Black carbon and polycyclic aromatic hydrocarbon emissions from vehicles in the United States-Mexico border region: pilot study

The investigators developed a system to measure black carbon (BC) and particle-bound polycyclic aromatic hydrocarbon (PAH) emission factors during roadside sampling in four cities along the United States-Mexico border, Calexico/Mexicali and El Paso/Juarez. The measurement system included a photoacoustic analyzer for BC, a photoelectric aerosol sensor for particle-bound PAHs, and a carbon dioxide (CO2) analyzer. When a vehicle with measurable emissions passed the system probe, corresponding BC, PAH, and CO2 peaks were evident, and a fuel-based emission factor was estimated. A picture of each vehicle was also recorded with a digital camera. The advantage of this system, compared with other roadside methods, is the direct measurement of particulate matter components and limited interference from roadside dust. The study revealed some interesting trends: Mexican buses and all medium-duty trucks were more frequently identified as high emitters of BC and PAH than heavy-duty trucks or passenger vehicles. In addition, because of the high daily mileage of buses, they are good candidates for additional study. Mexican trucks and buses had higher average emission factors compared with U.S. trucks and buses, but the differences were not statistically significant. Few passenger vehicles had measurable BC and PAH emissions, although the highest emission factor came from an older model passenger vehicle licensed in Baja California.     

Inverse dependency of particle residence times in ponds to the concentration of phosphate, the limiting nutrient

234Th, a commonly used short-lived particle-reactive tracer in marine systems, was measured in three different holding pond series at the Rocky Flats Environmental Technology Site (RFETS), Colorado, along with its parent nuclide 238U, to determine steady-state residence times of particle-reactive actinides such as Pu, and of particles. Series B ponds, which received industrial effluent that includes ortho-phosphate (PO4) and actinides, differed from series A and C ponds, which did not. This difference was also evident in the calculated particle residence times, which were <1 day for the ponds B4 and B5, where PO4 concentrations were higher (1.4 and 1.8 mg/l), and 3 and 3.4 days for ponds A3 and C2, respectively, where ortho-phosphate concentrations were lower (<0.1 mg/l). Particle residence times thus showed an inverse relationship with the concentration of ortho-phosphate, the limiting nutrient in fresh water systems. The same relationship to the concentration of ortho-phosphate or any of the other nutrient elements was not evident for the residence times of dissolved 234Th, which ranged between 0.1 and 2 days. This can be attributed to higher concentrations of dissolved and particulate ligands with greater binding potential for actinides such as four-valent Th and Pu in ponds with higher ortho-phosphate concentrations. Regardless of actual ortho-phosphate concentration, however, at water residence (holding) times of 1 month in these ponds, particles and associated actinides would be expected to be completely removed from the pond water to sediments.     

Anaerobic biodegradability and methanogenic toxicity of key constituents in copper chemical mechanical planarization effluents of the semiconductor industry

Copper chemical mechanical planarization (CMP) effluents can account for 30-40% of the water discharge in semiconductor manufacturing. CMP effluents contain high concentrations of soluble copper and a complex mixture of organic constituents. The aim of this study is to perform a preliminary assessment of the treatability of CMP effluents in anaerobic sulfidogenic bioreactors inoculated with anaerobic granular sludge by testing individual compounds expected in the CMP effluents. Of all the compounds tested (copper (II), benzotriazoles, polyethylene glycol (M(n) 300), polyethylene glycol (M(n) 860) monooleate, perfluoro-1-octane sulfonate, citric acid, oxalic acid and isopropanol) only copper was found to be inhibitory to methanogenic activity at the concentrations tested. Most of the organic compounds tested were biodegradable with the exception of perfluoro-1-octane sulfonate and benzotriazoles under sulfate reducing conditions and with the exception of the same compounds as well as Triton X-100 under methanogenic conditions. The susceptibility of key components in CMP effluents to anaerobic biodegradation combined with their low microbial inhibition suggest that CMP effluents should be amenable to biological treatment in sulfate reducing bioreactors.     

