Spatial Variability of Pool-Tail Fines in Mountain Gravel-Bed Stream Affects Grid-Count Results1

Bunte, Kristin, John P. Potyondy, Kurt W. Swingle, and Steven R. Abt, 2012. Spatial Variability of Pool-Tail Fines in Mountain Gravel-Bed Stream Affects Grid-Count Results. Journal of the American Water Resources Association (JAWRA) 48(3): 530-545. DOI: 10.1111/j.1752-1688.2011.00629.x Abstract: Fine sediment (<2 and <6 mm) particles underlying a 49-intersection grid placed on a streambed at 25, 50, and 75% of the wetted pool-tail width are commonly counted to assess the status and trend of aquatic ecosystems or to monitor changes in the supply of fines in mountain gravel-bed streams. However, results vary even when crews perform nearly identical procedures. This study hypothesized that spatial variability of pool-tail fines affects grid-count results and that a sampling scheme can be optimized for precision and accuracy. Grid counts taken at seven evenly spaced locations across the wetted width of 10 pool tails in a pool-riffle study stream indicated a bankward fining trend with secondary peaks of fines within the stream center. Sampling locations close to the waterlines harbored more than twice as many fines as central locations. Most of the five grid-count schemes derived from the seven sampled locations produced significantly different results. Compared with sampling at all seven locations, schemes that focus near waterlines overpredicted fines, while those that focus on the center underpredicted them. Variability of fines among pool tails was the highest within a broad band along the waterlines; hence, focusing sampling there yielded the most variable results. The scheme sampling at 25, 50, and 75% of the wetted width had the lowest precision and moderate accuracy. Accuracy and precision of grid-count results can be greatly improved by sampling at seven even-spaced locations across the pool tail.     

Non-timber forest product dependence among the <Emphasis Type="Italic">Jah Hut</Emphasis> subgroup of Peninsular Malaysia’s Orang Asli

Non-timber forest products (NTFP) represent key sources of cash and subsistence income for millions of rural and indigenous peoples living in tropical developing countries throughout the world. The current study investigates the use and significance of NTFP within a sample of Peninsular Malaysia’s Orang Asli (indigenous people). Data collected via household surveys across three sampling phases reveals that more than 75% of the population is actively engaged in NTFP collection. Household responses indicate diversity in both the types and uses of products collected. NTFP collection participation, frequency of collection, and collection reliance are found to be significantly negatively related to village proximity to the market, as well as to income level relative to the Malaysian poverty line. When collection variables are examined by different product categories, relationships with market access and income group are variable. Implications for different approaches to forest conservation and rural development are discussed.     

Environmental analysis of groundwater in Mecosta County, Michigan

Groundwater withdrawal has major economic, social, and environmental implications. In Michigan, recent legislative activity has begun to address the issue of groundwater sustainability. However, more hydrologic data are needed to help inform policy and legislation. A study was conducted in Mecosta County, Michigan to: (1) determine if a relationship could be established between land use/land cover and groundwater quality; and (2) develop a conceptual model for the shallow groundwater system of the study region. In general, groundwater quality was good, with below detection levels of E. coli, low total bacterial counts, and relatively low nutrient concentrations. No statistically significant associations were found between the bacterial numbers and either land use or the physical/chemical attributes measured, which may be because the scale of our spatial analysis was too coarse to detect patterns. Finer-scale, localized processes may have a greater influence on microorganism growth and abundance than coarser-scale, regional processes in this area. Our groundwater analysis suggested that shallow groundwater flow paths are generally consistent with regional surface water flow networks, and that shallow groundwater levels in most of the region have fluctuated within 1–2 m over the past 30 years, with no obvious increasing or decreasing trend.     

Illinois State Water Survey Bulletin 75: New Precipitation Frequency Study for Illinois

Storm frequency estimates and their temporal distributions are important in determining estimates of runoff or peak flow rates in many engineering and hydrological problems. Illinois State Water Survey Bulletin 70 has been serving as the design rainfall standard in Illinois since its publication in 1989. Although Bulletin 70 represented the best available data at the time of its publication, the standards needed to be reevaluated and updated after more than three decades and with the growing evidence of the nonstationary nature of heavy precipitation. The trends in heavy precipitation in Illinois prompted the creation of a new frequency study named Bulletin 75, providing precipitation frequencies for event durations ranging from 5 min to 10 days and for recurrence intervals ranging from 2 months to 500 years. The results are presented for the same 10 geographic sections in Illinois as in Bulletin 70 to maintain the continuity of hydrologic studies and compatibility with regulations. The primary goal of this paper is to outline some of the key methodological issues and challenges, to compare the results with the previous sources, and to highlight the effects of the changing precipitation standards on the development of amendments to existing ordinances. Lake County in Illinois, as one of the most affected urban areas with the highest change in heavy precipitation, was selected to illustrate issues related to the application of modified precipitation standards.     

