Metal ferrites nanoparticles for catalytic and photocatalytic ozonation in wastewater treatment: a review

Environmental Chemistry Letters - The discharge of various pollutant-rich wastewater in large volumes without adequate treatment seriously endangers the environment. Catalytic and photocatalytic...     

Evaluation of the RAMS Continuous Monitor for Determination of PM2.5 Mass Including Semi-Volatile Material in Philadelphia,PA

Abstract

The real-time ambient mass sampler (RAMS) is a continuous monitor based on particle concentrator, denuder, drier, and tapered element oscillating microbalance (TEOM) monitor technology. It is designed to measure PM_2.5 mass, including the semi-volatile species NH₄NO₃ and semi-volatile organic material, but not to measure PM_2.5 water content. The performance of the RAMS in an urban environment with high humidity was evaluated during the July 1999 NARSTO-Northeast Oxidant and Particles Study (NEOPS) intensive study at the Baxter water treatment plant in Philadelphia, PA. The results obtained with the RAMS were compared to mass measurements made with a TEOM monitor and to constructed mass obtained with a Particle Concentrator-Brigham Young University Organic Sampling System (PC-BOSS) sampler designed to determine the chemical composition of fine particles, including the semi-volatile species. An average of 28% of the fine particulate material present during the study was semi-volatile organic material lost from a filter during particle collection, and 1% was NH₄NO₃ that was also lost from the particles during sampling. The remaining mass was dominantly nonvolatile (NH₄)₂SO₄ (31%) and organic material (37%), with minor amounts of soot, crustal material, and nonvolatile NH₄NO₃. Comparison of the RAMS and PC-BOSS results indicated that the RAMS correctly monitored for fine particulate mass, including the semi-volatile material. In contrast, the heated filter of the TEOM monitor did not measure the semi-volatile material. The comparison of the RAMS and PC-BOSS data had a precision of ±4.1 μg/m³ (±9.6%). The precision of the RAMS data was limited by the uncertainty in the blank correction for the reversible adsorption of water by the charcoal-impregnated cellulose sorbent filter of the RAMS monitor. The precision of the measurement of fine par-ticulate components by the PC-BOSS was ±6-8%.     

罗布泊“大耳朵”地区沉积物重金属含量及空间分布特征

以罗布泊"大耳朵"地区为研究区域,利用石墨炉原子吸收分光光度计(GF-990)和火焰原子吸收分光光度计(AAS-990)分析测试了沉积物中Pb、Cu、Ni和Mn元素的总量,并测定了沉积物中有机质的含量,运用SPSS软件分析了各重金属总量与有机质之间的相互关系。结果表明:罗布泊"大耳朵"地区盐壳层沉积物中Pb含量的变化范围在2.57~58.63 mg/kg,Cu含量的变化范围在6.33~39.65 mg/kg,Ni含量的变化范围在5.55~46.33 mg/kg,Mn含量的变化范围在46.33~1474.60 mg/kg;除Pb的垂直分布随着深度的增加其含量减少并趋于稳定外,重金属Cu、Ni和Mn的总量在各剖面垂直方向上大部分呈波折多峰行分布,分布趋势差异较大;重金属Pb、Cu、Ni和Mn与有机质都存在显著相关性。     

改善海洋环境保护工作的一条有效途径

文章首先对我国海洋环境保护现状进行了分析,然后通过对秦皇岛市海洋环境保护统一协调管理机制的探讨,提出了解决目前涉海地区普遍存在的“多头管海”,又“无人管海”这一制的海洋环境保护工作发展问题的途径。     

Estimation of septic tank setback distances based on transport of E. coli and F-RNA phages

