Separation and characterization of the colored material from sugarcane molasses

The colored material (X) was effectively separated from sugarcane molasses using reversed-phase chromatography. Characterization of the molecular structure of sample X was performed using infrared absorption (IR) spectrometry, mass spectrometry (MS), and dynamic light scattering (DLS). The IR spectrum was similar to that of commercial humic acid, and the MS analysis showed that the sample possessed relatively small heterogeneous molecules with molecular masses around 234, 446, 657, 868, and 1079 Da. On the other hand, X sample showed an inhibitory activity toward the cysteine proteinase papain. Furthermore, the inhibitory (G-1) and weak inhibitory (G-2) fractions were separated from sample X using gel permeation chromatography. Samples G-1 and G-2 inhibited papain partial-noncompetitively and had the inhibition constants of 5.01 x 10(-5) and 1.08 x 10(-3)M, respectively. Interestingly, in the DLS experiment, the Stokes radius of sample G-1 was approximately 2 nm, about twice one of sample G-2.     

摇动床生物膜反应器和活性污泥法组合技术处理高浓度有机废水的研究

利用摇动床生物膜反应器(简称摇动床)技术具有的容积负荷高与污泥产量低的优点,在普通活性污泥池的前部填充高性能丙烯酸树脂纤维(Biofringe)填料,研究了摇动床和活性污泥法组合技术处理高浓度有机废水的有效性。结果表明,该组合技术具有很强的有机物去除能力,当进水COD平均质量浓度由1500mg/L上升到2514mg/L时,出水COD的平均去除率基本保持在96%以上;整个运行阶段的出水COD浓度均满足《污水综合排放标准》(GB8978—1996)的二级标准;当进水NH4+-N浓度增加时,NH4+-N的去除率由99.7%降低到76.5%,但是在试验运行的整个阶段,摇动床和活性污泥法组合技术系统都表现出较强的硝化能力;活性污泥池中最高的混合液悬浮固体(MLSS)质量浓度为10625mg/L,最高MLSS约为普通活性污泥法的4倍;运行结束后的污泥产率为0.186,污泥产率仅为普通活性污泥法的50%左右。     

Secondary polygyny by inbred wingless sexuals in the dolichoderine ant Technomyrmex albipes

Summary Technomyrmex albipes makes huge polydomous colonies which consist of up to several millions of adults. In field colonies, dealate queens are rare or absent, though winged males and winged females emerge annually (synchronously) in large numbers from late may to mid June. Field and laboratory observations showed that the reproduction of established colonies was performed by wingless females inseminated by wingless males from the same colony. Dissections and morphological examinations revealed that wingless females are workers with no spermatheca and intercastes with a spermatheca. Most intercastes were inseminated, had developed ovaries, and seemed to reproduce, while workers did not seem to reproduce. Extranidal tasks were performed only by workers. Approximately half of the adult population were intercastes, and wingless males represented only a small portion of all adults, the rest being nonreproductive workers. Intercastes and wingless males were produced throughout the year except in winter. The winged females and males copulate outside the nest only after the nuptial flight and the dealate females are able to perform independent founding, but they are also eventually supplanted by intercastes. The adoption of dealate queens by an established natal colony did not seem to occur. Thus we infer that in this species the winged reproductives disperse and found new colonies, while inbred wingless reproductives allow the enlargement and budding of colonies. This species has a special trophic-flow system. There is no trophallaxis among adults, and nutrient transfer from adults to other colony members is achieved exclusively by specialized trophic eggs. All females (dealate queens, intercastes, and workers) seem to produce trophic eggs. This aphid-like life cycle, i.e., the occurrence of both winged and wingless reproductive forms, may have evolved as an adaptation supporting the development of secondary polygyny and polydomy.Offprint requests to: K. Yamauchi     

Basic Research on the Emission of Polycyclic Aromatic Hydrocarbons caused by Waste Incineration

The emission of polycyclic aromatic hydrocarbons (PAH) caused by municipal waste incineration varies according to waste composition and operating parameters such as furnace temperature and excess air. However, to obtain a sample sufficient to measure the emission of PAH at trace levels, it is necessary to operate the incinerator for many hours. Since during these lengthy periods it has not always been possible to maintain stable conditions, it is very difficult to determine the relationship between the emission and waste composition.

In our basic research, therefore, we used municipal waste with an artificially regulated composition for our combustion experiments, and by using an experimental Incinerator we examined the emission behavior of PAH with respect to changes in waste composition and combustion conditions. The following facts were revealed by the results: ? The PAH found in the flue gas were predominantly the more volatile compounds.

? When municipal waste was incinerated at over 850 °C, the concentration of PAH in the flue gas increased rapidly as the proportion of plastics in the waste increased from 0 to 24 percent.

? The elimination of plastics from municipal waste by separate collection and the improvement of combustion conditions can effectively diminish the emission of PAH.

     

Studies on the coupling product between oxidation products derived from pentachlorophenol and cyclodextrins

The coupling products (CPs), which were formed via the peroxosulfate catalyzed oxidation of pentachlorophenol (PCP) with iron(III)-tetrakis(sulfonatophenyl)porphyrin (Fe(III)-TPPS) in the presence of hydroxypropyl-beta -cyclodextrin (HP-beta -CD) or HP-gamma -CD, were separated by ultrafiltration from the reaction mixture. When the percentages of chlorine species in the reaction mixture were calculated from the concentrations of organic chlorine in the reaction mixture and CPs, 10-25% of chlorine species in the reaction mixture was organic chlorine that was incorporated into CDs. Analyses of the CPs by pyrolysis-GC/MS (Py-GC/MS) and 13C NMR showed that the PCP-derived products were covalently incorporated into the CDs. To evaluate the acute toxicity of the CPs, a Microtox test was examined. Toxicities of the CPs were reduced slightly, compared to the controls (PCP alone and PCP + reaction blanks). In the reaction blanks, mesaconic acid (MA) moieties were detected as a result of the oxidation of CDs in the absence of PCP. Thus, factors in the toxicities, detected in the CPs, can be attributed to the oxidation products derived from CDs, such as MA, as well as the PCP-derived products incorporated into the CDs.     

