全文获取类型
收费全文 | 1011篇 |
免费 | 23篇 |
国内免费 | 12篇 |
专业分类
安全科学 | 53篇 |
废物处理 | 63篇 |
环保管理 | 203篇 |
综合类 | 95篇 |
基础理论 | 230篇 |
污染及防治 | 268篇 |
评价与监测 | 91篇 |
社会与环境 | 36篇 |
灾害及防治 | 7篇 |
出版年
2023年 | 14篇 |
2022年 | 11篇 |
2021年 | 15篇 |
2020年 | 17篇 |
2019年 | 21篇 |
2018年 | 21篇 |
2017年 | 26篇 |
2016年 | 23篇 |
2015年 | 24篇 |
2014年 | 33篇 |
2013年 | 156篇 |
2012年 | 51篇 |
2011年 | 53篇 |
2010年 | 30篇 |
2009年 | 43篇 |
2008年 | 48篇 |
2007年 | 58篇 |
2006年 | 41篇 |
2005年 | 35篇 |
2004年 | 32篇 |
2003年 | 31篇 |
2002年 | 31篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 11篇 |
1998年 | 15篇 |
1997年 | 12篇 |
1996年 | 11篇 |
1995年 | 6篇 |
1994年 | 14篇 |
1993年 | 12篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 5篇 |
1976年 | 4篇 |
1958年 | 2篇 |
1957年 | 3篇 |
1956年 | 2篇 |
1955年 | 3篇 |
排序方式: 共有1046条查询结果,搜索用时 15 毫秒
51.
Joseph A. Cannon 《Journal of the Air & Waste Management Association (1995)》2013,63(5):562-573
ABSTRACT Passage of the 1990 Clean Air Act Amendments launched the Acid Rain Program in the United States. This initiative, based on the market mechanism of a sulfur dioxide tradable “allowance” system, was a dramatic departure from traditional command and control strategies designed to reduce air pollution emissions. Power plant managers have flexibility under the program to select and implement a variety of options to reduce emissions below mandated levels. Federal agencies have collected annual performance data for affected facilities covered by the program for a number of years. Coal-burning plants are typically greater generators of sulfur dioxide (SO2) than oil burners of equivalent size. This study examined the effect of fuel type as a significant factor influencing a plant's achievement in reducing pollution emissions. Achievement was measured by using a derived variable, delta (A), defined as the difference between pounds of SO2 produced divided by the energy (in million Btu) generated, for the years 1990 and 1995. Rigorous nonparametric statistical analyses were used to compare the two populations of coal-fired and oil-fired plants. Results indicated that coal-burning facilities achieved greater program success, measured by the expected value of delta, than the oil combustors for the five-year period reviewed. Since utility managers must take steps to ensure all applicable requirements of the program are met, findings of the inquiry should prove to be useful in assessing achievable emissions reductions and aid in long-range facility planning. 相似文献
52.
Samuel Silberstein Richard A. Grot Kunimichi Ishiguro Joseph L. Mulligan 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1403-1411
This paper describes a laboratory project to assess the accuracy of emission and indoor air quality models to be used in predicting formaldehyde (HCHO) concentrations in residences due to pressed-wood products made with urea-formaldehyde bonding resins. The products tested were partlcleboard underlayment, hardwood- plywood paneling and medium-density fiberboard (mdf). The products were initially characterized in chambers by measuring their formaldehyde surface emission rates over a range of formaldehyde concentrations, air exchange rates and two combinations of temperature and relative humidity (23° C and 5 0% RH; 26°C and 60% RH). They were then installed in a two-room prototype house in three different combinations (underlayment flooring only; underlayment flooring and paneling; and underlayment flooring, paneling, and mdf). The equilibrium formaldehyde concentrations were monitored as a function of air exchange rate. Particleboard underlayment and mdf, but not paneling, behaved as the emission model predicted over a large concentration range, under both sets of temperature and relative humidity. Good agreement was also obtained between measured formaldehyde concentrations and those predicted by a mass-balance indoor air quality model. 相似文献
53.
54.
