Mapping residual pyrite after a mine spill using non co-located spatiotemporal observations

Monitoring of soil chemical properties for pollution assessment generally requires destructive soil sampling and results in spatiotemporal datasets where data from different sampling dates are non co-located. The objective of this study was to assess the spatial distribution of residual pyrite sludge at a reclaimed site, using temporally non co-located data on pH; soil oxidizable fraction (SOF); and EDTA-extractable Fe, Zn, and Cu from six different sampling dates over a period of 2 yr. During this period spatially averaged pH and Zn concentrations ranged, respectively, from 4.4 to 6.6 and from 60 to 140 mg kg(-1), with minimum pH values of below 2.7. The data were merged into a single dataset for each chemical property after applying a normal score (ns) transform. Normal score pH was significantly negatively correlated with the ns metal concentrations. A principal component analysis (PCA) showed that normal score pH, Zn, and Fe were associated with the residual contamination, while ns Cu, SOF, and elevation were related with historic contamination. The spatial dependence between the properties was found to be scale-dependent. The best ns estimates were produced by ordinary kriging with an anisotopic variogram model, for the properties related with Principal Component (PC) I, while those associated with PC II were best estimated using simple kriging with varying local means. A classified ns pH map showed that 33% of the study area reached at least once values of below 4 during the 2-yr period. This part of the area should be excluded to ensure successful revegetation.     

IDENTIFICATION OF AN OPTIMAL SAMPLING STRATEGY FOR A CONSTRUCTED WETLAND1

ABSTRACT: The objective of this investigation was to determine the effect of sampling frequency and sampling type on estimates of monthly nutrient loads and flow‐weighted nutrient concentrations in a constructed wetland. Phosphorus and nitrogen loads and concentrations entering and leaving a subtropical wetland (the Everglades Nutrient Removal Project, ENRP) were calculated on the basis of three sampling frequencies. The first frequency included weekly composite samples (three daily samples composited for one week) and grab samples from August 1994 to July 1997, representing a base‐line condition for comparison with results using reduced sampling frequencies. The second and third sampling frequency included three and two composite samples per month, respectively, drawn from the weekly samples. Total phosphorus and nitrogen loads calculated using two and three samples per month were almost identical to results based on four samples per month (least‐squares regression coefficients ranged from 0.96 to 0.98). Results of monthly mean flow‐weighted nutrient concentrations, obtained using reduced sampling frequencies, also were strongly correlated to concentrations calculated using the base‐line sampling frequency (r²ranged from 0.82 to 0.93). Grab samples did not always provide good estimates of loads or concentrations, particularly at the inflow when data were highly variable. From the results of this study, we can recommend that bi‐weekly composite sampling be used to monitor nutrient concentrations and loads discharged from larger‐scale Everglades Stormwater Treatment Areas (STAs) now under construction. Because there are high costs associated with water sample collection and processing, studies to identify optimal sampling frequencies should be a key feature in the design of any comprehensive wetland‐monitoring program.     

INFILTRATION AND WATER QUALITY ON RANGE SITES AT FORT STANTON,NEW MEXICO1

ABSTRACT: The hydrologic impacts of livestock grazing schemes on selected plant communities and soils at Fort Stanton, New Mexico, were evaluated. Simulated rainfall was applied to 1 m²plots. On a mesa-top, infiltration rates for a grassland livestock exclosure and a pinyon pine-juniper community closely approximated each other and were significantly greater (P = 0.10) than either a moderate continuous or a heavy continuous treatment in a grassland community. Sediment concentration from the heavy continuous treatment was more than twice that of the other treatments. Infiltration rates on the hillside site were highest in a pinyon pine-juniper community receiving short duration grazing. Infiltration for this treatment was found to be significantly higher (P = 0.10) than that of a short duration grazing treatment, but not from a rest rotation grazing treatment on grassland. The short duration grazing treatment on a grassland had the highest sediment concentration, while the rest rotation grazing on a grassland and the short duration pinyon pine-juniper treatments were found to be similar. In the bottomland site, a fertilized and unfertilized treatment showed no significant difference in infiltration or sediment concentration, although twice as many animals were present on the fertilized treatment.     

