Bench‐ and pilot‐scale applications of electrochemical peroxidation: A new remedial concept

Electrochemical peroxidation (ECP) is a proprietary process that utilizes sacrificial iron electrodes and stochiometrically balanced applications of hydrogen peroxide to efficiently destroy aqueous phase contaminants. In laboratory trials it has been successful in reducing, often to non‐detectable levels, BTEX, fuel additives, chlorinated solvents, and polychlorinated biphenyls in ground waters. The process has also been found effective in reducing the chemical and biological oxygen demand of industrial waste water. Agency‐approved pilot tests will be conducted at two gasoline spill sites during 2000 where traditional pump and treat methods have proven ineffectual because of ground water chemistry or subsurface hydrologic conditions. The ECP process utilizes a tripartite treatment strategy consisting of 1) ex situ chemical oxidation; 2) in situ oxidation by reinjection of treated water with residual oxidants at the head of the plume; and 3) reestablishment of aerobic biodegradation by alteration of subsurface redox conditions. In contrast to other in situ oxidation treatment methods, dissolved iron is derived electrochemically, negating the need for ferrous salt addition. Dilute hydrogen peroxide (3 percent) is incrementally added to maximize oxidation efficiency and eliminate safety and environmental concerns accompanying the use of highly concentrated solutions. Results of laboratory trials and the geological and geochemical considerations of upcoming pilot‐scale applications are presented. Other potential applications currently under investigation include combination with other remedial processes (e.g. permeable barriers and hydrogen release compounds) to insure complete and rapid contaminant mineralization.     

STEP WISE,MULTIPLE OBJECTIVE CALIBRATION OF A HYDROLOGIC MODEL FOR A SNOWMELT DOMINATED BASIN1

ABSTRACT: The ability to apply a hydrologic model to large numbers of basins for forecasting purposes requires a quick and effective calibration strategy. This paper presents a step wise, multiple objective, automated procedure for hydrologic model calibration. This procedure includes the sequential calibration of a model's simulation of solar radiation (SR), potential evapotranspiration (PET), water balance, and daily runoff. The procedure uses the Shuffled Complex Evolution global search algorithm to calibrate the U.S. Geological Survey's Precipitation Runoff Modeling System in the Yampa River basin of Colorado. This process assures that intermediate states of the model (SR and PET on a monthly mean basis), as well as the water balance and components of the daily hydrograph are simulated consistently with measured values.     

SPATIAL VARIABILITY IN WATER‐BALANCE MODEL PERFORMANCE IN THE CONTERMINOUS UNITED STATES1

ABSTRACT: A monthly water‐balance (WB) model was tested in 44 river basins from diverse physiographic and climatic regions across the conterminous United States (U.S.). The WB model includes the concepts of climatic water supply and climatic water demand, seasonality in climatic water supply and demand, and soil‐moisture storage. Exhaustive search techniques were employed to determine the optimal set of precipitation and temperature stations, and the optimal set of WB model parameters to use for each basin. It was found that the WB model worked best for basins with: (1) a mean elevation less than 450 meters or greater than 2000 meters, and/or (2) monthly runoff that is greater than 5 millimeters (mm) more than 80 percent of the time. In a separate analysis, a multiple linear regression (MLR) was computed using the adjusted R‐square values obtained by comparing measured and estimated monthly runoff of the original 44 river basins as the dependent variable, and combinations of various independent variables [streamflow gauge latitude, longitude, and elevation; basin area, the long‐term mean and standard deviation of annual precipitation; temperature and runoff; and low‐flow statistics (i.e., the percentage of months with monthly runoff that is less than 5 mm)]. Results from the MLR study showed that the reliability of a WB model for application in a specific region can be estimated from mean basin elevation and the percentage of months with gauged runoff less than 5 mm. The MLR equations were subsequently used to estimate adjusted R‐square values for 1,646 gauging stations across the conterminous U.S. Results of this study indicate that WB models can be used reliably to estimate monthly runoff in the eastern U.S., mountainous areas of the western U.S., and the Pacific Northwest. Applications of monthly WB models in the central U.S. can lead to uncertain estimates of runoff.     

Forced copulation as a conditional alternative strategy in camel crickets

In the animal kingdom, males typically acquire reproductive access to females through courtship, nuptial gifts, or combat. In many species, small or poor-condition males that are unable to produce an attractive display, proffer an adequate mating gift, or dominate in male–male competition may resort to forced copulation. Forced copulation has been previously demonstrated in the camel cricket Pristoceuthophilus marmoratus and is uniquely facilitated by male hind leg weaponry that functions in both intrasexual competition and sexual coercion. Because male leg armaments are positively allometric, the largest males would seem best equipped to force-copulate, although they might be the most attractive to females, and so least likely to adopt a forced copulation strategy. In order to resolve this potential paradox and determine which males are in fact most likely to force-copulate, we manipulated male body size using diet and performed mating trials. Results showed that (1) male size increased with diet quality, (2) females appear to prefer larger males, and (3) smaller males were more likely to attempt forced copulation. Our results thus suggest that forced copulation is a condition-dependent alternative mating tactic used by small males unattractive to females.