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121.
Resource managers require objective methodologies to optimize decisions related to forest road deactivation and other aspects of road management, especially in steep terrain, where road-related slope failures inflict extensive environmental damage. Decision analysis represents a systematic framework that clearly identifies real options and critical decision points. This framework links current decisions with expected future outcomes and provides advantages such as a common currency to systematically explore the liability consequences of limited budget expenditures to road deactivation and other road-related activities. Furthermore, the decision framework prevents the analysis from becoming hopelessly entangled by the vast number of possibilities generated by the alternative occurrences, magnitudes, and consequences of landslide/debris flow events and provides the information required for the first step of an adaptive management process. Here, a structured analysis of potential environmental risks for a road deactivation project in coastal British Columbia, Canada is presented. The application of decision analysis generates a ranking of the expected benefits of proposed deactivation activities on various road sections. The ranking distinguishes between road sections that offer high expected benefit from those that offer moderate to low expected benefit. Seventeen of 171, 100–m road segments accounted for 18% of the cumulative cost and 98% of the cumulative expected net benefits from road deactivation. Furthermore, the cost of deactivating a section of road is related to the expected benefit from such deactivation, thus providing the basis for more effective resource allocation and budgeting decisions.  相似文献   
122.
A two-dimensional reservoir toxics model is essential to establishing effective water resources management and protection. In a reservoir, the fate of a toxic chemical is closely connected with flow regimes and circulation patterns. To better understand the kinetic processes and persistence and predict the dissipation of toxic contaminants in the reservoir during a spill or storm runoff event, a toxics submodel was developed and incorporated into an existing laterally integrated hydrodynamics and transport model. The toxics submodel describes the physical, chemical, and biological processes and predicts unsteady vertical and longitudinal distributions of a toxic chemical. The two-dimensional toxicant simulation model was applied to Shasta Reservoir in California to simulate the physico-chemical processes and fate of a volatile toxic compound, methyl isothiocyanate (MITC), during a chemical spill into the Sacramento River in 1991. The predicted MITC concentrations were compared with those observed. The effect of reservoir flow regimes on the transport and fate of the toxic substance was investigated. The results suggested that the persistence of MITC is significantly influenced by different flow regimes. Methyl isothiocyanate is more persistent in the reservoir under an interflow condition due to reduced volatilization from deep layers than under an overflow condition. In the overflow situation, the plume moved more slowly toward the dam and experienced greater dissipation. This analysis can assist in toxic spill control and reservoir management, including field sampling and closure of water intakes.  相似文献   
123.
Some soils develop severe and persistent water repellency following contamination with crude oil. This study was conducted to characterize and compare the spatial distribution of soil water repellency and residual oil contamination at 12 such sites. The molarity of ethanol droplet (MED) test was used to assess soil water repellency and the content of dichloromethane-extractable organics (DEO) was used to quantify residual oil in soil. We found a relatively strong positive correlation between MED and DEO in soil (r2 = 0.74). Both variables tended to decrease abruptly with depth at 11 of the 12 study sites. Dichloromethane-extractable organics similarly decreased with depth in control adjacent soil (MED = 0 M), but from an average concentration one to two orders of magnitude lower than in water-repellent soil. Using data from corresponding control adjacent and water-repellent soils, we determined that approximately 29 and 10% of measured total organic carbon in water-repellent A- and B-horizon soil, respectively, consists of dichloromethane-insoluble organic carbon of petroleum origin. We propose that this fraction contains most of the causative agents of soil water repellency at the studied sites.  相似文献   
124.
The 1991 EU Nitrate Directive was designed to reduce water pollution from agriculturally derived nitrates. England and Wales implemented this Directive by controlling agricultural activities within their most vulnerable areas termed Nitrate Vulnerable Zones. These were designated by identifying drinking water catchments (surface and groundwater), at risk from nitrate pollution. However, this method contravened the Nitrate Directive because it only protected drinking water and not all waters. In this paper, a GIS was used to identify all areas of groundwater vulnerable to nitrate pollution. This was achieved by constructing a model containing data on four characteristics: the quality of the water leaving the root zone of a piece of land; soil information; presence of low permeability superficial (drift) material; and aquifer properties. These were combined in a GIS and the various combinations converted into a measure of vulnerability using expert knowledge. Several model variants were produced using different estimates of the quality of the water leaving the root zone and contrasting methods of weighting the input data. When the final models were assessed all produced similar spatial patterns and, when verified by comparison with trend data derived from monitored nitrate concentrations, all the models were statistically significant predictors of groundwater nitrate concentrations. The best predictive model contained a model of nitrate leaching but no land use information, implying that changes in land use will not affect designations based upon this model. The relationship between nitrate levels and borehole intake depths was investigated since there was concern that the observed contrasts in nitrate levels between vulnerability categories might be reflecting differences in borehole intake depths and not actual vulnerability. However, this was not found to be statistically important. Our preferred model provides the basis for developing a new set of groundwater Nitrate Vulnerable Zones that should help England and Wales to comply with the EU Nitrate Directive.  相似文献   
125.
