改性丝瓜络纤维对水体日落黄的吸附特性

采用化学改性的方法将丝瓜络制备为阴离子吸附剂,并将其用于水体日落黄(SY)染料的吸附,分别考察了吸附剂的用量、日落黄染料的初始浓度(C0)、pH值、温度(K)、时间(T)5个因素对吸附效果的影响。通过模拟吸附等温曲线、吸附动力学以及热力学方程并通过比表面积(BET)和红外光谱(FTIR)分析改性丝瓜络吸附染料前后和丝瓜络改性前后的变化情况以此探究其吸附机理。结果表明,pH对吸附效果影响不明显;最大吸附量随温度升高而增大,在298 K温度时最大吸附量达到137 mg/g,是未改性丝瓜络的9.78倍。Langmuir方程拟合吸附过程描述最好,吸附类别为化学吸附。吸附过程符合伪二级动力学,是一个自发和吸热的过程。改性丝瓜络可以有效去除水体中的日落黄染料。     

新发展阶段我国企业水信息披露评价研究

推动绿色发展,促进人与自然和谐共生是我国社会主义建设新时期的重点方向与方略。绿水青山就是金山银山,水信息披露作为治理企业水污染的首要环节、重要手段,在国内还未充分引起企业与有关部门的重视。本文通过构建中国上市公司水信息披露指标体系,弥补了我国多年来在水信息披露评价体系中的不足。基于该指标体系,结合三维度打分法、层次分析法和内容分析法,本研究人工搜集整理既往企业水信息并从披露整体情况、披露水平以及披露内容三个方面分析了我国上市企业水信息披露现状。结果表明,现阶段我国企业水信息披露还存在披露程度低、披露差异明显、披露内容可靠性不强等问题,其根源来自政府政策滞后、社会面监督不充分、企业战略缺失等因素。为此,本文从健全水信息披露框架、完善法律制度、落实法律监督、建立新闻发布制度、引导金融机构参与等方面为推动企业水信息披露提供建议。     

我国应急管理的发展现状与未来路径分析

2003年非典过后,我国应急管理"一案三制"体系正式提出并逐步构建,随后应急管理体系得到迅速完善,但总体来看还是"摸着石头过河".十八大后,习总书记提出国家总体安全观、防范和化解重大风险等重大战略安排和制度选择;十九大以来,国家机构改革组建应急管理部、召开十九届四中全会,明确提出要实现应急管理体系和能力现代化,为应急管...     

络合剂对铬污染土壤电动修复作用的影响

用电动方法对铬污染砂土的修复进行了实验室研究。结果表明,EDTA和柠檬酸的加入明显改变了电动过程中电流的大小和铬在砂土中的分配,柠檬酸因与C(rⅥ)发生明显的竞争吸附或与土壤中的C(rⅢ)发生较强的络合作用而增加土壤总铬的迁移率,迁移到阳极附近的铬占砂土中铬含量的78.4%,电动处理以后土壤中剩余的六价铬浓度均显著减少,尤其是加入络合剂后的迁移率比不加入约提高40%,充分表明电动处理时加入络合剂可明显增加对砂土中六价铬的迁移。     

太湖流域面源污染控制对策研究

近年来.随着点源污染得到逐步治理,面源污染已成为水体富营养化的主要污染源,本文介绍了太湖流域面源 污染的现状,分析了其构成,列举了国内外目前治理面源污染的一些措施,并就太湖流域面源污染的特点提出了一些控制 治理对策。     

我国核电发展现状浅析

核电作为一种安全的清洁能源,对于优化能源结构、减少环境污染、具有重要意义。本文介绍了我国核电的现状,从安全性、环保性、经济性几方面对核电进行分析比较,说明积极推进核电发展是我国未来电力发展的选择。     

Numerical model to quantify biogenic volatile organic compound emissions: The Pearl River Delta region as a case study

This article compiles the actual knowledge of the biogenic volatile organic compound (BVOC) emissions estimated using model methods in the Pearl River Delta (PRD) region, one of the most developed regions in China. The developed history of BVOC emission models is presented briefly and three typical emission models are introduced and compared. The results from local studies related to BVOC emissions have been summarized. Based on this analysis, it is recommended that local researchers conduct BVOC emission studies systematically, from the assessment of model inputs, to compiling regional emission inventories to quantifying the uncertainties and evaluating the model results. Beyond that, more basic researches should be conducted in the future to close the gaps in knowledge on BVOC emission mechanisms, to develop the emission models and to refine the inventory results. This paper can provide a perspective on these aspects in the broad field of research associated with BVOC emissions in the PRD region.     

有机固体废弃物堆肥的腐熟度参数及指标

腐熟度参数及其指标是评价堆肥过程及堆肥产品质量的重要尺度,本文综述了关于腐熟度的表观分析法、化学分析法、波谱分析法及植物生长分析法等４类评价方法和各种腐熟度参数及指标。     

厌氧-好氧法治理中药废水研究

厌氧—好氧法处理中药废水 ,污泥中生物相丰富 ,原生、后生动物数量多 ,污泥沉降性能优良 ,出水水质好 ,CODCr、BOD5 等指标都达到了一级排放标准。     

Applying a new method for direct collection,volume quantification and determination of N2 emission from water

The emission of N2 is important to remove excess N from lakes, ponds, and wetlands. To investigate the gas emission from water, Gao et al.(2013) developed a new method using a bubble trap device to collect gas samples from waters. However, the determination accuracy of sampling volume and gas component concentration was still debatable. In this study, the method was optimized for in situ sampling, accurate volume measurement and direct injection to a gas chromatograph for the analysis of N2 and other gases. By the optimized new method, the recovery rate for N2 was 100.28% on average; the mean coefficient of determination(R2) was 0.9997; the limit of detection was 0.02%. We further assessed the effects of the new method, bottle full of water, vs. vacuum bag and vacuum vial methods, on variations of N2 concentration as influenced by sample storage times of 1,2, 3, 5, and 7 days at constant temperature of 15°C, using indices of averaged relative peak area(%) in comparison with the averaged relative peak area of each method at 0 day.The indices of the bottle full of water method were the lowest(99.5%–108.5%) compared to the indices of vacuum bag and vacuum vial methods(119%–217%). Meanwhile, the gas chromatograph determination of other gas components(O2, CH4, and N2O) was also accurate. The new method was an alternative way to investigate N2 released from various kinds of aquatic ecosystems.