Uptake of oxytetracycline and its phytotoxicity to alfalfa (Medicago sativa L.)

A series of experiments were conducted in a hydroponic system to investigate the uptake of oxytetracycline (OTC) and its toxicity to alfalfa (Medicago sativa L.). OTC inhibited alfalfa shoot and root growth by up to 61% and 85%, respectively. The kinetics of OTC uptake could be well described by Michaelis-Menten equation with Vmax of 2.25 micromol g-1 fresh weight h-1, and Km of 0.036 mM. The uptake of OTC by alfalfa was strongly inhibited by the metabolic inhibitor, 2,4-DNP (2,4-dinitrophenol), at pH 3.5 and 6.0, but not by the aquaporin competitors, glycerol and Ag+. OTC uptake, however, was significantly inhibited by Hg2+, suggesting that the inhibition of influx was due to general cellular stress rather than the specific action of Hg2+ on aquaporins. Results from the present study suggested that OTC uptake into alfalfa is an energy-dependent process.     

Regression method of the hydrophobicity ruler approach for determining octanol/water partition coefficients of very hydrophobic compounds

A regression method was developed for the hydrophobicity ruler approach, which is an indirect method for determining the octanol/water partition coefficients of very hydrophobic compounds. Two constants introduced into the mathematical model were obtained by regression of the absorption data sampled before the partition equilibrium. A water miscible organic solvent was used to increase the solubility of the very hydrophobic compounds in the aqueous solution so that the hydrophobicity scale was reduced and the equilibration was accelerated. Polydimethylsiloxane/methanol aqueous solution and a series of 21 polychlorinated biphenyls (PCBs) were used to demonstrate the regression method. The PCB compounds with known experimental logK(o/w) values served as reference compounds, while the PCB compounds without known logK(o/w) values were determined. The distribution coefficients (logK(p/s)), uptake and elimination rate constants were obtained from the two regression constants for each compound (reference or unknown). The correlation of the logK(p/s) values of the reference PCB compounds with their logK(o/w) values was linear (logK(o/w)=2.69logK(p/s)+0.76, R(2)=0.97). The logK(o/w) values were compared with literature values and suggested that some values from the literature far off the calibration line could be inaccurate. The critical experimental factors, the merits of the regression method were discussed.     

Temporal dynamics of microcystins in two reservoirs with different trophic status during the early growth stage of cyanobacteria

Environmental Science and Pollution Research - Harmful cyanobacterial blooms are increasing in frequency and severity, which makes their toxic secondary metabolites of microcystins (MCs) have been...     

Correction to: Floating particles with high copper concentration in the sea-surface microlayer

Environmental Science and Pollution Research - A Correction to this paper has been published: https://doi.org/10.1007/s11356-021-14518-w     

Trend reversal from source region to remote tropospheric NO2 columns

Environmental Science and Pollution Research - Global tropospheric nitrogen dioxide (NO2) changes have different or even opposite impacts on the photochemical formation of ozone in different...     

The influence of carbon emission disclosure on enterprise value under ownership heterogeneity: evidence from the heavily polluting corporations

Environmental Science and Pollution Research - Under the background that China puts forth the goals of “Emission Peak” and “Carbon Neutrality”, heavily polluting...     

Photocatalytic degradation of organic pollutants in water by N-doping ZnS with Zn vacancy: enhancement mechanism of visible light response and electron flow promotion

Environmental Science and Pollution Research - In order to improve the visible light response, N-doping ZnS (N-ZnS) nanospheres with Zn vacancy and porous surface were prepared by a simple one-pot...     

Impact of δ-MnO2 on the chemical speciation and fractionation of Cr(III) in contaminated soils

Environmental Science and Pollution Research - Oxidation of Cr(III) by birnessite (δ-MnO2) was an important geochemical reaction determining the toxicity and mobility of dissolved Cr(III) in...     

基于形态空间格局分析方法和最小累积阻力模型的北京市平原区造林工程生态格局分析

为了科学评估北京市平原区造林工程的生态影响，利用高分卫星数据获取2018—2020年北京市平原区造林面积、分布及变化信息，分析了造林工程的空间格局特征，并采用形态空间格局分析(MSPA)方法及最小累积阻力(MCR)模型，构建了北京市平原区生态网络，通过情景模拟分析造林工程对生态源地、生态廊道产生的影响。结果显示，2018—2020年北京市平原区造林工程主要沿西北东南方向实施，实现了对原有林地资源分布不均衡问题的解决。热点建设区域为北部的延庆及东南部的通州、大兴，呈现由城市边界逐步向市中心蔓延的发展趋势。在不考虑其他因素对土地利用的影响的前提下，造林工程的实施使平原区林地面积增长了9.8%。通过情景模拟发现，造林工程的实施使生态网络向连通、完整、均衡方向发展。其中，生态源地面积增长了131.0 km²,主要生态源地连通性提升了41.1%,生态廊道的分布由主要分布在西北部山区向西北、东南两个方向均有密集分布转变。综上，造林工程的生态环境效应显著，造林工程的实施对生态环境质量改善具有重要意义。