Vertical movements, behavior, and habitat of bigeye tuna (Thunnus obesus) in the equatorial eastern Pacific Ocean, ascertained from archival tag data

The results presented in this report are based on analyses of 16,721 days of data downloaded from 96 archival tags recovered from bigeye tuna (Thunnus obesus; 54–159 cm in length, 0.97–5.44 years of age) at liberty from 31 to 1,508 days in the equatorial eastern Pacific Ocean. Analyses of daily timed depth and temperature records resulted in the classification of the data into three daily behavior types: characteristic, associative (associated with floating objects), and other. There is a significant positive correlation between the proportion of time fish exhibit characteristic behavior and increasing length, and significant negative correlations between the proportion of time bigeye exhibit associative and other behavior with increasing length. For the smallest (54–80 cm) to largest (100–159 cm) length classes, the vertical habitats utilized when exhibiting non-associative behaviors were 99 and 98% of the time above the thermocline depth (60 m) during the night, at the same average depth of 34 m, and 60 and 72% of the time below the thermocline during the day at average depths of 163 and 183 m, respectively. For the same smallest to largest length classes, when exhibiting associative behavior, the average nighttime and daytime depths were 25 and 21, and 33 and 37 m, respectively. The apparent effects of the environment on the behavior of the fish are discussed.     

Comparison of PCE and TCE disappearance in heated volatile organic analysis vials and flame-sealed ampules

The rates of hydrolysis reported for tetrachloroethylene (PCE) and trichloroethylene (TCE) at elevated temperatures range over two orders-of-magnitude, where some of the variability may be due to the presence of a gas phase. Recent studies suggest that volatile organic analysis (VOA) vials provide a low-cost and readily available zero headspace system for measuring aqueous-phase hydrolysis rates. This work involved measuring rates of PCE and TCE disappearance and the corresponding appearance of dechlorination products in water-filled VOA vials and flame-sealed ampules incubated at 21 and 55 °C for up to 95.5 days. While PCE and TCE concentrations readily decreased in the VOA vials to yield first-order half lives of 11.2 days for PCE and 21.1 days for TCE at 55 °C, concentrations of anticipated dechlorination products, including chloride, remained constant or were not detected. The rate of PCE disappearance was 34 times faster in VOA vials at 55 °C compared to values obtained with flame-sealed ampules containing PCE-contaminated water. In addition, the concentration of TCE increased slightly in flame-sealed ampules incubated at 55 °C, while a decrease in TCE levels was observed in the VOA vials. The observed losses of PCE and TCE in the VOA vials were attributed to diffusion and sorption in the septa, rather than to dechlorination. These findings demonstrate that VOA vials are not suitable for measuring rates of volatile organic compound hydrolysis at elevated temperatures.     

Qualitative analysis of volatile organic compounds on biochar

Qualitative identification of sorbed volatile organic compounds (VOCs) on biochar was conducted by headspace thermal desorption coupled to capillary gas chromatographic-mass spectrometry. VOCs may have a mechanistic role influencing plant and microbial responses to biochar amendments, since VOCs can directly inhibit/stimulate microbial and plant processes. Over 70 biochars encompassing a variety of parent feedstocks and manufacturing processes were evaluated and were observed to possess diverse sorbed VOC composition. There were over 140 individual chemical compounds thermally desorbed from some biochars, with hydrothermal carbonization (HTC) and fast pyrolysis biochars typically possessing the greatest number of sorbed volatiles. In contrast, gasification, thermal or chemical processed biochars, soil kiln mound, and open pit biochars possessed low to non-detectable levels of VOCs. Slow pyrolysis biochars were highly variable in terms of their sorbed VOC content. There were no clear feedstock dependencies to the sorbed VOC composition, suggesting a stronger linkage with biochar production conditions coupled to post-production handling and processing. Lower pyrolytic temperatures (?350 °C) produced biochars with sorbed VOCs consisting of short carbon chain aldehydes, furans and ketones; elevated temperature biochars (>350 °C) typically were dominated by sorbed aromatic compounds and longer carbon chain hydrocarbons. The presence of oxygen during pyrolysis also reduced sorbed VOCs. These compositional results suggest that sorbed VOCs are highly variable and that their chemical dissimilarity could play a role in the wide variety of plant and soil microbial responses to biochar soil amendment noted in the literature. This variability in VOC composition may argue for VOC characterization before land application to predict possible agroecosystem effects.     

