秦皇岛市空气质量分析与改善对策

秦皇岛市从1998年5月29日至1999年2月25日空气污染指数平均为84.92,首要污染物是总悬浮微粒(TSP),空气质量Ⅱ级,属良好范围,在北方城市中仅次于大连和烟台。影响秦皇岛市空气质量的不利因素有煤炭运输规模大、建筑工地及城市卫生管理不严、绿地分布不合理、集中供热规模偏小等。为此,应继续治理煤尘,实行热电连产,改进绿化,加强管理。     

Transformation of erythromycin during secondary effluent soil aquifer recharging: Removal contribution and degradation path

Erythromycin (ERY), a widely used antibiotic, has recently been detected in municipal secondary effluents and poses serious threats to human health during wastewater reusing. In this study, the removal, fate, and degradation pathway of ERY in secondary effluent during soil aquifer treatment was evaluated via laboratory-scale SAT tests. Up to a 92.9% reduction of ERY in synthetic secondary effluent was observed in 1.0 m depth column system, which decreased to 64.7% when recharged with wastewater treatment plant secondary effluent. XRD-fractionation results demonstrated that the transphilic acid and hydrophobic acid fractions in secondary effluent compete for the adsorption sites of the packed soil and lead to a declined ERY removal. Moreover, aerobic biodegradation was the predominant role for ERY removal, contributing more than 60% reduction of ERY when recharged with synthetic secondary effluent. Destruction of 14-member macrocyclic lactone ring and breakdown of two cyclic sugars (l-cladinose and d-desosamine) were main removal pathways for ERY degradation, and produced six new intermediates.     

Floating particles with high copper concentration in the sea-surface microlayer

This study sought to clarify whether suspended particles containing high Cu concentrations are present in the sea-surface microlayer (S-SML). For this reason, suspended particles (10–2000 μm) in the S-SML were collected periodically from a ship mooring pond during 2018–2020, and the acid-soluble Cu concentration in the suspended particles was measured as particulate Cu (P-Cu). The highest concentration of P-Cu in the S-SML of the pond was 75 μg L^?1 with a 90th percentile value of 2.5 μg L^?1. This is below P-Cu values reported for the S-SML in North American ports, but 140 times higher than this found in bulk seawater in the Atlantic Ocean. The highest P-Cu concentration in the S-SML of non-organism (abiotic) origin was 17 μg L^?1, and the abiotic P-Cu to P-Cu ratio varied from 0.2 to 100%, likely depending on the quality and quantity of biogenic material in the S-SML samples. It is assumed that the S-SML particles examined here contain high Cu concentrations originating from ship antifouling paints.

     

折流式水解反应器处理印染废水水温影响研究

在水温为5℃、9.7℃、14.9℃、19.7℃、23.5℃和31.1℃6种温度的条件下,应用折流式水解反应器对印染废水进行水解试验研究.结果表明,提高水温可增大COD、色度及UVA254的去除效率,相应的ORP值变小,pH值升高,水解程度加深.水温5℃时,水解效果较差;水温在10～23.5℃内,水解效果相对较好,31.1℃水解效果最好,研究结果能为工程应用提供一定的参考.     

Characterization of particle size distribution of mainstream cigarette smoke generated by smoking machine with an electrical low pressure impactor

Cigarette smoking is a particle-related exposure. Studying the characteristics of the particle size distribution of cigarette smoke can aid in providing knowledge of smoke aerosol attributes. We used an electrical low pressure impactor （ELPI） to measure the particle size distribution of mainstream cigarette smoke generated by a smoking machine and provided a continuum of particle sizes of cigarette smoke from a whole cigarette. The results showed that the aerodynamic diameters （D, geometric mean of a channel） of particles ranged from 0.021 to 1.956 ~m, and the number concentrations were on the order of 105-109 cm-3 for different sizes of particles. The particle number of the size category below 0.1 p,m approximated that of the category 0.1-2.0 Ixm, and the particles in the size category of 0.1-2.0 μm contributed extremely heavily to total particulate mass. In addition, the results with small samples indicated that the tar yields normalized per milligram of nicotine showed an approximately linear increase with increasing concentration of total particles.     

不封底PCC能量桩与传统能量桩换热效率对比研究

PCC能量桩是一种基于PCC桩的新型能量桩技术,目前针对PCC能量桩在制冷和供热过程中的换热效率及热传导特性的研究仍相对较少。基于模型试验方法,开展循环温度作用下不封底PCC能量桩、传统能量桩的温度响应测试,实测获得桩身、桩周土热响应变化规律;继而,结合数值模拟方法,对比分析进/出水温度等因素对不封底PCC能量桩换热效率的影响规律。研究结果表明,本文试验条件下,夏季制冷模式下不封底PCC能量桩的热响应略大于传统能量桩,而冬季供热模式下差异不大;相同条件下,夏季制冷模式下不封底PCC能量桩的换热效率较传统能量桩高出24%,而冬季供热模式下仅高7%。