Biotreatment of chromite ore processing residue by Pannonibacter phragmitetus BB

Chromite ore processing residues (COPR) is the source of the Cr(VI) contamination in the environment. Pannonibacter phragmitetus BB was used to treat two different types of COPRs in this research. The water-soluble Cr(VI) of COPR A and B is 3,982.9 and 1,181.4 mg/kg, respectively. In the column biotreatment process, P. phragmitetus BB can reduce Cr(VI) in the leachate to an undetectable level at the flow rate of 1 and 2 ml/min. In the direct biotreatment process, Cr(VI) in the liquid supernatant of COPR A and B decreased from 265 and 200 mg/l to 145 and 40 mg/kg after 240 h of incubation. In one-step and two-step biotreatment processes, Cr(VI) in the liquid supernatant of both COPRs can be reduced to an undetectable level. The toxicity characteristic leaching procedure results indicate that the Cr(VI) concentration of treated COPR A (3.48 mg/l) is lower than the identification standards for hazardous wastes of China (5 mg/l) (GB 5085.6-2007). The information obtained in this study has significance for the application of P. phragmitetus BB to remediate COPR contamination.     

发展循环经济、提高矿山生产的资源利用率——以伊犁阿希金矿为例

开展循环经济不仅是现代企业追求永续发展的必由之路,也是实现社会、经济和环境协调发展的必然选择。以新疆阿希金矿为例,对企业以追求更大的经济效益、更少的资源消耗、更低的环境污染为经济发展模式,确保企业的可持续发展。     

北京蟹岛集团发展循环经济调查

通过对民营企业北京蟹岛集团的实地调查,对其以“低消耗、低排放、低污染、高效益”为经营方针,以“生态、环保、可持续”为经营理念,成功实现“资源－消费－再利用”的循环经济增长模式进行详细介绍。并通过蟹岛集团自身的发展证明：循环经济不仅可以改变传统“资源－效益—废弃物”的线性增长模式,还可以促进企业的发展,为企业带来可观的经济效益。     

气相色谱法测定废水和废气中N′,N-二甲基甲酰胺

以气相色谱石英毛细管柱分离、ＦＩＤ检测,测定废水和废气中Ｎ′,Ｎ－二甲基甲酰胺（ＤＭＦ）。在１０ｍｇ／Ｌ～１８８１０ｍｇ／Ｌ范围内有良好的线性关系。检测限：废水为０５ｍｇ／Ｌ;废气为０８ｍｇ／ｍ３。样品测定的相对标准差为４％～８％,回收率在７６％～１１２％之间,精密度和准确度均较好     

成都市土壤天然放射性核素的外照射水平估算研究

利用IED22000A便携式微机多道能谱仪对成都市区土壤的天然放射性核素进行了直接就地测量,估算出天然环境放射性核素^238U、^232Th、^40K的比活度范围分别为10.37～77．19Bq／kg、17,85～225．74Bq／kg、284．83～892．67Bq／kg;外照射指数范围为0．16—0．8;离地面1m高的空气吸收剂量率均值为83．23nGy／h;1外照射年有效剂量当量为0．34～0．70mSv;等效镭浓度的变化范围是59．06-386．45Bq／kg,均值为164．15Bq／kg。各项指标均在容许范围之内,因而成都市属于外照射水平的安全区域,人居环境不受影响。     

Exploring the relationship between vegetation spectra and eco-geo-environmental conditions in karst region, Southwest China

Remote sensing of local environmental conditions is not accessible if substrates are covered with vegetation. This study explored the relationship between vegetation spectra and karst eco-geo-environmental conditions. Hyperspectral remote sensing techniques showed that there were significant differences between spectral features of vegetation mainly distributed in karst and non-karst regions, and combination of 1,300- to 2,500-nm reflectance and 400- to 680-nm first-derivative spectra could delineate karst and non-karst vegetation groups. Canonical correspondence analysis (CCA) successfully assessed to what extent the variation of vegetation spectral features can be explained by associated eco-geo-environmental variables, and it was found that soil moisture and calcium carbonate contents had the most significant effects on vegetation spectral features in karst region. Our study indicates that vegetation spectra is tightly linked to eco-geo-environmental conditions and CCA is an effective means of studying the relationship between vegetation spectral features and eco-geo-environmental variables. Employing a combination of spectral and spatial analysis, it is anticipated that hyperspectral imagery can be used in interpreting or mapping eco-geo-environmental conditions covered with vegetation in karst region.     

