Management of Urban Road Runoff Containing PAHs: Probabilistic Modeling and Its Application in Beijing,China1

Abstract: Pollutant loading from storm runoff is considered to be an important component of nonpoint source pollution in urban areas. In developing countries, because of the accelerated urbanization and motorization, storm runoff pollution has become a challenge for improving aquatic environmental quality. An effective storm runoff management plan needs to be developed, and questions concerning how much and which proportion of a storm should be treated need to be answered. In this study, a model is developed to determine the fraction of storm runoff that needs to be treated to meet the discharge standard within a given probability. The model considers that the pollutants can be mobilized during the early stage of a storm. The model is applied to a field study of polycyclic aromatic hydrocarbons (PAHs) in road runoff in Beijing, China. In this case, the probability that the PAH load will be mobilized with suspended sediments by the earlier portion of the flush is 73%. Given the high PAH loading in the study area and the referenced discharge standard, the probability that the entire runoff should be captured and treated is 94%. Thus, urban planners need to consider treatment systems for the majority of the storms in this area, whether the PAH load is in the first flush or not. This methodology can be applied to other regions where PAH loads may result in different management outcomes.     

Macro,Meso, and Micro‐Efficiencies in Water Resources Management: A New Framework Using Water Balance1

Haie, Naim and Andrew A. Keller, 2012. Macro, Meso, and Micro‐Efficiencies in Water Resources Management: A New Framework Using Water Balance. Journal of the American Water Resources Association (JAWRA) 48(2): 235‐243. DOI: 10.1111/j.1752‐1688.2011.00611.x Abstract: One of the most important performance indicators for water resources systems (WRSs) management is efficiency. Here, water balance, based on mass conservation, is utilized to systemically develop three levels of composite efficiency indicators for a WRS, which are configurable based on two types of water totals: total inflow and total consumption (outflow that effectively is not available for reuse). The indices characterize hydrology of an area by including in their formulations the flow dynamics at three integrated levels. Furthermore, the usefulness of water is incorporated into the indicators by defining two weights: one for quality, and the other for beneficial attributes of water use. Usefulness Criterion is the product of quality and beneficial weights, emphasizing the equal significance of the two dimensions. Both of these weights depend on the system itself and the priorities of the supervising organization, which also are shaped by the objectives and values of the given society. These concepts lead to the definition of Macro, Meso, and Micro‐Efficiencies, which form a set of integrated indicators that explicitly promotes stakeholder involvement in evaluation and design of WRSs. Macro, Meso, and Micro‐Efficiencies should be maximized for both water totals, which is an integrated prerequisite for sustainability and is less promoted by competing stakeholders. To demonstrate this new framework, it is applied to published data for urban and agricultural cases and some results are explained.     

A practical demonstration in modelling diclofenac and propranolol river water concentrations using a GIS hydrology model in a rural UK catchment

An existing GIS hydrology water quality model, LF2000-WQX, was applied to predict the concentrations of the pharmaceuticals diclofenac and propranalol in catchments. As a practical exercise the predominantly rural Tamar (UK) catchment was chosen. Consumption, excretion, and fate data were used to estimate the pharmaceutical input load for the model. The predicted concentrations throughout most of the catchment were 1 ng/L or less under low flow (90th percentile) conditions. However, at a few locations, downstream of small sewage treatment plants, concentrations above 25 ng/L were predicted. This exercise shows that it is relatively straightforward to predict the concentrations of new and emerging organic microcontaminants in real catchments using existing GIS hydrology water quality models. Further testing will be required to establish their accuracy.     

Nitrate in tile drainage of the semiarid Palouse Basin

Topographically heterogeneous agricultural landscapes can complicate and accelerate agrochemical contamination of streams due to rapid transport of water and chemicals to poorly drained lower-landscape positions and shallow ground water. In the semiarid Palouse region, large parts of these landscapes have been tile drained to enhance crop yield. From 2000-2004 we monitored the discharge of a tile drain (TD) and a nearby profile of soil water for nitrate concentration ([NO(3)]), electrical conductivity level (EC), and water content to develop a conceptual framework describing soil nitrate occurrence and loss via subsurface pathways. Tile-drain baseflow [NO(3)] was consistently 4 mg N L(-1) and baseflow EC was 200 to 300 microS cm(-1). Each year sudden synoptic increases in TD discharge and [NO(3)] occurred in early winter following approximately 150 mm of fall precipitation, which saturated the soil and mobilized high-[NO(3)] soil water throughout the profile. The greatest TD [NO(3)] (20-30 mg N L(-1)) occurred approximately contemporaneous with greatest TD discharges. The EC decrease each year (to approximately 100 microS cm(-1)) during high discharge, a dilution effect, lagged approximately 1 mo behind the first appearance of high [NO(3)] and was consistent with advective transport of low-EC water from the shallow profile under saturated conditions. Water-budget considerations and temporal [NO(3)] patterns suggest that these processes deliver water to the TD from both lower- and upper-slope positions, the latter via lateral flow during the high-flow season. Management practices that reduce the fall reservoir of soil nitrate might be effective in reducing N loading to streams and shallow ground water in this region.     

