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81.
82.
Culturable heterotrophic bacterial and phytoplanktonic densities were investigated at four sites in the Southern Adriatic Sea (Brindisi, S. Cataldo, Otranto and S. M. di Leuca) over an annual cycle. The main phytoplankton groups, the bacterial biodiversity, as well as the faecal contamination indicators were determined. Culturable bacterial numbers averaged 4.8 ± 0.2 log CFU ml−1 whereas phytoplankton numbers averaged 2.1 ± 0.4 log cells ml−1. Relationships between culturable bacteria, phytoplankton and the environmental factors were established. Bacterial and phytoplankton densities usually depended significantly on temperature, dissolved oxygen, phosphate and nitrite only in the S. Cataldo transect. In all the examined transects phytoplankton showed a bloom during the January–February period followed by a bacterial peak during the February–March period. Thus we can suppose that the phytoplankton winter bloom is responsible for the availabily of organic matter for bacterial populations in the following months in this oligotrophic ecosystem. 相似文献
83.
Ahmed AS Webster L Pollard P Davies IM Russell M Walsham P Packer G Moffat CF 《Journal of environmental monitoring : JEM》2006,8(2):307-316
The distribution and composition of hydrocarbons in sediment from the Fladen Ground oilfield in the northern North Sea have been investigated. The total PAH concentrations (2- to 6-ring parent and alkylated PAHs, including the 16 US EPA PAHs) in sediments were relatively low (<100 microg kg(-1) dry weight). The PAH, the Forties crude and diesel oil equivalent concentrations were generally higher in sediment of fine grain size and higher organic carbon concentration. PAH distributions and concentration ratios indicated a predominantly pyrolytic input, being dominated by the heavier, more persistent, 5- and 6-ring compounds, and with a high proportion of parent PAHs. The n-alkane profiles of a number of the sediments contained small, high boiling point, UCMs, indicative of weathered oil arising from a limited petrogenic input. The geochemical biomarker profiles of the sediments that contained UCMs showed a small bisnorhopane peak and a high proportion of norhopane relative to hopane, indicating that there was contamination from both Middle Eastern and North Sea oils. Therefore contamination was not directly as a result of oil exploration activity in the area. The most likely source of petrogenic contamination was from general shipping activity. 相似文献
84.
Gerboles M Buzica D Amantini L Lagler F Hafkenscheid T 《Journal of environmental monitoring : JEM》2006,8(1):174-182
This paper presents the results of a feasability study for the preparation and certification of reference materials (RMs) for nitrogen dioxide (NO(2)) and sulfur dioxide (SO(2)) in diffusive samplers. RMs for NO(2) were prepared by exposure to gas mixtures in a chamber while the RMs for SO(2) were prepared by liquid spiking. Certification of RMs for NO(2) was found feasible with a certified uncertainty of 5.8% and a proposed shelf life of 5 years. The uncertainty was calculated with contribution from the homogeneity of preparation, stability and transport of the CRMs and from an external verification of the certified value. To reach 5.8% of uncertainty, the contribution of the differences between the results of analysis by ion chromatography and colorimetry must be eliminated. It is proposed to solve this by pre-extracting the samplers with water before analysis. The results of this study indicate that the samplers are stable for at least two years before and after exposure when stored in a refrigerator. By contrast, the certification of RMs for SO(2) was found to not be feasible due to instability problems. This instability was attributed to reaction of sulfate on the walls of the samplers. Alternatively, the preparation of RMs by simultaneous exposure to SO(2) and NO(2) has been tested. Satisfying homogeneities has been reached both for NO(2) and SO(2). 相似文献
85.
Thomassen Y Koch W Dunkhorst W Ellingsen DG Skaugset NP Jordbekken L Arne Drabløs P Weinbruch S 《Journal of environmental monitoring : JEM》2006,8(1):127-133
The number concentration and size distribution of ultrafine particles in a S?derberg and a prebake potroom of an aluminium primary smelter have been measured using a scanning mobility particle spectrometer. The particle morphology was studied by transmission electron microscopy (TEM). The study shows the existence of elevated number concentrations of ultrafine particles in both potrooms. The main source of these particles is likely to be the process of anode changing. The ultrafine particles were measured directly at the source but could also be identified as episodes of high number concentrations in the general background air. Unlike the larger particles belonging to the 50-100 nm mode, the nanoparticle mode could not be detected in the TEM indicating that they may not be stable under the applied sampling conditions and/or the high vacuum in the instrument. 相似文献
86.