Robert R. Arnts Robert L. Seila Joseph J. Bufalini 《Journal of the Air & Waste Management Association (1995)》2013,63(4):453-460
A relative rate procedure was used to measure hydroxyl rate constants at room temperature in the presence of oxygen. The photolysis of methyl nitrite in the presence of nitric oxide was used to generate OH radicals. The rate of loss of the test compounds was measured relative to that of ethane (kOH = 2.74 × 10-13 cm3 molec-1 s-1). The rates obtained at 297 ± 2 K are: acetylene = (7.8 ± 1.6) × 10-13 cm3 molec-1 s-1,1,2-dichloroethane (2.8 ± Q.6) × 10-13 cm3 molec-1 s-1, 1,2-dibromoethane (2.4 ± 0.5) × 10-13 cm3 molec-1 s-1, p-dichlorobenzene (4.3 ± 0.9) × 10-13 cm3 molec-1 s-1 and carbon disulfide (29 ± 6) × 10-13 cm3 molec-1 s-1. Under a proposed EPA rule, this OH rate determination procedure could be used to determine if a given volatile organic will be subject to control for reduction of photochemical ozone. 相似文献
55.
56.
Norman L. Eatough Michele Eatough Delbert J. Eatough Jyothi M. Joseph Fern M. Caka 《Journal of the Air & Waste Management Association (1995)》2013,63(3):455-467
The precision and accuracy of the determination of particu-late sulfate and fluoride, and gas phase SO2 and HF are estimated from the results obtained from collocated replicate samples and from collocated comparison samples for high-and low-volume filter pack and annular diffusion denuder samplers. The results of replicate analysis of collocated samples and replicate analyses of a given sample for the determination of spherical aluminosilicate fly ash particles have also been compared. Each of these species is being used in the chemical mass balance source apportionment of sulfur oxides in the Grand Canyon region as part of Project MOHAVE, and the precision and accuracy analyses given in this paper provide input to that analysis. The precision of the various measurements reported here is ±1.8 nmol/m3 and ±2.5 nmol/m3 for the determination of SO2 and sulfate, respectively, with an annular denuder. The precision is ±0.5 nmol/m3 and ±2.0 nmol/m3 for the determination of the same species with a high-volume or low-volume filter pack. The precision for the determination of the sum of HF(g) and fine particulate fluoride is ±0.3 nmol/m3. The precision for the determination of aluminosilicate fly ash particles is ±100 particles/m3. At high concentrations of the various species, reproducibility of the various measurements is ±10% to ±14% of the measured concentration. The concentrations of sulfate determined using filter pack samplers are frequently higher than those determined using diffusion denuder sampling systems. The magnitude of the difference (e.g., 2-10 nmol sulfate/m3) is small, but important relative to the precision of the data and the concentrations of particulate sul-fate present (typically 5-20 nmol sulfate/m3). The concentrations of SO2(g) determined using a high-volume cascade impactor filter pack sampler are correspondingly lower than those obtained with diffusion denuder samplers. The concentrations of SOx (SO2(g) plus particulate sulfate) determined using the two samplers during Project MOHAVE at the Spirit Mountain, NV, and Hopi Point, AZ, sampling sites were in agreement. However, for samples collected at Painted Desert, AZ, and Meadview, AZ, the concentrations of SOx and SO2(g) determined with a high-volume cascade impactor filter pack sampler were frequently lower than those determined using a diffusion denuder sampling system. These two sites had very low ambient relative humidity, an average of 25%. Possible causes of observed differences in the SO2(g) and sulfate results obtained from different types of samplers are given. 相似文献
57.
Peter A. Scheff Donna M. Kenski Joseph Chung George Wolff 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1048-1057
Abstract Large-scale studies like the Southeast Michigan Ozone Study (SEMOS) have focused attention on quantifying and spedating inventories for volatile organic compounds (VOCs). One approach for evaluating the accuracy of a VOC emission inventory is the development of a chemical mass balance (CMB) receptor model for ambient non-methane organic compound (NMOC) measurements. CMB evaluations of ambient hydrocarbon data provide a sample-specific allocation of emissions to individual source categories. This study summarizes the results of an application of the CMB model to the NMOC data from the SEMOS study. Comparison of CMB results with emission inventory values for the Detroit area show that vehicle emissions are well represented by the inventory, as are architectural coatings and coke ovens. Estimated emissions from petroleum refineries and graphic arts industries are much lower in the inventory than determined from the receptor allocation. Under-reporting of fugitive VOC emissions from petroleum refineries is an ongoing problem. Emissions from graphic arts industries are underestimated in the inventory partly because of the broad characterization of the emission factor (i.e., mass emitted/capita), which may be less useful when specific locations and days are under consideration. This study also demonstrates the effectiveness of the CMB approach when used prospectively to track the implementation of emission control strategies. While vehicle emission concentrations were unchanged from 1988 to 1993, measurement-based CMB results suggest a decrease in evaporative emissions during this time period resulting from Reid vapor pressure (RVP) reductions (from 11.0 psi in 1988 to 8.6 psi in 1993) and fleet turnover. Changes in emissions from coke plants and petroleum refineries were also seen in the CMB allocations for these sources. 相似文献
58.
