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291.
Endocrine disrupting nonyl- and octylphenol in infant food in Germany: considerable daily intake of nonylphenol for babies 总被引:1,自引:0,他引:1
Nonylphenol and octylphenol are persistent endocrine disrupters that are priority substances of the European Union Water Framework Directive. Their presence in the environment has caused increasing concern about their impact to human health. Infants are more sensitive to hormonal impacts of environmental chemicals than adults. The results of the present study indicate that nonylphenol is ubiquitous in foodstuffs for babies and toddlers commercially available in Germany, while octylphenol could only be determined in 80% of all food samples. The daily intakes based on consumption studies in μg nonylphenol kg−1 body weight per day for high consumers in the baby category (0.23-0.65 μg kg−1 bw d−1) were relatively high. This could lead to a higher risk especially for babies. 相似文献
292.
Incorporation of in silico biodegradability screening in early drug development—a feasible approach?
Steger-Hartmann T Länge R Heuck K 《Environmental science and pollution research international》2011,18(4):610-619
Introduction
The concentration of a pharmaceutical found in the environment is determined by the amount used by the patient, the excretion and metabolism pattern, and eventually by its persistence. Biological degradation or persistence of a pharmaceutical is experimentally tested rather late in the development of a pharmaceutical, often shortly before submission of the dossier to regulatory authorities. 相似文献293.
Haifeng Zhang Klaus Guenther Sebastian Zuehlke 《Environmental pollution (Barking, Essex : 1987)》2009,157(6):1904-1910
The degradation of a chiral nonylphenol isomer, 4-(1-ethyl-1,4-dimethylpentyl)phenol (NP112), in two agricultural soils from Monheim and Dortmund, Germany has been studied. The degradation of NP112 and the formation of a nitro-nonylphenol metabolite were determined by means of GC-MS analysis. The degradation followed bi-exponential order kinetics, with half-life of less than 5 days in both soils. The nitro-metabolite was found at different concentration levels in the two soils. The nitro-metabolite of NP112 was more persistent than its parent compound. After 150 days about 13% of the initially applied NP112 remained in the Monheim soil as its nitro-metabolite. Results of the E-screen assay revealed that the nitro-NP112 has oestrogenic potency of 85% of that of NP112. Furthermore, the results of chiral GC-MS analysis revealed that no chiral degradation of NP112 occurred in this study. 相似文献
294.
In spite of broad and positive expectations, payments for ecosystem services (PES) can bring about unexpected and negative consequences, especially in terms of their impacts on the well-being of local communities dependent on ecosystems. Based on numerous observations of recurring problems with PES, we put forward an ecosystem service curse hypothesis (Kronenberg and Hubacek in Ecol Soc 18:art.10. doi: 10.5751/ES-05240-180110, 2013), that points to counterintuitive negative development outcomes for countries and regions rich in ecosystem services. The social and economic problems that we have been able to depict in many PES schemes reflect the persistence of maladaptive states in pursuit of sustainability. Instead of providing an opportunity to break out of poverty, these problems reflect entrapment, which is most often related to poor quality of institutions. Here we highlight the linkages between the ecosystem service curse hypothesis and the dynamic system stability landscapes discussed in this special issue. Our article consists of three parts in which we: (1) present the original ecosystem service curse hypothesis; (2) link this hypothesis to the broader discussions relevant to sustainability science; and (3) highlight the context of traps on which this special feature focuses. 相似文献
295.
Organic waste and municipal solid waste usually contain considerable amounts of different nitrogen compounds, which may inhibit anaerobic degradation processes and cause problems in the downstream and peripheral devices. This refers particularly to the different process stages of anaerobic digestion, to wastewater treatment, and to exhaust air treatment. Neither the knowledge about nitrogen problems nor the technologies for elimination of nitrogen compounds from the wastewater or the exhaust air of anaerobic digestion can be regarded as state-of-the-art. Most of the technologies in question have already been applied in other areas, but are barely tested for application in anaerobic digestion plants. The few performance data and experiences at hand were mainly derived from pilot and demonstration facilities. In this paper, the problem of nitrogen will be discussed in detail according to the separate problem fields based on the authors' experience, as well as on the basis of a review of the relevant literature. Furthermore, possible solutions will be proposed and the need for further research and development will be formulated. 相似文献
296.
