TRANSIENT STORAGE ASSESSMENTS OF DYE‐TRACER INJECTIONS IN RIVERS OF THE WILLAMETTE BASIN,OREGON1

ABSTRACT: Rhodamine WT dye‐tracer injections in rivers of the Willamette Basin yield concentration‐time curves with characteristically long recession times suggestive of active transient storage processes. The scale of drainage areas contributing to the stream reaches studied in the Willamette Basin ranges from 10 to 12,000 km². A transient storage assessment of the tracer studies has been completed using the U.S. Geological Survey's One‐dimensional Transport with Inflow and Storage (OTIS) model, which incorporates storage exchange and decay functions along with the traditional dispersion and advection transport equation. The analysis estimates solute transport of the dye. It identifies first‐order decay coefficients to be on the order of 10^?5/sec for the nonconservative Rhodamine W.T. On an individual subreach basis, the first‐order decay is slower (typically by an order of magnitude) than the transient storage process, indicating that nonconservative tracers may be used to evaluate transient storage in rivers. In the transient storage analysis, a dimensionless parameter (A_s/A) expresses the spatial extent of storage zone area relative to stream cross section. In certain reaches of Willamette Basin pool‐and‐riffle, gravel‐bed rivers, this parameter was as large as 0.5. A measure of the storage exchange flux was calculated for each stream subreach in the simulation analysis. This storage exchange is shown subjectively to be higher at higher stream discharges. Hyporheic linkage between streams and subsurface flows is the probable physical mechanism contributing to a significant part of this inferred active transient storage. Hyporheic linkages are further suggested by detailed measurements of river discharge with an Acoustic Doppler Current Profiler system delineating zones in two large rivers where water alternately enters and leaves the surface channels through gravel‐and‐cobble riverbeds. Measurements show patterns of hyporheic exchange that are highly variable in time and space.     

PROTECTING BEIJLNG'S MUNICIPAL WATER SUPPLY THROUGH WATERSHED MANAGEMEN AN ECONOMIC ASSESSMENT1

ABSTRACT: Watersheds above the Miyun reservoir, a principal source of surface water for Beijing, are designated to be managed for water production, but under the principle of multiple use. Because of the scarcity of arable land, these watersheds cannot be managed only for drinking water. Efforts are under way to reduce sediment delivery, improve the quality of water entering Miyun reservoir, and improve the welfare of watershed inhabitants. An economic appraisal of a watershed management project for the 3,298‐ha Shixia watershed above the Miyun reservoir, indicates a 24 percent economic rate of return on the investment made in the project. The net present value (NPV) of the project, calculated at a discount rate of 10 percent, is approximately US$3.49 million. Sensitivity analyses indicate that a doubling of labor costs lowers the NPV to US$2.07 million and a 10 percent decrease in benefits lowered the NPV to US$2.87. It is concluded that the implementation of conservation practices on the Shixia Demonstration Watershed represent an economically efficient use of resources.     

Field Trial of Biosparging with Oxygen for Bioremediation of Volatile Organic Compounds

Xpert Design & Diagnostics, LLC (XDD), & Conestoga‐Rovers and Associates (CRA) conducted a biosparging field trial at a Superfund site in New Jersey. The biosparging field trial proved that biosparging with oxygen was very effective in promoting the biological destruction of benzene. The approximately 265‐day period of oxygen injection successfully reduced benzene concentrations by several orders of magnitude, or even to non‐detect values, at least 40 feet from the point of injection. Through co‐precipitation of arsenic with oxidized iron, biosparging also effectively reduced total concentrations of arsenic and iron in groundwater. Based on the results of the biosparging field trial, the final remedy for the site has been amended to include the use of biosparging technology as an alternative to groundwater pumping and aboveground treatment in select locations. © 2001 John Wiley & Sons,Inc.     

Predicted uranium and radon concentrations in New Hampshire (USA) groundwater—Using Multi Order Hydrologic Position as predictors

Two radioactive elements, uranium (U) and radon (Rn), which are of potential concern in New Hampshire (NH) groundwater, are investigated. Exceedance probability maps are tools to highlight locations where the concentrations of undesirable substances in the groundwater may be elevated. Two forms of statistical analysis are used to create exceedance probability maps for U and Rn in NH groundwater. The first, Boosted Regression Tree (BRT), was selected for estimating U exceedance values. It computes exceedance values directly using the Bernoulli distribution function. The second method of statistical analysis used for Rn to determine exceedance probabilities is ordinary least squares (OLS) regression. In the process of determining exceedance probabilities for U and Rn, the utility of a new dataset is investigated. That new predictor dataset is the Multi-Order Hydrologic Position (MOHP) dataset. MOHP raster datasets have been produced nationally for the conterminous United States at a 30-m resolution. The concept behind MOHP is that, for any given point on the earth's surface, there is the potential for a longer groundwater flow path as one goes deeper beneath the land surface. MOHP predictors were tested in both models. Three MOHP predictors were found useful in the BRT model and two in the OLS model. MOHP data were found useful as predictors along with other site characteristics in predicting U and Rn exceedance probabilities in New Hampshire groundwater.     

Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate-thiosulfate redox couple

The objective of the laboratory study is to examine the conditions under which transition metal ions (e.g., ferrous ion, Fe2+) could activate the persulfate anion (S2O8(2)-) to produce a powerful oxidant known as the sulfate free radical (SO4-*) with a standard redox potential of 2.6 V. The SO4-* is capable of destroying groundwater contaminants in situ such as trichloroethylene (TCE). Experiments using Fe2+ as an activator under various molar ratios of S2O8(2)-/Fe2+/TCE in an aqueous system indicated that partial TCE degradation occurred almost instantaneously and then the reaction stalled. Either destruction of SO4-* in the presence of excess Fe2+ or the rapid conversion of all Fe2+ to Fe3+ limited the ultimate oxidizing capability of the system. Sequential addition of Fe2+ in small increments resulted in an increased TCE removal efficiency. Therefore, it appeared that Fe2+ played an important role in generating SO4-*. An observation of oxidation-reduction potential (ORP) variations revealed that the addition of sodium thiosulfate (Na2S2O3) to the ferrous ion activated persulfate system could significantly decrease the strong oxidizing conditions. It was hypothesized that the thiosulfate induced reducing conditions might convert Fe3+ to a lower valence state of Fe2+, making the Fe2+ available to activate persulfate decomposition. The sequential addition of thiosulfate (S2O3(2)-), after the initial stalling of ferrous ion activated persulfate oxidation of TCE, resulted in an improvement in TCE removal. The ferrous ion activated persulfate-thiosulfate redox couple resulted in fairly complete TCE degradation in aqueous systems in a short time frame. In soil slurry systems, TCE degradation was slower in comparison to aqueous systems.     

瓦里关气相色谱法大气CO_2和CH_4在线观测数据处理分析

加强我国本底站温室气体数据资源的科学管理与共享,首先应保证观测全流程的标准化和规范化,确立数据处理和质量控制方法.我国青海瓦里关全球本底站自1994年开始了气相色谱-氢火焰离子化检测器法(GC-FID)大气CO2和CH4在线观测,本文详细讨论了该系统原始资料采集、数据信息合并、时间序列检查、观测员级质量控制和专家级质量控制等流程.利用局部近似回归法对大气CO2和CH4数据进行本底值筛分,获得CO2本底数据百分比约占有效数据的72%、CH4占44%.在线观测的CO2和CH4月平均浓度与同期瓶采样分析结果基本一致,相对偏差均在±0.5%以内.经流程化处理和质控的瓦里关大气CO2和CH4本底浓度变化资料已进入全球同化数据库(Globalview-CO2、Globalview-CH4),报送世界温室气体数据中心(WDCGG)并应用于世界气象组织(WMO)温室气体公报和联合国政府间气候变化专门委员会(IPCC)评估.     

Energy return on investment: toward a consistent framework

Numerous technologies have been proposed as partial solutions to our declining fossil energy stocks. There is a significant need for consistent metrics to compare the desirability of different technologies. The ratio of energy produced to energy consumed by an energy production technology-known as the energy return on investment (EROI)-is an important first indicator of the potential benefits to society. However, EROI analysis lacks a consistent framework and has therefore yielded apparently conflicting results. In this article, we establish a theoretical framework for EROI analysis that encompasses the various methodologies extant in the literature. We establish variations of EROI analysis in two different dimensions based on the costs they include and their handling of nonenergy resources. We close by showing the implications of the different measures of EROI upon estimating the desirability of a technology as well as for estimating its ultimate net energy capacity.     

Transport of oxytetracycline,chlortetracycline, and ivermectin in surface runoff from irrigated pasture

The transport of oxytetracycline, chlortetracycline, and ivermectin from manure was assessed via surface runoff on irrigated pasture. Surface runoff plots in the Sierra Foothills of Northern California were used to evaluate the effects of irrigation water application rates, pharmaceutical application conditions, vegetative cover, and vegetative filter strip length on the pharmaceutical discharge in surface runoff. Experiments were designed to permit the maximum potential transport of pharmaceuticals to surface runoff water, which included pre-irrigation to saturate soil, trimming grass where manure was applied, and laying a continuous manure strip perpendicular to the flow of water. However, due to high sorption of the pharmaceuticals to manure and soil, less than 0.1% of applied pharmaceuticals were detected in runoff water. Results demonstrated an increase of pharmaceutical transport in surface runoff with increased pharmaceutical concentration in manure, the concentration of pharmaceuticals in runoff water remained constant with increased irrigation flow rate, and no appreciable decrease in pharmaceutical runoff was produced with the vegetative filter strip length increased from 30.5 to 91.5 cm. Most of the applied pharmaceuticals were retained in the manure or within the upper 5 cm of soil directly beneath the manure application sites. As this study evaluated conditions for high transport potential, the data suggest that the risk for significant chlortetracycline, oxytetracycline, and ivermectin transport to surface water from cattle manure on irrigated pasture is low.     

SOCIOECONOMIC IMPACTS OF CLIMATE CHANGE ON U.S. WATER SUPPLIES1

ABSTRACT: A greenhouse warming would have major effects on water supplies and demands. A framework for examining the socioeconomic impacts associated with changes in the long-term availability of water is developed and applied to the hydrologic implications of the Canadian and British Hadley2 general circulation models (GCMs) for the 18 water resource regions in the conterminous United States. The climate projections of these two GCMs have very different implications for future water supplies and costs. The Canadian model suggests most of the nation would be much drier in the year 2030. Under the least-cost management scenario the drier climate could add nearly $105 billion to the estimated costs of balancing supplies and demands relative to the costs without climate change. Measures to protect instream flows and irrigation could result in significantly higher costs. In contrast, projections based on the Hadley model suggest water supplies would increase throughout much of the nation, reducing the costs of balancing water supplies with demands relative to the no-climate-change case.