Assessing the impacts of current and future concentrations of surface ozone on crop yield with meta-analysis

Meta-analysis was conducted to quantitatively assess the effects of rising ozone concentrations ([O₃]) on yield and yield components of major food crops: potato, barley, wheat, rice, bean and soybean in 406 experimental observations. Yield loss of the crops under current and future [O₃] was expressed relative to the yield under base [O₃] (≤26 ppb). With potato, current [O₃] (31–50 ppb) reduced the yield by 5.3%, and it reduced the yield of barley, wheat and rice by 8.9%, 9.7% and 17.5%, respectively. In bean and soybean, the yield losses were 19.0% and 7.7%, respectively. Compared with yield loss at current [O₃], future [O₃] (51–75 ppb) drove a further 10% loss in yield of soybean, wheat and rice, and 20% loss in bean. Mass of individual grain, seed, or tuber was often the major cause of the yield loss at current and future [O₃], whereas other yield components also contributed to the yield loss in some cases. No significant difference was found between the responses in crops grown in pots and those in the ground for any yield parameters. The ameliorating effect of elevated [CO₂] was significant in the yields of wheat and potato, and the individual grain weight in wheat exposed to future [O₃]. These findings confirm the rising [O₃] as a threat to food security for the growing global population in this century.     

苏南地区CO2本底浓度及源汇特征

基于2015~2018年苏州张家港站CO₂在线观测数据，采用时序检查、选取稳定性数据、异常值剔除等质量控制方法获得可靠数据，并通过平均移动过滤（MAF）本底筛分法获得本底数据，讨论苏南地区CO₂变化特征.结果发现：CO₂本底浓度日变化为单峰结构，谷值和峰值分别出现在下午15：00和凌晨5：00前后；季节变化为双峰结构，峰值分别出现在12月和4月；日、季节变化的分布特征均与陆地生态系统、气象条件和人类活动有关.此外，2015~2018年CO₂浓度呈逐年上升趋势，抬升浓度占比逐年增加，吸收浓度占比波动较小，表明人类活动对CO₂浓度的影响正在逐年增加；而陆地生态系统对CO₂吸收汇的作用则相对稳定.源汇分析显示，CO₂抬升浓度随季节小幅波动；吸收浓度则夏半年较低，冬半年较高；抬升浓度日变化为单峰结构，谷值和峰值分别出现在15：00和8：00前后，早晨正值上班高峰，机动车排放可能为早晨峰值的主要因素；吸收浓度日间低、夜间高，这主要与植物光合作用及对流输送有关.分析CO₂浓度与风的关系发现，所有季节静风情况下，CO₂浓度偏高均最为明显，大部分方向CO₂浓度高低与风速大小有明显的负相关，其中S~WNW方向偏高最为明显，这可能是因为SW~NW方向主要为内陆城市群，且测站周边建筑区主要位于W~N方向，弱风有利于本地排放累积的结果.此外，WNW方向风速较大时浓度仍偏高明显，可能与测站W~N方向为建筑区及内陆城市群有关；而测站偏东方向主要为农田和林区，受人类活动影响较小，且海上气流较为洁净，故偏东风较弱时浓度也不高；说明了CO₂浓度除了与风速大小有关外，与周边下垫面类型及较远距离环境特征（城市群或海洋）也有一定的关系.     

工业有毒物质防治的技术措施

简要介绍了几种毒物防治的技术措施。     

生石灰孔结构对高温脱硫性能的影响

喷钙脱硫工艺的炉内脱硫率 ,不仅受工艺参数的影响 ,还与石灰石分解生成的新生CaO或直接喷入的CaO的表面结构有关。本研究用同一石灰石经不同方法 (煅烧、过烧、煅烧 -水合 -脱水等 )制备了四种具有不同比表面积和孔结构的生石灰。高温脱硫研究表明 :这四种不同孔结构的生石灰 ,具有不同的脱硫率。通过对高温脱硫前后吸着剂宏观结构变化的对比 ,发现半径小于 30 的孔易被反应产物堵塞 ,因而脱硫能力有限 ,而半径大于 5 0 的孔对脱硫更有效。本研究将为提高炉内喷钙的脱硫率、研制和开发高效脱硫剂提供新的途径。     

Effect of methylmercury on LPO levels, SH groups and activities of GSH-Px, SOD, XOD in liver of rats

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