低频率干湿交替环境中有机涂层失效过程

目的 研究低频率干湿循环条件下的有机涂层失效过程。方法 应用电化学阻抗谱技术,结合浸泡过程中涂层表面以及基底金属的形貌变化,对比研究全浸环境和低频率干湿交替环境下,浸泡初期、浸泡中期、浸泡末期有机涂层的失效过程及特征。结果 低频率干湿交替环境下,涂层在浸泡初期、中期、末期所经历的时长分别为18、4、46天,较全浸环境来讲,显著缩短了浸泡中期的时长,同时也显著延长了浸泡末期的时长。两种环境下的涂层均发生明显的局部剥离,且基底金属也均有明显的局部腐蚀。结论 低频率干湿交替环境明显延长了涂层的失效过程,且此环境下基底金属出现了明显的局部腐蚀。     

石油化工企业有限空间中的气体检测

介绍了便携式气体检测报警仪用于石油化工企业中有限空间的气体检测时的采样方法、检测点选择、检测工作程序以及检测结果的处理.     

Adsorption characteristics of benzene on biosolid adsorbent and commercial activated carbons

This study selected biosolids from a petrochemical waste-water treatment plant as the raw material. The sludge was immersed in 0.5-5 M of zinc chloride (ZnCl2) solutions and pyrolyzed at different temperatures and times. Results indicated that the 1-M ZnCl2-immersed biosolids pyrolyzed at 500 degrees C for 30 min could be reused and were optimal biosolid adsorbents for benzene adsorption. Pore volume distribution analysis indicated that the mesopore contributed more than the macropore and micropore in the biosolid adsorbent. The benzene adsorption capacity of the biosolid adsorbent was 65 and 55% of the G206 (granular-activated carbon) and BPL (coal-based activated carbon; Calgon, Carbon Corp.) activated carbons, respectively. Data from the adsorption and desorption cycles indicated that the benzene adsorption capacity of the biosolid adsorbent was insignificantly reduced compared with the first-run capacity of the adsorbent; therefore, the biosolid adsorbent could be reused as a commercial adsorbent, although its production cost is high.     

都市农业生态系统中污水资源化利用

文章介绍了都市农业生态系统中的污水处理工艺和资源化利用方案,并对回用过程中的水质状况进行了连续监测与分析,结果表明,主要污染物CODCr、BOD5、浊度、TN的去除率均达到90%以上。再生水完全可以满足系统内农业灌溉的要求,每年可减少50%的地下水开采量,且提供了良好的景观资源。蟹岛生态度假村以生活污水处理为中心的水资源循环利用方式,为污水资源化利用工程作了有益的尝试并取得了良好的效果。     

基于HERA-JANUS模型的空管人误认知分析

空管人误分类分析是空管人误研究的基础。为了对管制员人误进行系统的分类研究,结合空管业务知识和认知心理学理论,对欧洲航空安全局和美国联邦航空局合作开发的HERA-JANUS模型的工作原理和流程进行较详细地分析。运用该方法模型,对我国一起空管不安全事件案例进行分析后得到3个由管制员所产生的人误差错,并对这3个人误差错分别从人误类型、人误认知、相关因素3方面进行详尽的分析研究,最后得出该不安全事件的21项人误结果。结果表明,HERA-JANUS模型能较全面地从深层次分析管制员的人误,其分类形式也便于开展空管人误统计。     

亚硝态氮胁迫下菲律宾蛤仔实时定量P CR内参基因的筛选

为了更好地从基因角度研究亚硝态氮对贝类的生态毒性,需要筛选一个合适的内参基因作为参考,对其毒性相关基因进行定量表达分析。本研究以菲律宾蛤仔(Ruditapes philippinarum)作为研究对象,以亚硝态氮胁迫的鳃组织cDNA作为模板,利用geNorm软件和NormFinder软件对6个候选内参基因进行表达稳定性分析,并对2个结果做了综合赋权分析。结果显示,geNorm分析的基因表达稳定性结果为ActinCyPAEF1αUbi18STubu,NormFinder软件分析的结果为ActinUbiCyPAEF1α18STubu,最后经加权赋值法综合分析获得6个候选基因的表达稳定性为ActinCyPAUbiEF1α18STubu,即Actin为表达最稳定的基因。因此,Actin可以作为衡量亚硝态氮胁迫后菲律宾蛤仔鳃组织中基因表达的内参基因。     