Exposure to environmental tobacco smoke (ETS) is an important worldwide public health issue. The present study demonstrates that cigarette smoke can be a major source of endotoxin (lipopolysaccharide, LPS) in indoor environments. Gas-chromatography/mass-spectrometry was used to determine 3-hydroxy fatty acids as markers of endotoxin in air-borne house dust in homes of smokers and non-smokers. Air concentrations of endotoxin were 4-63 times higher in rooms of smoking students than in identical rooms of non-smoking students. The fact that cigarette smoke contains large amounts of endotoxin may partly explain the high prevalence of respiratory disorders among smokers and may also draw attention to a hitherto neglected risk factor of ETS. 相似文献
87.
88.
A Characterization of Selected Endocrine Disruptor Compounds in a Portuguese Wastewater Treatment Plant 总被引:1,自引:0,他引:1
Maurício R Diniz M Petrovic M Amaral L Peres I Barceló D Santana F 《Environmental monitoring and assessment》2006,118(1-3):75-87
Anthropogenic compounds that are able to disrupt the endocrine system of wildlife species are a major cause for concern and
have led to a demand for new screening methods. The identification and quantification of endocrine disruptor compounds at
wastewater treatment plant is of major interest to assess the endocrine activity of wastewater treatment plant discharges
into the environment. This study consists of a preliminary survey of concentrations of previously selected endocrine disruptor
compounds, undertaken to establish environmental concentrations and to support a biological program assay exposing freshwater
fish to them. Selected endocrine disrupting chemicals (APEs, bisphenol A and 17 β-estradiol) were measured in samples from a wastewater treatment plant located in Lisbon (Portugal), using recent commercial
enzyme-linked immunosorbent assay kits and also LC-MS/MS. The results show that the wastewater treatment plant treatment process
is efficient on the removal of target endocrine disruptor compounds. However, environmentally significant concentrations are
still present in the treated effluent. The results also show that enzyme-linked immunosorbent assay kit is suitable for routine
analysis of the selected compounds. The results are also useful since the wastewater treatment plant is located in a Mediterranean
region, which results in an effluent with its own characteristics. 相似文献
89.
San Vicente Bay is a coastal shallow embayment in Central Chile with multiple uses, one of which is receiving wastewater from
industrial fisheries, steel mill effluents, and domestic sewage. A simulation model was developed and applied to dissolved
oxygen consumption by organic residues released into this embayment. Three compartments were established as function of: depth,
circulation and outfall location. The model compartments had different volumes, and their oxygen saturation value was used
as baseline. The parameters: (a) BOD5 of the industrial and urban effluents, (b) oxygen demand by organic sediments, (c) respiration, (d) photosynthesis and (e)
re-aeration were included in the model. Iteration results of the model showed severe alterations in Compartment 1, with a
decrease of 65% in the oxygen below saturation. Compartment 2 showed a small decline (10%) and compartment 3 did not show
apparent changes in oxygen values. Measures recommended for remediation were to decrease the BOD5 loading by 30% in the affected sector. Iteration of the model for 200 h following recommendations derived from the preceding
results produced an increase in saturation of 60% (5 ml O2 L−1), which suggested an improvement of the environmental conditions. 相似文献
90.
Zhang Y Ruan L Fasola M Boncompagni E Dong Y Dai N Gandini C Orvini E Ruiz X 《Environmental monitoring and assessment》2006,118(1-3):355-368
The rapidly developing Asian countries may face threatening environmental contamination, that however remains largely unassessed.
We studied persistent trace elements in three wetlands, Poyang Lake, relatively unpolluted, and Tai Lake, and Pearl River
Delta, selected as hotspots of pollution in Central China. We adopted as indicator the Little Egret, a widespread colonial
waterbird, and during 1999 and 2000 we collected and analysed the same samples as for a parallel study we conducted in Pakistan,
e.g. eggs, body feathers of chicks, prey spontaneously regurgitated by the chicks, and sediments at the areas most used by
foraging egrets. The levels of trace-metals at our three study areas were similar, or within the range, of those found in
the few other studies for East Asia, with few exceptions. The concentrations of the various elements were below the threshold
that may affect the survival or reproduction of the birds, and even the highest concentrations relative to background, i.e.
Se in eggs, and Hg in feathers at Pearl Delta, do not pose toxic hazards. In sediments, the levels of trace elements were
lower than the critical levels assumed for contaminated soil, except for alarming high levels of As at Poyang. These results
do not confirm our expectation, that Poyang was relatively uncontaminated, while Tai and Pearl were polluted. Although trace
metal concentration differed significantly among the three study areas, these differences were minor and were not consistent
among elements and samples. The bioaccumulation ratios from sediments through prey, feather and egg, were consistent with
our previous findings for Pakistan. Only Hg exhibited high bioaccumulation, while Se and Zn had low accumulation, and the
other elements no accumulation. This reasserts that feathers of predators such as egrets, may be more sensitive indicators
of environmental contamination for the elements subject to bioaccumulation, whereas the sediments or the organisms low in
the food chain are better indicators for the other elements. 相似文献