Enhanced attenuation: Its place in the remediation of chlorinated solvents

The development and regulatory acceptance of monitored natural attenuation (MNA) as a remedial strategy has forever changed the field of environmental cleanup. MNA is continuing to develop but it is challenged by a lack of a clear definition for the appropriate application of the MNA strategy. This challenge has resulted in the lack of a significant record of restoration and site closure. Environmental professionals face challenges in providing guidance that addresses how to manage these sites when technologies, performance monitoring, and even environmental conditions are subject to further development, refinement, and/or altered perspectives. As our experience and institutional knowledge grows around the implementation of MNA, we have the opportunity to develop “second‐generation” management tools and procedures for optimizing sites utilizing MNA as a part of a comprehensive site management plan. This opportunity is the focus of the Enhanced Attenuation: Chlorinated Organics (EACO) Team of the Interstate Technology Regulatory Council (ITRC). The development of the “second‐generation” tools/procedures has included defining EA and evaluating, through the use of a national survey of state regulators, the experience with MNA and interest in EA. The results of these two efforts formed the basis for developing a framework that provides a “bridge” from active treatment to MNA. © 2007 Wiley Periodicals, Inc.     

Migration,markets, and mangrove resource use on Kosrae,Federated States of Micronesia

Kosrae, Federated States of Micronesia, is a prototype of an island economy prone to economic crowding. Average family size is large, the habitable land area is small, economic activity is limited, and household dependence on natural resources for fuel and food is high. We analyze how economic crowding--and its mitigation through trade and migration policies--affects mangrove resource use. A comparison of household survey data from 1996 and 2000 indicates that despite decreases in US aid and public-sector jobs, average household consumption of mangrove resources has not increased. Migration and remittances have allowed the purchase of imported fuel and building materials substituting for mangrove wood. Despite changing preferences and shifts toward import consumption, population growth and further declines in US financial support will likely cause aggregate demand for mangrove and upland wood to rise. Moreover, continued emigration may accelerate the export of mangrove crabs to off-island Kosraeans.     

The beauty and the beast: Some preliminary comparisons of ‘high’ versus ‘popular’ residential architecture and public versus architect judgments of same

This research examined differences between the features of ‘high’ and ‘popular’ style residential architecture and between responses to those styles by architects and non-architects. Forty slides (20 of each style) were scored in terms of physical properties. They were also rated by 20 architects and 20 non-architects. The research identified distinct physical features of each style. ‘High’ style residential architecture had fewer materials, more concrete, simpler forms, more white, and off-center entrances. They were judged as more complex, novel, and exciting. ‘Popular’ style residential architecture was characterized by use of more building materials, horizontal orientation, hip roofs, framed windows, centered entrances, and warm colors. Architects and non-architects differed in how they characterized and evaluated the two kinds of buildings, Architects rated the ‘high’ buildings as more clear, coherent pleasant, relaxing, and meaningful. Models of preference revealed that both groups favored novelty and coherence (or clarity), but the non-architects favored simplicity and ‘popular’ attributes, while the architects favored complexity and ‘high’ attributes.     

So far,so good: Up to now,the challenge–hindrance framework describes a practical and accurate distinction

There are many ways to categorize work‐related stressors, and in recent years, a common distinction in occupational health psychology is between stressors viewed as challenges versus hindrances. Is this a useful conceptualization that provides practical and theoretical implications for IO psychologists? As Kurt Lewin famously prescribed, “there is nothing so practical as a good theory,” and we discuss the challenge–hindrance framework as a developing theory that can be useful for researchers and practitioners. We note that some of the early thinking and development of the challenge–hindrance distinction relied on both resource and appraisal theories of stress. Overall, we find that the challenge–hindrance distinction can be viewed as a framework that is useful by producing interesting, valuable, and innovative research. Simply striving to find meaningful and useful categorizations of stressors can lead us to discover new insights into the occupational stress domain, and the challenge–hindrance categories have already spurred a great deal of research.     

The response of female Mountain White-crowned Sparrows to songs from their natal dialect and an alien dialect

Summary Female Mountain White-crowned Sparrows from Colorado were tested in a laboratory playback experiment to determine their response to male songs from their own natal dialect and to those from an alien dialect of the same subspecies, Zonotrichia leucophrys oriantha (Fig. 1). Observations were made on locomotor activity and copulation postures produced during each experimental test session.The subjects gave copulation displays almost exclusively when hearing their natal dialect and new or no displays when hearing the alien dialect (Fig. 2). The birds also exhibited significantly greater locomotor activity when hearing the natal dialect than they did when hearing the alien dialect (Fig. 3).We conclude that females are sensitized by their early song learning experience to be responsive to songs from their natal dialect and virtually sexually unresponsive to songs from an alien dialect. We speculate that the copulation posture given in the experiment implies that females in natural populations would preferably only mate assortatively with males from their natal dialect region.