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841.
Enhui Wu Daifeng Lin Yinye Chen Xiaoshan Feng Kui Niu Yongjin Luo Baoquan Huang Jianbin Qiu Qingrong Qian Qinghua Chen 《环境科学学报(英文版)》2022,34(6):79-89
A series of nitrogen-doped CoAlO (N-CoAlO) were constructed by a hydrothermal route combined with a controllable NH3 treatment strategy. The effects of NH3 treatment on the physico-chemical properties and oxidation activities of N-CoAlO catalysts were investigated. In comparison to CoAlO, a smallest content decrease in surface Co3+ (serving as active sites) while a largest increased amount of surface Co2+ (contributing to oxygen species) are obtained over N-CoAlO/4h among the N-CoAlO catalysts. Meanwhile, a maximum N doping is found over N-CoAlO/4h. As a result, N-CoAlO/4h (under NH3 treatment at 400°C for 4 hr) with rich oxygen vacancies shows optimal catalytic activity, with a T90 (the temperature required to reach a 90% conversion of propane) at 266°C. The more oxygen vacancies are caused by the co-operative effects of N doping and suitable reduction of Co3+ for N-CoAlO/4h, leading to an enhanced oxygen mobility, which in turn promotes C3H8 total oxidation activity dominated by Langmuir-Hinshelwood mechanism. Moreover, in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTs) analysis shows that N doping facilities the decomposition of intermediate species (propylene and formate) into CO2 over the catalyst surface of N-CoAlO/4h more easily. Our reported design in this work will provide a promising way to develop abundant oxygen vacancies of Co-based catalysts derived from hydrotalcites by a simple NH3 treatment. 相似文献
842.
水稻土被广泛认为是甲烷(CH4)和氧化亚氮(N2O)主要排放源,深入研究不同水肥管理条件下热带地区双季稻田CH4和N2O的排放特征,对补充我国双季稻田温室气体排放研究的不足意义重大.本研究设置8个处理:常规灌溉-施磷钾肥(D-PK)、常规灌溉-施氮磷钾肥(D-NPK)、常规灌溉-施氮磷钾+有机肥(D-NPK+M)、常规灌溉-施有机肥(D-M)、长期淹水-施磷钾肥(F-PK)、长期淹水-施氮磷钾肥(F-NPK)、长期淹水-施氮磷钾+有机肥(F-NPK+M)和长期淹水-施有机肥(F-M).采用密闭静态箱-气相色谱法测定双季稻田CH4和N2O排放量,测定水稻产量和估算全球增温潜势(GWP)及温室气体排放强度(GHGI).结果表明:①早稻季和晚稻季CH4累积排放量分别为10.3~78.9 kg·hm-2和84.6~185.5 kg·hm-2.与F-PK和F-NPK处理相比,早稻季F-NPK+M和F-M处理显著增加CH4累积排放量.同一施肥条件下,长期淹水处理CH4累积排放量高于常规灌溉处理.灌溉和施肥极显著影响早稻季CH4累积排放量.②早稻季和晚稻季N2O累积排放量分别为0.18~0.76 kg·hm-2和0.15~0.58 kg·hm-2.与F-PK处理相比,早稻季F-NPK处理N2O累积排放量显著增加;与D-PK相比,D-NPK、D-NPK+M和D-M处理显著增加N2O累积排放量.与F-PK相比,晚稻季长期淹水其它处理N2O累积排放量显著增加;与D-PK处理相比,D-NPK和D-M处理N2O累积排放量显著增加.施肥极显著影响早稻季N2O排放;灌溉和施肥极显著影响晚稻季N2O排放.③早稻和晚稻产量分别为7310.7~9402.4 kg·hm-2和3902.8~7354.6 kg·hm-2,且F-NPK和F-M处理下早稻产量显著高于F-PK和D-NPK、D-PK和D-NPK处理.与PK处理相比,同一灌溉条件下其余3种施肥处理均显著增加晚稻产量.早稻季GWP和GHGI分别为580.8~2818.5kg·hm-2和0.08~0.30 kg·kg-1.与F-PK处理相比,常规灌溉条件下早稻季各施肥处理间GWP无显著性差异;但长期淹水条件下F-NPK+M和F-M处理GWP均显著增加.早稻季F-NPK+M和F-M处理GHGI显著高于其它处理.晚稻季GWP和GHGI分别为3091.6~6334.2 kg·hm-2和0.50~1.23 kg·kg-1.灌溉显著影响早稻和晚稻季GWP和GHGI,施肥对晚稻季GWP和GHGI的影响不显著.④土壤NH4+-N含量和5 cm土温均与CH4排放呈极显著负相关,pH与CH4排放呈极显著正相关,但与N2O排放呈显著负相关.土壤NH4+-N和NO3--N含量与N2O排放呈极显著负相关.综合作物产量、GWP和GHGI考虑,D-NPK+M可推荐为当地最优的减排稳产的水肥管理模式. 相似文献
843.