Enhanced removal of heavy metals in primary treatment using coagulation and flocculation.

The goal of this study was to determine the removal efficiencies of chromium, copper, lead, nickel, and zinc from raw wastewater by chemically enhanced primary treatment (CEPT) and to attain a total suspended solids removal goal of 80%. Operating parameters and chemical doses were optimized by bench-scale tests. Locally obtained raw wastewater samples were spiked with heavy metal solutions to obtain representative concentrations of metals in wastewater. Jar tests were conducted to compare the metals removal efficiencies of the chemical treatment options using ferric chloride, alum, and anionic polymer. The results obtained were compared with those from other studies. It was concluded that CEPT using ferric chloride and anionic polymer is more effective than CEPT using alum for metals removal. The CEPT dosing of 40 mg/L ferric chloride and 0.5 mg/L polymer enhanced heavy metals removal efficiencies by over 200% for chromium, copper, zinc, and nickel and 475% for lead, compared with traditional primary treatment. Efficient metals capture during CEPT can result in increased allowable headworks loadings or lower metal levels in the outfall.     

Humic substances

GOALS, SCOPE AND BACKGROUND: Changing environmental conditions and handling stress are well known to cause chronic or acute stress situations in fish with subsequent infections. These requires a therapy by means of antibiotics and chemicals. In contrast to the huge number of pathogens, only a few substances are permitted for application as therapeutics in German aquaculture. Hence, there emerges an urgent need for highly effective and residueless alternatives. MAIN FEATURES: The prophylactic stimulation and training of the defense system of fish by alternative approaches becomes increasingly necessary. One approach is the application of dissolved humic substances (HS) of natural or artificial origin. For example, there exist several reports on the positive effect of HS to fishes. These effects shall be considered in detail. Furthermore, the impact of HS on the constitution of parasites and pathogens will be displayed. The reports on this issue are diverse, if not inconsistent. We try to shed some light on these discrepancies. The last aspect covered by this review is the outdated paradigm that calcium ions act as antidotes. In the presence of HS, even the opposite effect may occur. APPROACH: To overcome old paradigms on HS and their potential interactions with fish and fish parasites, we reviewed recent international literature, as well as 'grey' literature. We also include results from own former and ongoing studies. RESULTS AND DISCUSSION: HS are able to increase the physiological condition of the individuals and to reduce adverse physiological and histological consequences caused by stress; the mechanism behind remains obscure. HS detoxify heavy metals and organic pollutants. Damages caused by several fish pathogens, such as bacteria and parasites, can be repaired more quickly in the presence of HS. Some parasites--mainly fungi--appear to be directly affected by HS. Comparing the fungicidal effects of HS from various sources, evidence is increasing that the aliphatic moiety may be the effective structures. However, further research is necessary to relate more physiological and anti-pathogenic effects to the chemical characteristics of HS. CONCLUSIONS: HS are not real alternatives to strong traditional therapeutics. However, they show different advantages in repairing secondary, stress induced damages in fish. The ecophysiological relevance of HS in either aquatic systems or aquaculture is getting conspicuously. PERSPECTIVES: The lack of therapeutic and antiparasitic substances in aquaculture requires new strategies and ways of thinking. The search for alternatives to the 'traditional' chemical therapeutics calls for the intensive research. Inevitably, this search will lead to an intensive contemplation on HS as 'health promoting substances' and/or even therapeutics. Basic research is needed to detect the functional groups of the HS responsible for the effects observed. Health promoting effects of first investigations made in vitro to affect pathogens via application of HS and several field studies with HS raises hopes for a broader utilisation of HS to reduce stress consequences in fish and fish pathogens residuelessly.