Risk assessment of heavy metals in road and soil dusts within PM2.5, PM10 and PM100 fractions in Dongying city, Shandong Province, China

15 road and 14 soil dust samples were collected from an oilfield city, Dongying, from 11/2009-4/2010 and analyzed by inductively coupled plasma-mass spectroscopy (ICP-MS) for V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb within PM(2.5), PM(10) and PM(100) fractions synchronously. Metal concentrations, sources and human health risk were studied. Results showed that both soil and road dust exhibited higher values for Mn and Zn and lower values for Co and Cd for the three fractions. Mass concentration ratios of PM(2.5)/PM(10) and PM(10)/PM(100) for metals in road and soil dust indicate that most of the heavy metals tend to concentrate in fine particles. Geoaccumulation index and enrichment factors analysis showed that Cu, Zn and Cd exhibited moderate or heavy contamination and significant enrichment, indicating the influence of anthropogenic sources. Vanadium, Cr, Mn and Co were mostly not enriched and were mainly influenced by crustal sources. For Ni, As and Pb, they ranged from not enriched to moderately enriched and were influenced by both crustal materials and anthropogenic sources. The conclusions were confirmed by multivariate analysis methods. Principle component analysis revealed that the major sources were vehicle emission, industrial activities, coal combustion, agricultural activities and crustal materials. The risk assessment results indicated that metal ingestion appeared to be the main exposure route followed by dermal contact. The most likely cause for cancer and other health risks are both the fine particles of soil and road dusts.     

Chemical compositions and sources of atmospheric PM10 in heating, non-heating and sand periods at a coal-based city in northeastern China

Mass concentrations and chemical components (18 elements, 9 ions, organic carbon [OC] and elemental carbon [EC]) in atmospheric PM(10) were measured at five sites in Fushun during heating, non-heating and sand periods in 2006-2007. PM(10) mass concentrations varied from 62.0 to 226.3 μg m(-3), with 21% of the total samples' mass concentrations exceeding the Chinese national secondary standard value of 150 μg m(-3), mainly concentrated in heating and sand periods. Crustal elements, trace elements, water-soluble ions, OC and EC represented 20-47%, 2-9%, 13-34%, 15-34% and 13-25% of the particulate matter mass concentrations, respectively. OC and crustal elements exhibited the highest mass percentages, at 27-34% and 30-47% during heating and sand period. Local agricultural residuals burning may contribute to EC and ion concentrations, as shown by ion temporal variation and OC and EC correlation analysis. Heavy metals (Cr, Ni, Zn, Cu and Mn) from coal combustion and industrial processes should be paid attention to in heating and sand periods. The anion/cation ratios exhibited their highest values for the background site with the influence of stationary sources on its upper wind direction during the sand period. Secondary organic carbon were 1.6-21.7, 1.5-23.0, 0.4-17.0, 0.2-33.0 and 0.2-21.1 μg m(-3), accounting for 20-77%, 44-88%, 4-77%, 8-69% and 4-73% of OC for the five sampling sites ZQ, DZ, XH, WH and SK, respectively. From the temporal and spatial variation analysis of major species, coal combustion, agricultural residual burning and industrial emission including dust re-suspended from raw material storage piles were important sources for atmospheric PM(10) in Fushun at heating, non-heating and sand periods, respectively. It was confirmed by principal component analysis that coal combustion, vehicle emission, industrial activities, soil dust, cement and construction dust and biomass burning were the main sources for PM(10) in this coal-based city.     

农药厂周边有机磷农药在生物体中残留的检测方法研究

对中美两国固定源测试技术体系进行总结并按照辅助类参数、烟气类污染物、烟尘类污染物、有机类污染物、元素及卤化物、在线监测规范进行分类并比较,指出两国测试体系的异同。结合目前形势指出中国烟尘、烟气及VOCs类污染物监测体系面临问题并提出建议。