Setback distances between septic tank systems and the shorelines of Lake Okareka, New Zealand were determined from model simulations for a worst-case scenario, using the highest hydraulic conductivity and gradient measured in the field, removal rates of the microbial indicators (Escherichia coli and F-RNA phages) determined from a column experiment, and maximum values of the design criteria for the disposal system, and assuming an absence of an unsaturated zone, a continuous discharge of the raw effluent from a failed or non-complying treatment system (both indicators at concentrations of 1x10(7) counts/100 ml) into the groundwater and no sorption of pathogens in the aquifer. Modelling results suggest that the minimal setback distances were 16 m to satisfy the New Zealand Recreational Water Quality Guidelines for E. coli <126 per 100 ml (Ministry for the Environment, 1999) and 48 m to meet the Drinking-Water Standards for New Zealand 2000 for enteric virus <1 per 100 l (Ministry of Health, 2000). These distances may be applicable for other lakeshores in pumice sand aquifers with groundwater velocities <7 m/day. Findings of laboratory column and batch experiments provided an insight into the microbial attenuation and transport processes in pumice sand aquifers. Bacterial removal was predominately through filtration (87-88%) and partially by die-off (12-13%), while viral removal was by both die-off (45%) and filtration (55%). In addition, microbial die-off in groundwater without aquifer material (i.e., free microbes) was much lower than die-off in groundwater with aquifer material (i.e., sorbed microbes) and contributed only 2-6% to the total removal. This implies that the setback distances estimated from die-off rates for the free microbes, determined in the laboratory without considering aquifer media and other removal processes, which are often reported in the literature, could be larger than necessary.     

中国降水量高度效应及全球升温对它的影响

利用中国气象中心160站点的实际观察资料,对中国半个世纪的降水变化进行了系统分析,发现中国的夏季降水量与海拔高度存在着很好的反相关关系;同时,全球升温使得降水量的高度效应增强,主要表现为高海拔降水量海拔效应明显增强,这主要是由全球升温引起环流系统增强所引起的.     

二级UASB厌氧工艺在制药废水中的应用

抗菌素制药污水复杂,其CODCr高达39000mgL,硫酸盐的浓度在6500mgL左右,常规工艺很难处理,山东某制药厂采用了二级厌氧工艺处理此类废水,取得了良好的处理效果和经济效益。     

基于Kaya方法的四个直辖市碳效率评价与比较

应用Kaya恒等式的计算方法对我国4个直辖市2005-2009年的碳效率进行了评价和比较分析,结果显示:4个直辖市碳效率的排序在2005-2009年间没有发生变化,4个城市的碳效率都处于上升态势。     

Linking China’s emissions trading pilot schemes

All seven emissions trading pilots in China operate independently. One challenge facing most of them is the low inclusion thresholds for enterprises and the few total covered emissions, which negatively influences the effects of the emissions trading systems (ETSs). Some pilot sites, such as Guangdong, Hubei, Tianjin and Beijing, have indicated their willingness to link their schemes with others. ETS linking could expand scheme coverages and therefore help to reduce the overall costs of achieving the linked schemes’ emissions control targets. Linking could also help to address the issues of carbon leakage and reduce price fluctuations. The potential benefits and feasibility of linking different pilot systems are analyzed in this article. The seven pilot regions are at different stages of social and economic development, with significant differences in total emissions and emissions structures as well as carbon abatement potentials and costs. Through linking, more-developed regions such as Beijing, Shanghai and Shenzhen, which are typically considered to face higher mitigation costs, will have the opportunity to achieve their emissions control targets by purchasing carbon units from less-developed regions, which will earn financial revenues from selling the units. To realize this win-win result, a series of policy and technical barriers at both the central government and pilot government levels needs to be overcome. Establishing a unified national emissions trading market would appear to be the ideal solution to these challenges, but it will take considerable time and will not be the short-term solution. In the absence of a unified national scheme, it is recommended that the central government encourage pilot schemes to link, that it develops corresponding national policies to support the linking efforts and that the pilot schemes that are intended to be linked coordinate on certain design elements. Based on the coordinating need, the major elements of an ETS can be divided into four categories: elements that need mutual recognition (cap setting and allowance allocation methods); elements that should be completely identical (compliance mechanisms, price containment measures, banking and borrowing rules, and offset mechanisms); technical elements that are preferably identical and easy to coordinate (MRV standards, technical registry standards); and elements that require no coordination (coverages and scopes).     

Application of hinokitiol potassium salt for wood preservative

The decay of wood and other cellulosic materials by fungi cause significant economic loss. The widely used chromated copper arsenate was prohibited for the environmental impact and safety of arsenic and chromium. It was found that natural product hinokitiol (HK) had fungicidal and insecticidal activities, and its toxicity was bearable for the environment. We described the practical synthesis of HK-K salt. According to the GB/T18261-2000 and LY/T1283-1998, wood preservative performance of HK-K salt was tested. The results showed that the best inhibitory concentration of HK-K salt was 50 mg/L, for which the prevention effectiveness on mold is better, the killed value is between 0 and 1, and the corrosion-resistant for wood-rotting fungi is grade A.