呋虫胺对斑马鱼胚胎-幼鱼生长发育及细胞凋亡的影响

第三代新烟碱类农药呋虫胺作为超高效、广谱性杀虫剂在水稻、蔬菜和水果上广泛应用,因其水溶性高,对水生生物的毒性不容忽视。本研究以斑马鱼胚胎为对象,参考OECD标准,在胚胎受精后30 min内,采用静态法染毒,观察其24 h、48 h、72 h、96 h的生长发育情况,根据死亡数计算呋虫胺对斑马鱼96 h-LC_(50),采用吖啶橙染色(acridine orange fluorescent,AO-F)和原位末端标记法(TUNEL)2种方法,检测其对斑马鱼96 hpf(hour post-fertilization,hpf)幼鱼的细胞凋亡情况。结果表明:呋虫胺对斑马鱼胚胎的96 h-LC_(50)为10.36 g·L~(-1)(95%置信区间为7.76~12.93 g·L~(-1)),属于微毒;较高浓度的呋虫胺能使斑马鱼的摆尾数、内心率、孵化率降低,对生长发育有延迟的作用,可导致部分斑马鱼色素褪去,出现心包囊肿、卵黄囊肿和尾部畸形的现象。且随着浓度的升高,在斑马鱼头部、腹部、尾部均有明显的细胞凋亡情况加重,其中以心脏和内耳尤为明显,呈规律的剂量-效应关系。     

Changes in soil organic matter composition after afforestation of arable farmland in northeast China

Since the 1970s, a substantial area of arable farmland in a semi-humid area of northeast China has been planted as deciduous forests (Populus tomentosa Carr.). This study investigates the effects of afforestation on soil organic carbon (SOC) content and the chemical composition of the soil. Soil samples (Calcic chernozem) were collected from the upper 10?cm of paired arable land and secondary forests established 5 and 25 years previously. Carbon isotope analysis and pyrolysis–gas chromatography/mass spectrometry were used to determine SOC composition. The results show that (i) compared to the arable land, five years of afforestation caused a decrease in SOC and N concentration, while 25 years of afforestation resulted in an increase in SOC content; (ii) stable isotope δ¹³C analyses of the forest soils show gradual loss of crop-derived C and an accumulation of forest-derived C; and (iii) afforestation increased lignin abundance and decreased decompositional activity in the 25-year-old forest topsoil. Higher amounts of short-/mid-chain aliphatic compounds were observed in the 5-year-old forest (5–10?cm); and (iv) the arable soil contained substantially higher amounts of decomposed plant material and microbially derived substances. The results obtained suggest that long-term afforestation increases the SOC concentration, and alters the chemical composition of SOC.     

铜和镉对珠江天然仔鱼和幼鱼的毒性效应及其潜在生态风险

以静水实验法探讨珠江流域主要金属污染物铜和镉对当地天然仔鱼和幼鱼的急性毒性效应。结果显示,铜对西江赤眼鳟和鲴仔鱼(48 h)和广东鲂幼鱼(96 h)的LC50分别为0.066、0.055和0.10 mg·L-1,对应的安全浓度分别为0.006、0.010和0.010 mg·L-1;镉对赤眼鳟和鲴仔鱼(48 h)以及广东鲂幼鱼(96 h)的LC50分别为1.29、0.83和3.20 mg·L-1,对应的安全浓度分别为0.163、0.077和0.320 mg·L-1。其中,铜对上述受试鱼的安全浓度低于或接近我国《渔业水质标准》及《地表水环境质量标准》Ⅱ类水对铜的规定,而镉对这些受试鱼的安全浓度则高于相关标准对镉的规定。研究结果表明,珠江流域铜污染可能会对当地天然仔鱼、幼鱼群体的补充构成一定程度的威胁,但镉污染暂不会对该区域主要鱼类早期群体补充带来严重的生态风险。     

盐城海滨湿地植被地上生物量遥感估算研究

以盐城湿地自然保护区核心区的ETM+图像数据和同期野外实测的31 个样方地上生物量干重、湿重数据为数据源,分析了15 个遥感信息变量与湿地植被地上生物量干重、湿重的相关关系,并选择在0.01 水平上显著相关的8 个遥感变量建立一元线性回归模型、一元曲线回归模型以及多元逐步回归模型,并对比得出最优模型,进而计算出整个研究区的地上生物量。研究得出：①与研究区湿地植被地上生物量干重和湿重相关性最大的都是ETM+4 波段,干重的相关系数为0.833,湿重的相关系数为0.796;②研究区植被地上生物量干重和湿重的遥感估算模型都是一元三次函数模型,且干重模型的拟合精度要优于湿重模型;③得到研究区地上生物量干重总重量为2.28×10⁸ kg,湿重总重量为6.10×10⁸ kg。     

Incorporating greenhouse gas effects to evaluate energy efficiency in China

Reducing greenhouse gas emissions without hampering economic growth is a significant issue for China. Taking into account environmental sustainability principles, this study analysed the energy efficiency of 30 regions of China for the period 2002–2007. By employing a data envelopment analysis (DEA) approach, this study included undesirable CO₂ and SO₂ outputs and the desirable GDP output in the model. Empirical outcomes demonstrated that the overall average technical efficiency (TE) of China is 0.843, indicating a 15.70% input inefficiency. Among three geographic areas, the east has the highest technical efficiency, with the highest ability to set up clean-burning power plants based on best technology available. Performance in the west is less good because of much inefficient technology. Finally, the study demonstrates detailed management implications of the BCG matrix. The most important contribution of this paper is a detailed demonstration of an energy performance evaluation mechanism for China. The valuable results and insights gained can be equally effectively applied to studies in other developing countries facing the same gaseous emissions.     