钢板组合PEC柱-削弱截面钢梁组合框架抗震试验研究

为深入研究PEC柱-钢梁组合框架结构体系的抗震性能,设计了1榀两层单跨钢板组合截面PEC柱-削弱截面钢梁组合框架1∶2缩尺试件,并对其进行了低周往复荷载抗震试验。根据实测数据整理,得到了试验滞回特征曲线,并结合试验过程现象记录,分析了试件滞回特性、抗侧刚度退化规律、节点连接性能、耗能与延性和试件破坏模式等力学性能。研究结果表明:试件结构具有较高的承载力和较大的抗侧刚度;采取梁端截面削弱方式可实现梁端塑性铰位置远离节点区,且端板对穿螺栓连接能有效将梁端受拉翼缘拉力转化为对应边对节点区的压力,使得节点区形成了混凝土斜压带传力模式,提高了节点区抗震性能;试件滞回曲线较为饱满,在梁翼缘与端板连接焊缝存在施工缺陷情况下,其整体侧移、延性系数和等效黏滞阻尼比分别达到3.50%(推)/4.50%(拉)、2.92(推)/3.21(拉)和0.306,且承载力仍未下降至其极限承载力的85%,即试件结构具有良好的变形、抗震延性与耗能能力;该试件在循环往复荷载下呈现的破坏模式为梁削弱截面部位和PEC柱脚相继形成塑性铰的塑性机构。     

Carbon nanotubes-incorporated MIL-88B-Fe as highly efficient Fenton-like catalyst for degradation of organic pollutants

CNTs were incorporated into MIL-88B-Fe to get a new Fenton-like catalyst (C@M). Fe(II) was introduced in C@M to get a fast initiation of Fenton-like reaction. Fe(II) content in C@M was related with oxygen-containing functional groups on CNTs. C@M shows efficient catalytic degradation of pollutants over a wide pH range. Iron-based metal organic frameworks have been verified to be efficient heterogeneous Fenton catalysts due to their open pore channels and highly uniform distribution of metallic centers. In these catalysts, however, the iron element is mainly in the form of Fe(III), which results in a process required to reduce Fe(III) to Fe(II) to initiate Fenton reaction. To address this problem, carbon nanotubes (CNTs) with electron-rich oxygen-functional groups on the surface were incorporated into the metal organic frameworks (MIL-88B-Fe) to improve Fe(II) content for an enhanced Fenton-like performance. The prepared CNT@MIL-88B-Fe (C@M) showed much stronger catalytic ability toward H₂O₂ than MIL-88B-Fe. The pseudo-first-order kinetic constant for phenol degradation by C@M (0.32 min^–1) was about 7 times that of MIL-88B-Fe, and even higher than or comparable to the values of reported heterogeneous Fenton-like catalysts. Moreover, the Fenton-like system could effectively degrade various kinds of refractory organic pollutants and exhibited excellent catalytic activity over a wide pH range (4–9). XPS analysis confirmed that Fe(II) content of the catalyst gradually increased with CNT loadings. Electron spin resonance analysis showed that the signal intensity (•OH) of C@M was much higher than MIL-88B-Fe, which was consistent with the degradation efficiency of pollutants. Furthermore, the Fe(II) content of the catalyst gradually increased along with the oxygen-functional group content of CNTs. The result demonstrated that oxygen-containing functional groups of CNTs have a significant impact on the enhanced catalytic performance of C@M. This study provides a new insight to enhance Fenton reaction by using nanocarbon materials.     

Adsorption of Ammonium by Graphene Oxide-Based Composites Prepared by UV Irradiation and Using as Slow-Release Fertilizer

A novel sodium alginate-grafted poly(acrylic acid)/graphene oxide (NaAlg-g-PAA/GO) composite hydrogel was prepared via ultraviolet irradiation, and characterized by infrared spectroscopy spectrometer. X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. It was employed to adsorb NH₄⁺ from aqueous solution and used as slow-release nitrogen fertilizers (SNFs). Result indicated that the adsorption process for NH₄⁺ reached equilibrium within 50 min, with the adsorption capacity of 6.6 mmol g^?1 even if 30 wt% GO was incorporated. The results of adsorption kinetic and isotherm were well described by the pseudo-second-order and Freundlich model. The thermodynamics analysis showed the adsorption process was spontaneous. The study indicated excellent water-holding ratio of soil with 2 wt% SNFs was 81.2%, and nitrogen release was up to 55.1% within 40 days in soil. Overall, NaAlg-g-PAA/GO could be considered as an efficient adsorbent for the recovery of nitrogen with the agronomic reuse as a fertilizer.