The Influence of Synoptic-scale Air Flow and Local Circulation on the Dust Layer Height in the North of the Taklimakan Desert

The present study investigates the influences of synoptic-scale air flows and local wind circulations on the dust layer height (DLH) in the Taklimakan Desert, based on lidar observations performed in the north of the desert in March 2003. The DLH fluctuates approximately every three days between 2500 m (above sea level) and 5000 m, including diurnal variations. Meteorological analyses and numerical simulations show that the three-day fluctuation of DLH corresponds with variations in synoptic-scale air flows over the Taklimakan Desert, and the diurnal variations are linked to downdrafts and updrafts that are formed over the north of the desert as part of local circulations. When strong northerly winds prevail in the upper troposphere and a developed valley wind blows toward the Tienshan Mountains in the lower troposphere, the downdrafts strengthen in the middle troposphere over the north of the desert, lowering the DLH to about 2500 m. In contrast, the DLH rises to about 5000 m when the updrafts develop between strong southerly winds in the upper troposphere and a developed mountain wind blowing from the Tienshan Mountains. Simulations for the local circulation behavior without the presence of the Tienshan Mountains demonstrate that the valley and mountain winds on the southern slope of the Tienshan Mountains control the intensity of the downdrafts and updrafts, thereby influencing the DLH over the north of the Taklimakan Desert.     

Climatic and Environmental Changes in the Source Areas of Dust Storms in Xinjiang, China, during the Last 50 Years

The desert environmental changes in the source areas of dust storms occurring in Xinjiang are discussed based on the climate changes and the impacts of human activities in Xinjiang during the past 50 years. The results show that the climate in Xinjiang is changing from a warm-dry type to a warm-wet one. The warm-wet climate has been obvious since the mid-1970's, and especially the sensitivity of the regional climate change in this arid area is obviously revealed by many factors, such as the characteristics of the local climate change in south Xinjiang and north Xinjiang, the difference of climate change in the alpine zones and the basins, and the change of areas of the waters bodies. Furthermore, these factors also reveal the difference in the regional climate change between Xinjiang and central and eastern areas of China. The occurrence and development of dust storms are directly affected by the precipitation, air humidity, status of underlying surface, etc. in the arid areas. The frequency and intensity of dust storms are closely related to the natural conditions, changes of climate and desert environment, as well as the dynamic conditions (i.e., weather systems) in the source areas of dust storms. Therefore, global warming is one of the main causes resulting in the degradation of the ecological environment and the frequent occurrence of natural disasters, especially the disasters of sand drift and dust storms in the arid areas since the late-1980's, which reveals that the inland arid areas are sensitive regions to climate changes.     

联合国建议的固体氧化物燃烧测试方法的研究

由于日本消防法中固体氧化物的燃烧试验方法,与联合国黄皮书中所建议的试验方法有所不同,在实际应用中经常出现矛盾.因此,本文对其中的一些不同之处进行了重新的研究考察.并与日本海事检定协会和代表联合国标准测试方法的荷兰应用科学研究组织进行合作,对比研究了联合国建议的关于固体氧化物燃烧试验的方法.并就其中发现的问题提出了相应的改进意见.具体有以下4方面的措施:(1)纤维素种类对于燃烧时间的影响;(2)环境湿度及纤维素含水量对燃烧时间的影响;(3)导火线材料与导火线破裂方式出现的问题;(4)联合国建议中的举例数据.     

Agroforestry as a sustainable landuse option in degraded tropical forests: a study from Bangladesh

The tropical deciduous forest in Bangladesh provides a substantial part of country’s forest and where the government has introduced participatory agroforestry landuse. This study examined management issues, financial viability, and environmental as well as social sustainability of this landuse system. The forest department allocated a plot of size 1.0 ha among the selected participants where they were allowed to practice agriculture as well as to plant tree species for 10 years. The financial indicators indicated that the landuse system was profitable and attractive [net present value (NPV) = US$ 17,710 and benefit-cost ratio (BCR) = 4.12]. It was also viable and suitable from the social and environmental stand points. The study concluded that under the present environmental and socio-economic scenario, this production system could be the best management tool that would earn money, stop forest degradation, and finally be a model of sustainable land management in an overpopulated country.     

A study on the self-assembly behavior of dark materials from molasses

We have previously demonstrated that dark materials (DM) in acidified molasses are effectively adsorbed to Amberlite XAD7HP resin and are eluted from the resin with 0.1 M sodium hydroxide. In this paper, we have characterized the self-assembly behavior of molasses DM by using dynamic and static light scattering in combination with isoelectric focusing and infrared absorption spectroscopy in order to better understand the resin adsorption mechanism. One of DM derivatives, X-G2, contained carboxyl and hydroxyl groups and had a weight-average molar mass of 9.39?×?10³ to 4.42?×?10⁴ at pH 2.1–11.5. The aggregates retained their spherical shape over the full pH range and the large gyration radius (66.4–80.0 nm) indicated that the inner structure was loosely packed. Furthermore, X-G2 had an isoelectric point of 1.8, and its density increased sharply at pH 5.9 and then approached a nearly constant value under alkaline conditions. In summary, the self-assembly processes of DM are controlled by intermolecular hydrogen-bonding and hydrophobic interactions. The aggregates adsorb to the resin through hydrophobic interactions and are eluted when excess carboxylate anions are generated.