Mercury fate in ageing and melting snow: development and testing of a controlled laboratory system

A snow cover can modify when, to what extent, and in what form atmospherically deposited mercury is released to the underlying surface media and/or back to the atmosphere. Investigations of mercury transport and transformation processes in snow packs are hampered by the difficulty in controlling experimental and melt conditions and due to the huge variability in the composition and physical structure of environmental snow packs. A method was developed that allows the detailed mechanistic investigation of mercury fate in snow that is made, aged and melted under controlled laboratory conditions. A number of control samples established that mercury in indoor air, scavenged during the snow making process, constitutes the dominant source of mercury in the artificial snow. No addition of mercury is required. The amount of mercury in fresh snow was quantitatively (102 and 106% in two experiments) recovered in the dissolved and particulate fractions of the melt water and the vessel head space, confirming a mass balance for mercury and the absence of unquantifiable mercury sources and sinks in the experimental system. In snow made from unmodified tap water, more than half of the mercury present in the snowpack was recovered from the bottom of the snow vessel after all of the snow had melted. Such late elution is indicative of mercury being mostly associated with particles that are filtered by, and retained in, the shrinking snowpack. Addition of salt to the snow-making water at an environmentally realistic pH notably shifted the distribution of mercury in the snowpack from the particulate to the dissolved phase, resulting in more than 60% of the mercury eluting in the dissolved phase of early melt water fractions.     

Death in the octopus’ garden: fatal blue-lined octopus envenomations of adult green sea turtles

The blue-lined octopus Hapalochlaena fasciata contains the powerful neuromuscular blocker tetrodotoxin (TTX), which causes muscle weakness and respiratory failure. H. fasciata is regarded as one of the most venomous marine animals in the world, and multiple human fatalities have been attributed to the octopus. To date, there have been no recorded incidents of an envenomation of a wild animal. Here, we present a newly developed, multi-stage tandem mass spectrometry technique that provides unequivocal evidence for two cases of envenomation of two ~110 kg herbivorous green sea turtles by two tiny cryptic blue-lined octopuses (~4 cm body length). These cases of accidental ingestion provide evidence for the first time of the antipredator effect of TTX and highlight a previously unconsidered threat to turtles grazing within seagrass beds.     

Protection of biota on nonpark public lands: Examples from the US Department of Energy Oak Ridge Reservation

Security buffers of Department of Defense (DoD) and Department of Energy (DOE) reservations provide long-term habitat protection for many rare and endangered species. The importance of these government-owned reservations as nationally valuable resources has been relatively unrecognized. During the last 50 years, the DOE Oak Ridge Reservation (ORR) has been a relatively protected island in a region of rapidly expanding urbanization and land clearing. Consisting of the Oak Ridge National Environmental Research Park and associated lands surrounding DOE facilities at Oak Ridge Tennessee, the unique nature of the ORR in the surrounding landscape is clearly visible from the air and has been documented using remote sensing data. Although forests dominate much of other regions of eastern Tennessee, this 15,000-ha tract of mostly natural forest habitat is unique in the southern Ridge and Valley physiographic province, which is otherwise widely developed for pasture, marginal cropland, woodlot, and urban uses. Twenty state-listed and federal-candidate plant species are known to be present on the ORR. This richness of species, which are provided protection by state and federal laws, exceeds that of the Great Smoky Mountains National Park on a species area basis and is an index of the value of the ORR both regionally and nationally in conserving biodiversity. With the end of the Cold War, changing DoD and DOE missions combined with increasing development pressure contribute to uncertainty in the future management of security reservations.     

Ideology and wildlands management: The case of Rondeau Provincial Park,Ontario

This is a critical examination of some of the basic concepts that have guided management of parks and related reserves, often termed wildlands. Study is focussed on Rondeau Provincial Park, Ontario, and on concepts such as wilderness, primeval forest, and the Carolinian forest. Deer culling and other management policies and practices have been based upon the idea that the highly valued sassafras, tulip, and other species of the Carolinian forest are decreasing due to browsing. Field mapping and analysis of historic vegetation records indicate that this trend is not in fact occurring. Historic research also reveals difficulties in defining the Carolinian or other perceived types of forest for management purposes. A major reassessment of ideology and management policy and practice seem to be required in Rondeau and other wildlands. Vague or general concepts such as wilderness or preservation should be strongly complemented and supported by more precise statements of objectives, a learning attitude, and experimentation and research. As a result of the technical uncertainties and value judgments frequently involved, management should also be based upon the expressed preferences and continuing involvement of citizens.     