De Maria S Rivelli AR Kuffner M Sessitsch A Wenzel WW Gorfer M Strauss J Puschenreiter M 《Chemosphere》2011,84(9):1256-1261
Although the beneficial effects on growth and trace element accumulation in Salix spp. inoculated with microbes are well known, little information is available on the interactions among trace elements and macronutrients. The main purpose of this study was to assess the effect of phytoaugmentation with the rhizobacteria Agromyces sp., Streptomyces sp., and the combination of each of them with the fungus Cadophora finlandica on biomass production and the accumulation of selected trace elements (Zn, Cd, Fe) and macronutrients (Ca, K, P and Mg) in Salix caprea grown on a moderately polluted soil. Dry matter production was significantly enhanced only upon inoculation with Agromyces sp. Regarding the phytoextraction of Cd and Zn, shoot concentrations were mostly increased after inoculation with Streptomyces sp. and Agromyces sp. + C. finlandica. These two treatments also showed higher translocation factors from roots to the leaves for both Cd and Zn. The accumulation of Cd and Zn in shoots was related to increased concentrations of K. This suggests that microorganisms that contribute to enhanced phytoextraction of Cd and Zn affect also the solubility and thus phytoavailability of K. This study suggests that the phytoextraction of Zn and Cd can be improved by inoculation with selected microbial strains. 相似文献
59.
This study was carried out to explore the lowest achievable dinitrotoluene (DNT) isomer concentrations that would support sustained growth of DNT degrading microorganisms under an aerobic condition. Studies were conducted using suspended (chemostat) and attached growth (column) systems. The biodegradation limits for 2,4-dinitrotoluene chemostat and column system were 0.054 ± 0.005 and 0.057 ± 0.008 μM, respectively, and for 2,6-dinitrotoluene, the limits for chemostat and column system were 0.039 ± 0.005 and 0.026 ± 0.013 μM, respectively. The biodegradation limits determined in this study are much lower than the regulatory requirements, inferring that bacterial ability to metabolize DNT does not preclude applications of bioremediation (including natural attenuation) for DNT contaminated media. 相似文献
60.
Ronald Leroy Mickelsen Joseph Wood Michael Worth Calfee Shannon Serre Shawn Ryan Abderrahmane Touati Francis Robbins Delafield Lola Denise Aslett 《补救:环境净化治理成本、技术与工艺杂志》2019,30(1):47-56
Remediation and recovery efforts after a release of Bacillus anthracis (anthrax) spores may be difficult and costly. In addition, response and recovery technologies may be focused on critical resources, leaving the small business or homeowner without remediation options. This study evaluates the efficacy of relatively low levels of hydrogen peroxide vapor (HPV) delivered from off‐the‐shelf equipment for the inactivation of Bacillus spores within an indoor environment. Decontamination evaluations were conducted in a house using both Bacillus atrophaeus var. globigii (Bg; as surrogates for B. anthracis) inoculated on the carpet and galvanized metal as coupons and Geobacillus stearothermophilus (Gs) as biological indicators on steel. The total decontamination time ranged from 4 to 7 days. Using the longer exposure times, low concentrations of HPV (average levels below 20 parts per million) effectively inactivated Bg and Gs spores on the materials tested. The HPV was generated with commercial humidifiers and household‐strength hydrogen peroxide solutions. The presence of home furnishings did not have a significant impact on HPV efficacy. This simple, inexpensive, and effective decontamination method could have significant utility for remediation following a B. anthracis spore release, such as following a terrorist attack. 相似文献