Removal of phenol by powdered activated carbon adsorption

In this study, the adsorption performance of powdered activated carbon (PAC) on phenol was investigated in aqueous solutions. Batch adsorption studies were performed to evaluate the effects of various experimental parameters like PAC type, PAC dose, initial solution pH, temperature and pre-oxidation on the adsorption of phenol by PAC and establish the adsorption kinetics, thermodynamics and isothermal models. The results indicated that PAC adsorption is an effective method to remove phenol from water, and the effects of all the five factors on adsorption of phenol were significant. The adsorption rate of phenol by PAC was rapid, and more than 80% phenol could be absorbed by PAC within the initial 10 min. The adsorption process can be well described by pseudo-second-order adsorption kinetic model with rate constant amounted to 0.0313, 0.0305 and 0.0241 mg·μg ^-1·min ^-1 with coal, coconut shell and bamboo charcoal. The equilibrium data of phenol absorbed onto PAC were analyzed by Langmuir, Freundlich and Tempkin adsorption isotherms and Freundlich adsorption isotherm model gave the best correlation with the experimental data. Thermodynamic parameters such as the standard Gibbs free energy (?G^o), enthalpy (?H^o) and entropy (?S^o) obtained in this study indicated that the adsorption of phenol by PAC is spontaneous, exothermic and entropy decreasing.     

淮安市砂土地震液化势的综合评估

建立了BP神经网络模型LM算法的砂土地震液化判别方法,采用LVQ模式分类网络对数据进行分类,选取唐山地震时76个场地、320组现场液化勘察资料为研究对象,训练和检验网络模型的数据各160组,结果表明,该方法的砂土液化预测准确度为96.8%。根据淮安市典型场地土的钻孔资料,采用《建筑抗震设计规范法》液化判别法(规范法)、美国国家地震研究中心建议的液化判别简化方法(NCEER法)和谢君斐-陈国兴液化判别方法(谢-陈法)等3种液化判别方法及本文提出的BP神经网络模型液化判别方法对22个钻孔、120标贯点进行了液化判别,结果表明:14种地震液化判别方法的计算结果基本一致;2NCEER法比谢-陈法的计算结果要保守;3谢-陈法与规范法的计算结果很吻合,预测正确率相差不大;4规范法相对BP神经网络模型法的计算结果要保守;5BP神经网络模型法比其他3种方法的预测结果更符合实际的液化规律。最后,综合4种方法的液化判别结果给出了该地区地震液化势的评估结果,并给出了部分典型地质剖面土层地震液化势分布图。     

MgO改性赤泥复合材料对废水中氮磷的同步回收

为处理高浓度氮磷废水同时实现赤泥资源化利用,通过赤泥负载氧化镁制备高效氮磷回收材料(MgO-RM),用以对废水进行氮磷同步回收.考察了废水初始pH值、废水氮磷比和MgO-RM投加量对氮磷同步回收效果的影响.采用动力学模型和等温吸附模型对回收特性进行了描述,在此基础上利用FTIR、XRD、SEM、BET测试手段对MgO-...     

异地栽培对云南粳稻育成品种品质性状的影响

以15个云南粳稻育成品种(Oryza sativa L.)为试验材料,研究异地栽培对稻米品质性状的影响.结果表明:云南粳稻在温度相对较高的韩国水原种植,其粒长、粒宽、垩白粒率、精米白度、味度值、最高黏度值、崩解值极显著增加,长宽比、糙米率、精米率、整精米率、碱消值、直链淀粉含量、蛋白质含量、消减值和到达最高黏度时间极显著降低,而最低黏度值、最终黏度值和起浆温度不因栽培环境改变而发生明显变化.品质性状对栽培环境的反应不仅与具体的品质性状有关,也与品种密切相关.对环境反应最敏感的品质性状是垩白粒率,环境反应指数变幅为100.3%～2 077.8%,平均值为318.9%,变异系数为204.7%.其次依次是崩解值、消减值和精米白度,环境反应指数分别为202.8%、47.5%和123.1%,对环境反应最迟钝的品质性状是起浆温度和粒长.环境反应指数分别为100.2%和97.3%,其余性状对环境反应较敏感.最低黏度和最终黏度值对环境反应在品种问存在较大差异,有的品种在韩国水原种植这两项特征值增加,有的品种则降低.