Practical Introduction using Excel
J. Hardisty, D. M. Taylor & S. E. Metcalfe
Chichester, Wiley, 1993, 204 pp., £14.95
Keeping Pace with Science and Engineering: Case Studies in Environmental Regulation
Washington DC, US National Academy of Engineering, 1993
World Without End: Economics, Environment and Sustainable Development
D. W. Pearce & J. J. Warford
Oxford University Press, New York, 1993, 440 pp., £35.95 相似文献
889.
890.