POTENTIAL IMPACTS OF CLIMATE CHANGE ON CALIFORNIA HYDROLOGY1

ABSTRACT: Previous reports based on climate change scenarios have suggested that California will be subjected to increased wintertime and decreased summertime streamflow. Due to the uncertainty of projections in future climate, a new range of potential climatological future temperature shifts and precipitation ratios is applied to the Sacramento Soil Moisture Accounting Model and Anderson Snow Model in order to determine hydrologic sensitivities. Two general circulation models (GCMs) were used in this analysis: one that is warm and wet (HadCM2 run 1) and one that is cool and dry (PCM run B06.06), relative to the GCM projections for California that were part of the Third Assessment Report of the Intergovernmental Panel on Climate Change. A set of specified incremental temperature shifts from 1.5°C to 5.0°C and precipitation ratios from 0.70 to 1.30 were also used as input to the snow and soil moisture accounting models, providing for additional scenarios (e.g., warm/dry, cool/wet). Hydrologic calculations were performed for a set of California river basins that extend from the coastal mountains and Sierra Nevada northern region to the southern Sierra Nevada region; these were applied to a water allocation analysis in a companion paper. Results indicate that for all snow‐producing cases, a larger proportion of the streamflow volume will occur earlier in the year. The amount and timing is dependent on the characteristics of each basin, particularly the elevation. Increased temperatures lead to a higher freezing line, therefore less snow accumulation and increased melting below the freezing height. The hydrologic response varies for each scenario, and the resulting solution set provides bounds to the range of possible change in streamflow, snowmelt, snow water equivalent, and the change in the magnitude of annual high flows. An important result that appears for all snowmelt driven runoff basins, is that late winter snow accumulation decreases by 50 percent toward the end of this century.     

The expert valuation method for assessing agro‐environmental policy

The Contingent Valuation Method (CVM) and other conventional valuation methods of non‐market goods often prove to be unsuitable for the evaluation of the benefits of agro‐environmental policy. Therefore, a new method is introduced, according to which a group of experts jointly evaluates the strengths, weaknesses and finally monetary benefit of agro‐environmental programmes. While the methodology combines expert surveys, group discussions and CVM, its theoretical background is merit good theory. Compared to CVM, the most important practical difference in its outcome is the greater openness of the results. As an example, the Expert Valuation Method is applied to two groups of agro‐environmental policy measures in Switzerland. Suggestions for more efficient levels of reimbursements are made.     

The impact of intersection design on simulated driving performance of young and senior adults

PURPOSE: The Federal Highway Administration (FHWA) proposed guidelines for highway design to increase the safe driving ability of older drivers; however, little empirical evidence exists to support the effectiveness of these guidelines. The purpose of this study was to investigate the effects of implementing these guidelines (in 4 pairs of intersections) on safe driving performance of older and younger drivers using a high-fidelity driving simulator. DESIGN AND METHODS: We replicated four intersection pairs (improved versus unimproved) in a high-fidelity, virtual reality driving simulator. Simulator scenarios were created from actual road locations, replicating road geometrics and traffic control devices. The simulator's controls were integrated with an actual vehicle to make the driving experience as realistic as possible. Kinematic measures were obtained from the simulator in conjunction with driving errors recorded by trained driving evaluators sitting in the cab of the car. Thirty-nine subjects, 19 younger and 20 older adults, participated in the study. RESULTS: For the kinematic data we found greater lateral control, as indicated by significantly smaller maximum yaw during the turn phase, at all of the improved intersections when compared to the unimproved intersections. We found some significant age differences, but mostly in only one of the intersection-pairs. For the behavioral data, there were significant differences in driving errors between improved and unimproved intersections in two intersection-pairs; however, there were no significant differences in driving errors between the older and younger drivers. IMPLICATIONS: The findings suggest that both young and older drivers may benefit from roadways with safety features recommended by the FHWA guidelines as indicated by the increased lateral control of the vehicle when negotiating these intersections. These findings generate critical information for those involved in the design of roadway systems.     

The impact of roadway intersection design on driving performance of young and senior adults

OBJECTIVE: To test the effectiveness of the FHWA guidelines for intersection design. METHODS: In an experimental design we used kinematics measures from an instrumented vehicle and behavioral (error) data collected during on-road evaluations to quantify the effects of improved versus unimproved intersections (turn phase) and to determine if these intersections were safer (vehicular stability and driver confidence) for both older (65-85 years) and younger (25 -45) drivers. We analyzed kinematics data with a 2 x 2 repeated measures ANOVA and behavioral data (driving errors yes, no) with Wilcoxon sign rank test (within subject variable: intersection improved vs. unimproved) and Wilcoxon rank sum test (between subject variable: age, younger vs. older driver). RESULTS: Kinematics measures (turn phase), showed three maneuvers had statistically significantly lesser side forces (measured by lateral acceleration and combined acceleration) for the improved conditions, and four maneuvers had statistically significantly greater, yet appropriate, speeds for the improved conditions. Lesser side forces indicated improved lateral stability and increased speed indicated greater confidence. Drivers made fewer errors on two of the improved intersections; but across all maneuvers, older drivers appeared to make fewer errors on the improved intersections. CONCLUSIONS: This study brings empirical intersection design and safety information for engineers and city planners to consider as they plan and develop intersections. Future researchers may want to use the conceptual and analytical framework of this study to determine the effectiveness of other FHWA guidelines. Given that these intersection design guidelines benefit younger and older drivers alike, plausible policy-making opportunities are opened in the design of safe roadway systems, to benefit the broad spectrum of adult drivers.     

The importance of individuals' repertoires of behaviors: the scientific appropriateness of studying multiple behaviors and general attitudes

This paper addresses Blau's critique of our early research on behavioral aggregates; we review the theoretical and empirical work on multiple behaviors. We address the definition and measurement of behavioral aggregates, the issue of common method variance, and factors influencing behavior choices. Research from other behavioral areas that uses an approach similar to ours is reviewed as well as relevant research on withdrawal aggregates since 1991. We argue that a focus on general withdrawal constructs rather than individual behaviors will generate significant scientific and practical advantages. The study of constructs will likely provide a basis for generalizations across situations, populations, and time. © 1998 John Wiley & Sons, Ltd.