844.
Kailin Xu Li Jiao Chuqiao Wang Yiming Bu Yuling Tang Liwei Qiu Qiuya Zhang Liping Wang 《环境科学学报(英文版)》2022,34(1):93-103
Nonylphenol(NP) residues, as a typical endocrine disrupting chemical(EDC), frequently exist in sewage, surface water, groundwater and even drinking water, which poses a serious threat to human health due to its bioaccumulation. In order to remove NP, a series of MIL-100(Fe)/Zn Fe2O4/flake-like porous carbon nitride(MIL/ZC) was synthesized through in-situ synthesis at room temperature. High performance of ternary MIL/ZC is used to degrade NP under visible light irradiation. ... 相似文献
845.
Guilin Han Yang Tang Qixin Wu Qiu Tan 《Atmospheric environment (Oxford, England : 1994)》2010,44(2):174-181
Strontium isotope ratios and concentrations of Ca2+, NH4+, Na+, K+, Mg2+, Cl?, SO42?, NO3? and Al3+, Sr2+ were measured for 52 rainwater samples collected in virgin forest in a rural region between May 2007 and Dec. 2008. The rainwater pH values vary from 4.1 to 7.2 with a volume weight mean (VWM) value of 5.40. 40 of 52 samples have pH value above 5.0, indicating that the regional rainwater was not acidic. Among anions and cations, sulphate concentration (40.4 μeq l?1, VWM) is the highest in the rainwater, followed by ammonium and calcium (30.2 and 20.8 μeq l?1, VWM). Rainwater quality is characterized by low salinity and neutralized pH.The chemical compositions and 87Sr/86Sr ratios of the rainwater samples vary considerably. Using Na+ concentration as an indicator of marine origin, the proportions of sea salt and crustal elements were estimated from elemental ratios. The 87Sr/86Sr ratios were used to characterize different sources base on the data sets of this study and those from literatures. Such sources include weathering of limestone (87Sr/86Sr = 0.7075), remote soil dust (87Sr/86Sr > 0.7135) and anthropogenic source (fertilizers: 87Sr/86Sr = 0.7079). The results of the present study suggest that one likely source for high ammonium and calcium concentration is local soil. Due to a large contribution of these cations to the sulphate neutralization action, the rainwater in this region displays non-acidity, and thus has not significant environmental impact. The wet precipitation in the karst virgin forest in Guizhou province is strongly influenced by natural sources rather than anthropogenic sources. 相似文献
846.
XQH1.00地震安全性评价工作程序包具先进性、灵活性、可靠性和实用性。编制者对危险性分析、人造地震动和土层反应等主要程序作了一系列改进,使之具有较强的计算性能。其中,人造地震动采用了自己研究提出的新技术——即时域迭加技术和反应谱整体逼近技术。该软件包采用菜单方式,实行人机对话和各种表格图件全部汉化。图件的输出可使用打印机和绘图仪,具有优良的服务性能。 相似文献
847.
钢铁冶金行业生产会产生大量的高炉渣。高炉渣由于自身温度比较高,含热量丰富,对能源工业来说是一种很好的二次资源。世界上已有一些国家对高炉渣热量的回收利用进行了一定的研究,而国内这方面的研究却很少。详细介绍了近几年国内外对高炉渣热量回收利用的情况,在此基础上,阐述了高炉渣热回收技术需要解决的关键问题和发展趋势。 相似文献
848.
849.
生物化学协同除磷研究 总被引:7,自引:0,他引:7
采用聚合硅酸铝和聚合硅酸铁两种混凝剂,比较了将混凝剂直接投加到反应器中和对生物反应器出水再进行混凝沉淀2种工艺的除磷效果,并对2种混凝剂的除磷效果进行了比较。结果表明:对于聚合硅酸铝,没有生物协同作用;对于聚合硅酸铁,投加量在40mg/L以下时具有生物协同作用,30mg/L时协同作用最明显;而且聚合硅酸铁的除磷效果好于聚合硅酸铝。 相似文献
850.