Elemental uptake by edible herbs and lettuce (Latuca sativa)

The total concentration of toxic elements (aluminum, cadmium, chromium and lead) and selected macro and micro elements (iron, manganese, copper and zinc) are reported in six leafy edible vegetation species, namely lettuce, spinach, cabbage, chards and green and red types of Amaranth herbs. Although spinach and chards had greater than 125 mv of iron, both the amaranthus herbs recorded > than 320 μ g g^{? 1} dry weight. In both the spinach and chard species, the Mn and Zn levels were appreciable recording > 225 μ g g^{? 1} and 150 μ g g^{? 1} dry weight, respectively. Aluminum concentrations were (in μ g g^{? 1} dry weight) lettuce (10), cabbage (11), spinach (167), chards (65), amaranthus green (293) and amaranthus red (233). All the micro and macro elements and the toxic elements (Ni, Cr, Cd and Pb) elements analyzed, were below the recommended maximum permitted levels (RMI) in vegetables. Further the elemental uptake and distribution of the nine elements, at three growth stages of the lettuce plant grown on soil bed under controlled conditions are detailed. In the soil, except for iron (16%), greater than 33% of the other cations were in exchangeable form. Generally in the lettuce plant, roots retained much of the iron (> 224 μ g g^{? 1}) and aluminum (> 360 μ g g^{? 1}), while leaves had less than 200 μ g g^{? 1} of iron and 165 μ g g^{? 1} of Al. Although the concentrations of elements marginally decreased with growth, the lettuce leaves had significant amounts of Mn (30 μ g g^{? 1}), Zn (50 μ g g^{? 1}) and Cu (3.6 μ g g^{? 1}). Some presence of lead in leaves (2.0 μ g g^{? 1}) was noticed, but all the toxic and other elements analyzed were well below the RMI values for the vegetables.     

Ageing of chromium(III)-bearing slag and its relation to the atmospheric oxidation of solid chromium(III)-oxide in the presence of calcium oxide

Slag arising in ferrochromium and stainless steel production is known to contain residual levels of trivalent chromium. As the chromium is normally bound in the slag matrix in various silicate or spinel phases, and hence not easily mobilised, utilisation or controlled disposal of such slag is generally considered unproblematic. Experimental test work with a number of slag materials indicates, however, that very gradual oxidation of trivalent to hexavalent chromium does occur when the slag is exposed to atmospheric oxygen, rendering a quantifiable but small portion of chromium in this much more mobile and toxic form. Mechanisms and rates of the oxidation reaction were investigated in a number of long-term studies using both original slag materials and artificial mixes of chromium and calcium oxides. Powders of these materials, some of them rolled into balls, were left to age under different conditions for periods of up to 12 months. In the slag samples, which contained between 1 and 3 wt.% chromium, 1000–10 000 μg Cr(VI) were found per gram of chromium within 6–9 months of exposure to an ambient atmosphere. The rate of the oxidation reaction decreased exponentially, and the reaction could generally be said to have ceased within 12 months. In mixtures of calcium and chromium oxides the oxidation reaction is presumed to occur at the boundaries between chromium oxide and calcium oxide phases through diffusion of oxygen along the grain boundaries and of Cr³⁺ across the boundaries, resulting in the formation of calcium chromate. In the slags, where calcium and chromium oxide can form a solid solution, the oxidation is likely to occur at the exposed surface of grains containing this solution.     

Assessment of physico-chemical qualities and heavy metal concentrations of Umgeni and Umdloti Rivers in Durban,South Africa

We assessed the effects of seasonal dynamics on the physico-chemical qualities and heavy metals concentrations of the Umgeni and Umdloti Rivers in Durban, South Africa. Water samples were taken from nine different sampling points and analysed for the following parameters; temperature, pH, turbidity, electrical conductivity (EC), biological oxygen demand (BOD₅), chemical oxygen demand (COD), phosphate (PO₄ ^2?), nitrate (NO₃ ^2?), ammonium (NH₄ ⁺), sulphate (SO₄ ^2?), lead (Pb²⁺), mercury (Hg²⁺), cadmium (Cd²⁺), aluminium (Al³⁺), and copper (Cu²⁺) using standard methods. The data showed variations it terms of the seasonal fluctuations and sampling regime as follows: temperature 12–26.5 °C; pH 5.96–8.45; turbidity 0.53–18.8 NTU; EC 15.8–5180 mS m^?1; BOD₅ 0.60–7.32 mg L^?1; COD 10.5–72.9 mg L^?1; PO₄ ^2??<?500–2,460 μg L^?1; NO₃ ^2? <0.05–4.21 mg L^?1; NH₄ ⁺?<?0.5–1.22 mg L^?1; SO₄ ^2? 3.90–2,762 mg L^?1; Pb²⁺ 0.023–0.135 mg L^?1; Hg²⁺ 0.0122–0.1231 mg L^?1 Cd²⁺ 0.068–0.416 mg L^?1; Al³⁺ 0.037–1.875 mg L^?1, and Cu²⁺0.006–0.144 mg L^?1. The concentrations of most of the investigated parameters exceeded the recommended limit of the South African Guidelines and World Health Organization tolerance limits for freshwater quality. We conclude that these water bodies are potentially hazardous to public health and this highlights the need for implementation of improved management strategies of these river catchments for continued sustainability.     