Monitoring, assessment and modelling using water quality data in the Saale River Basin, Germany 总被引:1,自引:0,他引:1
Bongartz K Steele TD Baborowski M Lindenschmidt KE 《Environmental monitoring and assessment》2007,135(1-3):227-240
The European Water Framework Directive (WFD) is the overall driver for this environmental study and currently requires the
identification of patterns and sources of pollution (monitoring) to support objective ecological sound decision making and
specific measures to enhance river water quality (modelling). The purpose of this paper is to demonstrate in a case study
the interrelationship between (1) hydrologic and water quality monitoring data for river basin characterization and (2) modelling
applications to assess resources management alternatives. The study deals with monitoring assessment and modelling of river
water quality data of the main stem Saale River and its principal tributaries. For a period of 6 years the data, which was
sampled by Environmental Agencies of the German states of Thuringia, Saxony and Saxony-Anhalt, was investigated to assess
sources and indicators of pollution. In addition to the assessment a modelling exercise of the routing of different pollutants
was carried out in the lower part of the test basin. The modelling is a tool to facilitate the evaluation of alternative measures
to reduce contaminant loadings and improve ecological status of a water body as required by WFD. The transport of suspended
solids, salts and heavy metals was modelled along a selected Saale reach under strong anthropogenic influence in terms of
contaminants and river morphology between the city of Halle and the confluence with the Elbe River. The simulations were carried
out with the model WASP5 which is a dynamic flood-routing and water quality model package developed by the US Environmental
Protection Agency. 相似文献
297.
Kerstin Ulrich Sabine Wölfle Anja Mayer Klaus Heeg Thomas Braunbeck Lothar Erdinger Holger Bartz 《Environmental science and pollution research international》2010,17(6):1257-1267
Background, aim, and scope
Lungs are permanently and simultaneously challenged by airborne microorganisms and airborne pollutants. Temporal increase of airborne particulate matter (APM), a potential carrier for extractable organic matter (EOM), degrades the situation of pulmonary patients. The Ah receptor (AhR) has been described as an important factor influencing the immunological challenge by viral infections. Molecular mechanisms underlying epidemiological observations are not well understood. Cytokine secretion (IL-6, IL-8, and TGF-β) from human bronchial epithelial cells (Beas2B) was determined as an indicator for immune responses upon co-stimulation with an artificial analog of viral dsRNA [polyinosinic/polycytidylic acid, (PIC)] and EOM of Standard Reference Material 1649a (SRM). Since polycyclic aromatic hydrocarbons are major components of APM usually acting via the AhR, particular focus was on AhR involvement. 相似文献298.
Naresh?KumarEmail author Daisy?Ramirez-Ortiz Helena?M.?Solo-Gabriele Joseph?B.?Treaster Olveen?Carrasquillo Michal?Toborek Sapna?Deo Jim?Klaus Leonidas?G.?Bachas David?Whitall Sylvia?Daunert Jose?Szapocznik 《Environmental science and pollution research international》2016,23(3):2003-2013
Guánica Bay, located in southwestern Puerto Rico, has suffered oil spills and other pollution discharges since the 1960s. Previous research showed elevated concentrations of polychlorinated biphenyls (PCBs) in coral reef and sediment. This research examined PCB concentrations in sediment and fish. Sediment and fish sampling in the bay was facilitated by community members. This study identified the second highest reported PCB level (129,300 ng/g) in sediment in the USA. Fish samples also showed elevated concentrations (1623 to 3768 ng/g), which were higher than the thresholds of safe levels of PCBs in fish for human consumption. The alarmingly high concentration of PCBs calls for proactive community engagement to bring awareness about contamination of the bay and more extensive sampling to test for the concentration of PCBs in seafood and the people of Guánica. This study also underscores the value of the involvement of local communities during sampling design aimed at identifying hot spots of contaminants. 相似文献
299.
300.
Zhisheng Yao Xunhua Zheng Baohua Xie Chunyan Liu Baoling Mei Haibo Dong Klaus Butterbach-Bahl Jianguo Zhu 《Atmospheric environment (Oxford, England : 1994)》2009,43(11):1888-1896
Chamber techniques can easily be applied to field trials with multiple small plots measuring carbon- and nitrogen-trace gas fluxes. Nevertheless, such chamber measurements are usually made weekly and rarely more frequently than once daily. However, automatic chambers do allow flux measurements on sub-daily time scales. It has been hypothesized that sub-daily measurements provide more reliable results, as diurnal variations are captured better compared to manual measurements. To test this hypothesis we compared automatic and manual measurements of N2O, CO2 and CH4 fluxes from tilled and non-tilled plots of a rice–wheat rotation ecosystem over a non-waterlogged period. Our results suggest that both techniques, i.e., either manual or automatic chambers of N2O and CO2 emissions resulted in biased fluxes. The manual measurements were adequate to capture either day-to-day or seasonal dynamics of N2O, CO2 and CH4 exchanges, but overestimated the cumulative N2O and CO2 emissions by 18% and 31%, respectively. This was due to neglecting temperature-dependent diurnal variations of C and N trace gas fluxes. However, the automatic measurements underestimated the cumulative emissions of N2O and CO2 by 22% and 17%, respectively. This underestimation resulted from chamber effects upon soil moisture during rainfall processes. No significant difference was detected between the two methods in CH4 exchanges over the non-waterlogged soils. The bias of manual chambers may be significant when pronounced diurnal variations occur. The bias of automatic measurements can only be avoided/minimized if chamber positions are frequently changed and/or if chambers are automatically opened during rainfall events. We therefore recommend using automatic chambers together with continuous measurements of soil chamber moisture to allow for soil moisture correction of fluxes or to correct flux estimates as derived by manual chambers for possible diurnal variations. 相似文献