Remobilisation of contaminant metals from sediments can occur by chemical, biological or physical changes. This in turn can lead to contaminant fluxes to the porewaters and ultimately the water column. The aim of the research presented here is to document post-depositional controls on metal mobility and fluxes in a heavily metal-contaminated estuary. This will allow for an improved understanding of the impact of contaminated sediments on water quality from both a short-term and long-term perspective. Dulas Bay is situated on the east coast of Anglesey, North Wales, and receives polluted waters from Parys Mountain. Metals within Dulas Bay sediments show surface enrichment and variations in mineralogical form. Diagenesis clearly plays a role in post-depositional behaviour of the metals, forming sulphides and potentially carbonates. The presence of a dominant exchangeable/carbonate fraction, and elevated porewater metals, in this sulphidic system is significant and could indicate the presence of freshwater diagenesis, or, reflect the high levels of metals in the sediment.  相似文献   
126.
Roy S  Mysior P  Brzezinski R 《Chemosphere》2002,48(8):833-842
High resolution mass spectrometry gas chromatography (GC/MS) is the standard method for dioxin and furan analysis in environmental matrices. Considered as very accurate, this method is however time consuming and expensive. Methods based on biological interactions have the necessary sensitivity but began only recently to be investigated in the context of environmental applications. We have compared dioxin and furan toxicity levels (expressed as toxic equivalent quantities (TEQs)) in soil samples by three analytical approaches: the micro-ethoxyresorufin-o-deethylase (EROD) bioassay (a receptor-based method), an immunoassay (antibody-based method) and GC/MS analysis (used as a reference) using a shortened extraction-purification method. Both biological methods were sensitive to interferences from compounds co-extracted from samples. Most samples were underestimated by the immunoassay and, at a greater extent, overestimated by the EROD bioassay. The average accuracy of TEQ estimation (86 +/- 45% of values established by GC/MS) and the absence of false-negatives showed by the immunoassay suggest the usefulness of this method for semi-quantitative, preliminary characterization of potentially contaminated sites.  相似文献   
127.
Irreversible environmental changes are occurring along the Colorado River in the Grand Canyon as a result of regulation of the river flow by the Glen Canyon Dam. The questions of primary importance in managing this great natural resource are 1) in what manner and how rapidly are the physical and ecological adjustments taking place, and 2) is the increased use of the river for recreational boating contributing to the degradation? Human use along the Colorado River is limited, for the most part, to the relic, pre-dam fluvial deposits colloquially called “beaches.” With the new river regime these deposits are positioned well above the present high-water stage, 27,000 cubic feet/second (cfs), or 765 cubic meters/second (cms), so they are not replenished periodically as they were prior to construction of the dam in 1963. The dominant natural processes now are aeolian sand transport and mass wasting. The float-trip passengers use the river beaches for hiking, camping, and. lunch stops. At the most desirable sites thirty to forty people camp on the beaches each night over a four to five month season. Human impact includes incorporation of campsite litter, burial of chemically treated waste, and the direct stress associated with people walking on the vegetation and unstable sedimentary deposits. Results of our investigations indicate that the rate of degradation at the most heavily used sites exceeds the capacity of aeolian processes to reestablish natural landscapes. Therefore, careful management of float trjps is needed if these environments are to be maintained in a natural state rather than a “sand-box” state.  相似文献   
128.
ABSTRACT: The detection of change in a hydrologic varaible, particularly water quality, is a current problem. A method is presented for testing whether there has been a shift in the mean of a hydrologic variable based on the well established bivariate normal distribution theory. In this technique, the dependent, or target, and the independent, or control, variables are formed as weighted linear combinations of the mean values at a number of locations in a selected target and control area. The weighting factors are determined based on a mathematical programming technique which minimizes the conditional coefficient of variation thereby minimizing the number of observations required to detect a change of a preselected magnitude in the mean of the target area. The result is a situation where a savings in the number of observations required to detect a change is a consequence of adding more stations: the space-time tradeoff. Two applications of the technique are presented, the first using electrical conductivity (EC) data from two sets of river basins and the second using EC data from a set of basins as the target variable and annual discharge as the control. The results indicate that a significant savings in time can be achieved by using this method.  相似文献   
129.
130.
Landfills that generate too little biogas for economic energy recovery can potentially offset methane (CH4) emissions through biological oxidation by methanotrophic bacteria in cover soils. This study reports on the CH4 oxidation efficiency of a 10-year old landfill cap comprising a volcanic pumice soil. Surface CH4 and CO2 fluxes were measured using field chambers during three sampling intervals over winter and summer. Methane fluxes were temporally and spatially variable (?0.36 to 3044 mg CH4 m?2 h?1); but were at least 15 times lower than typical literature CH4 fluxes reported for older landfills in 45 of the 46 chambers tested. Exposure of soil from this landfill cover to variable CH4 fluxes in laboratory microcosms revealed a very strong correlation between CH4 oxidation efficiency and CH4/CO2 ratios, confirming the utility of this relationship for approximating CH4 oxidation efficiency. CH4/CO2 ratios were applied to gas concentrations from the surface flux chambers and indicated a mean CH4 oxidation efficiency of 72%. To examine CH4 oxidation with soil depth, we collected 10 soil depth profiles at random locations across the landfill. Seven profiles exhibited CH4 removal rates of 70–100% at depths <60 cm, supporting the high oxidation rates observed in the chambers. Based on a conservative 70% CH4 oxidation efficiency occurring at the site, this cover soil is clearly offsetting far greater CH4 quantities than the 10% default value currently adopted by the IPCC.  相似文献   
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