Carbon footprint analysis for increasing water supply and sanitation in South Africa: a case study

This study investigates the environmental burdens due to the provision of potable water and sanitation in the eThekwini Municipality (Durban), South Africa. This was achieved by employing LCA studies for the individual parts of the urban water system (impoundment, water treatment, distribution, collection, sewage treatment and water recycling). Based on the results of the individual LCAs a base case was constructed.For the provision of potable water and sanitation to new customers, which have not been previously served, two different scenarios (200 000 new customers in an urban environment with waterborne sewage and in a peri-urban environment with on-site sanitation) and three different options (maximising use of existing assets, recycling water and building new infrastructure) were considered and analysed. With regard to the impact scores calculated for both scenarios (urban and peri-urban), the recycling of water is followed by maximising the use of existing assets as the most environmentally friendly options. The construction of new infrastructure carries a higher environmental burden and the use of bottled water for drinking (an additional scenario) carries the highest environmental burden.     

Carboxymethyl cellulose thiol-imprinted polymers:Synthesis,characterization and selective Hg(Ⅱ) adsorption

Sulfur containing ion imprinted polymers(S-IIPs) were applied for the uptake of Hg(Ⅱ) from aqueous solution. Cysteamine which was used as the ligand for Hg(Ⅱ) complexation, was grafted along the epichlorohydrin crosslinked carboxylated carboxymethyl cellulose polymer chain through an amide reaction. The adsorption ability of S-IIPs towards Hg(Ⅱ)was investigated by kinetic and isotherm models, which, corresponding, showed that the adsorption process followed a pseudo-second-order, fitted well with the Langmuir isotherm with a maximum adsorption capacity of 80 mg/g. Moreover, thermodynamic studies indicated an endothermic and spontaneous reaction with the tendency of an enhanced randomness at the surface of the S-IIPs with temperature increases. S-IIPs indicated a high degree of selectivity towards Hg(Ⅱ) in the presence of Cu~(2+), Zn~(2+), Co~(2+), Pb~(2+)and Cd~(2+).Furthermore, the efficiency of S-IIPs was also evaluated against real samples showing86.78%, 91.88%, and 99.10% recovery for Hg(Ⅱ) wastewater, ground water and tap water,respectively. In this study, the adsorbent was successfully regenerated for five cycles, which allows for their reuse without significant loss of initial adsorption capability.     

Comparing community structure on shells of the abalone Haliotis midae and adjacent rock: implications for biodiversity

This paper concerns the effects on biodiversity of depletion of the South African abalone Haliotis midae, which is a long-lived species with a large corrugated shell that provides a habitat for diverse benthic organisms. We compared community structure on H. midae shells with that on adjacent rock at three sites (Cape Point and Danger Point sites A and B) and at two different times of the year at one of these sites. Shells of H. midae consistently supported communities that were distinctly different from those on rock. In particular, three species of non-geniculate (encrusting) corallines, Titanoderma polycephalum, Mesophyllum engelhartii and Spongites discoideus, were all found either exclusively or predominantly on shells, whereas another non-geniculate coralline, Heydrichia woelkerlingii, occurred almost exclusively on adjacent rock. The primary rocky substratum, however, supported a higher number of species than abalone shells. Possible reasons for the differences between the two substrata include the relative age, microtopography and hardness of the substrata; the abundance of grazers on them; and the relative age of different zones of the abalone shell, which support communities at different stages of succession. Diversity on shells was lowest in zones that were either very young or very old, in keeping with the intermediate disturbance hypothesis. The distinctiveness of shell epibiota will increase β diversity despite having a lower α diversity than that of adjacent rock. Decimation of H. midae by overfishing therefore has implications for biodiversity conservation.