Assessing the US Clean Water Act 303(d) listing process for determining impairment of a waterbody

This study evaluated the US Clean Water Act (CWA) Section 303(d) listing and delisting processes, based on historical and current federal and state guidelines, to determine whether there are regional differences in water quality assessment criteria used by various states to determine impairment of a waterbody for inclusion in the 303(d) list. A review of almost 50 total maximum daily load (TMDL) and delisting documents revealed that the basis for listing or delisting a waterbody varies considerably and that, in many cases, determination of impairment was based on insufficient water quality information. Historical USEPA guidance on the 303(d) listing and delisting processes has been generally broad, resulting in wide interpretation of the assessment criteria by various states. This has led to unclear or conflicting listing methodologies among states, leading to inconsistencies in impairment determination. Common problems include inconsistent data quality and quantity, differences in frequency of monitoring, variable interpretation of narrative water quality standards, and differences in specificity of implementation and monitoring plans, resulting in significant difference in the basis for listing and delisting waterbodies. In response, several states have taken the initiative to provide much more specific guidance for their internal agencies. Listing and delisting criteria are generally clearer at the state level, but the development of differing state guidance documents has resulted in diversity in the development of the 303(d) lists and in the process of delisting a waterbody. While state guidelines are better able to address local considerations, such as variations in climate, landuse, and water quality objectives, as well as social and economic preferences, the variation in listing criteria has led to inconsistencies across state boundaries in the levels of attainment of national water quality objectives. For stakeholders that participate in the 303(d) listing process within a particular state, these types of discrepancies may not have a significant impact. However, these inconsistencies can lead to confusion for some stakeholders who participate in the process in multiples states, and must deal with differing and sometimes conflicting requirements depending on the location of their facilities.     

Effects of ultraviolet-B enhancement on marine trophic levels in a stratified coastal system

We examined the effects of enhanced UV-B radiation (relative to ambient) on marine trophic levels inhabiting a stratified coastal ecosystem, using living models (13 000 liter marine enclosures) of a temperate estuarine water column. The experiment was carried out in June and July 1994 on a plankton community drawn from lower Narragansett Bay, Rhode Island, USA. The effects of altered UV-B radiation (elevated 50% over ambient, tenfold DNA-weighted) on three trophic strata: the primary producers (photosynthetic algae), primary herbivores (copepods), and fish eggs and larvae (Anchoa mitchilli Cuvier and Valenciennes) were examined. The goal was to determine if UV-B–induced alterations at the base of the food chain had impacts on other elements of the trophic web. Phytoplankton abundance (P=0.02) and biomass (P=0.007) were significantly reduced in UV-B–enhanced treatments, above but not below the thermocline (2.25 m), during the second week of the study. Copepod nauplii were significantly less abundant in UV-B–enhanced mesocosms than in control treatments during the third and fourth weeks of the study (P=0.01). A portion of the impact on nauplii may be a result of alterations at the base of the food web. The greater mortality of nauplii in UV-B–enhanced systems did not translate to reduced abundance of copepodite (P=0.83) or adult (P=0.29) copepods. No significant effects were observed for microzooplankton (P=0.15). Neither the mortality rates nor the growth rates of larval anchovy were significantly affected by the experimental increase in UV-B (P>0.05). Despite the tenfold increase in biologically damaging UV-B, effects were not seen at higher trophic levels, most likely because of the rapid extinction of UV-B in the highly colored coastal water. Received: 13 November 1996 / Accepted: 18 July 1997     

Ground vegetation monitoring in Swiss forests: comparison of survey methods and implications for trend assessments

At Swiss long-term forest ecosystem research sites, ground vegetation was assessed during the period 1994-2003/2008 following two approaches: (1) visual assessment of the cover of species occurring in sixteen 1 m(2) quadrats, distributed over a 43 × 43 m area, and (2) phytosociological relevés in concentric circular plots of 30, 200, and 500 m(2). We first compared the two approaches with respect to diversity assessment. The number of species recorded in the 16 quadrats was in general higher than in the 30 m(2) plot and it represented 42% to 108% of the number of species recorded in the 500 m(2) plot. In a second step, we tested whether any temporal trends were apparent. In a few cases, a decrease or increase in Landolt's mean indicator values for light, nitrogen availability, soil pH, soil moisture, or temperature was found to be significant. However, these changes were usually restricted to one approach or one area. The only clear trend was detected in an unmanaged former coppice beech stand, for which all survey approaches indicated canopy closure. At another site, vegetation reacted to the local opening of the canopy following windthrow. In a third step, we compared the leaf area index (LAI), measured with an LAI-2000 instrument (Licor, Inc.) over each quadrat, with the indicator value of the vegetation for light (L). Within a site, there was no clear relationship between LAI and L values per quadrat. In contrast, across all sites, the relationship between LAI and L, averaged per site for all available years, was highly significant.