Combined incineration of industrial wastes with in-plant residues in fluidized-bed utility boilers--decision relevant factors.

In Austria more than 50% of the high-calorific industrial residues and wastes generated are utilized for energy recovery in industrial utility boilers. This study investigated full-scale trials of combined incineration of in-plant residues with various industrial wastes. These trials were carried out in order to learn how the alternatively used fuel influences the incineration process itself as well as the quantity and quality of the various incineration products. The currently used fuel, which consisted of in-plant residues as well as externally acquired waste wood and the refuse-derived fuel (RDF) mixtures used during the full-scale trials are characterized in terms of material composition as well as chemical and physical parameters. An input-output mass balance for the incineration plant (two fluidized bed combustion units, 20 and 30 MW, respectively) has been established, based on the data collected during the full-scale incineration trials. Furthermore, pollutant concentrations in the off-gas as well as the solid incineration residue are reported. It is not only the pollutant content but also a variety of other internal as well as external factors that have to be considered if a company is to decide whether or not to thermally utilize specific waste types. Therefore a strengths and weaknesses profile for several types of waste and the specific industrial boiler is also presented.     

Microméthode de dosage simultané de l'alcool isopropylique et de son métabolite l'acétone

Simultaneous determination of Isopropyl Alcohol and Acetone prove to be necessary in cases of poisoning by this widely used alcohol. An aluminum capsule containing a sample of blood to be analyzed is introduced into a gas chromatograph equipped with a flameionization detector and a Carbowax 20 M - Chromosorb WHP column. Use of a small blood sample (0.50 μl) and high sensitivity of the method make it a selected procedure in the clinical diagosis of poisoning by Isopropyl Alcohol.     

Sand Fences in the Coastal Zone: Intended and Unintended Effects

Sand-trapping fences modify the character of the coastal landscape and change its spatial structure, image, and meaning. This paper examines the relationship between these changes and fence usage at the municipal level, where most decisions about fence deployment are made. Use of fences in 29 municipalities on the developed coast of New Jersey is examined over a 6-year period. Interviews with municipal officers indicate that wooden slat sand-trapping fences are used primarily to build dunes to provide protection against wave uprush and flooding, but they are also used to control pedestrian traffic and demarcate territory. These uses result in changes in landforms and habitats. An aerial video inventory of fences taken in 2002 indicates that 82% of the shoreline had fences and 72% had dunes. Single and double straight fence rows are the most commonly used. Fences are often built to accomplish a specific primary purpose, but they can cause many different and often unanticipated changes to the landscape. The effects of a sand fence change through time as the initial structure traps sand, creates a dune that is colonized by vegetation, and becomes integrated into the environment by increasing topographic variability and aesthetic and habitat value. Sand fences can be made more compatible with natural processes by not placing them in locations where sources of wind blown sand are restricted or in unnatural shore perpendicular orientations. Symbolic fences are less expensive, are easy to replace when damaged, are less visually intrusive, and can be used for controlling pedestrian access.     

Impact of an Invasive Exotic Species on Stream Nitrogen Levels in Southern Illinois1

Abstract: Autumn‐olive (Elaeagnus umbellata Thunb.) is an invasive, exotic shrub that has become naturalized in the eastern United States. Autumn‐olive fixes nitrogen (N) via a symbiotic relationship with the actinomycete Frankia. At the plot scale, the presence of autumn‐olive has been related to elevated soil water nitrate‐N (NO₃^?‐N) concentrations. This study examined the relationship between autumn‐olive cover in a watershed and stream water quality. Stream water nitrate‐N (NO₃^?‐N) and ammonium‐N (NH₄⁺‐N) concentrations were measured in 12 first order ephemeral streams draining watersheds with mixed forest cover and a range of 0‐35% autumn‐olive cover. Percent autumn‐olive cover was positively correlated with mean stream NO₃^?‐N concentrations, but was not correlated with mean stream NH₄⁺‐N concentrations. While other studies have demonstrated a significant relationship between native N‐fixers and stream NO₃^?‐N, this is the first study to document a relationship for an invasive, exotic N‐fixing species. Results suggest that this exotic species can be an additional source of NO₃^? in local and regional water bodies and demonstrates an additional negative ecosystem consequence of invasion beyond losses in biodiversity.