低温条件下苯酚降解菌的分离鉴定及降解特性

在15℃低温的条件下,从本溪钢铁集团公司焦化厂曝气池活性污泥中分离、筛选得到1株高效苯酚降解菌,即Bb-2,它对起始质量浓度为400 mg·L-1的苯酚降解率为74.8%.经形态观察和生理生化实验,初步鉴定为假单胞菌属.该菌株能在4～40℃的温度条件下生长繁殖,因此为耐冷菌.当醋酸钠和葡萄糖作为第二碳源存在时,促进了低温下Bb-2对苯酚的生物降解.采用反应动力学方程拟合其降解过程,初始苯酚质量浓度较低时,遵循Monod方程;初始质量浓度较高时,其降解过程以基质抑制型的Haldane方程为主.     

科学大数据开放共享机制研究及其对环境信息共享的启示

科学大数据得以充分利用和增值的前提是开放共享,而影响数据开放共享的关键问题是共享机制.本文首先分析了科学大数据的产生方式、数据类型、投资方式、管理主体和服务定位及其与共享程度的关系.进一步在分析国内外自上而下和自下而上科学数据共享通用机制与原则的基础上,结合国家地球系统科学数据共享平台、全球变化科学数据出版等实践,提出了数据汇交、数据出版、数据联盟和服务激励四种数据共享机制,并分析了每种机制中的关键问题及具体做法.最后,结合云计算、"互联网+"等新一代信息技术和思维,对环境保护大数据共享机制提出四点建议,即:国家统一投资建设的环境保护核心业务数据强制汇交机制,其他部委、机构环境保护相关数据联盟交换机制,企业、科学家个人数据出版等激励机制,以及社会公众数据的"众创机制".     

降水和人类活动对秃尾河流域基流的影响

基于秃尾河高家川站1956—2012 年实测日径流数据,采用递归数字滤波法进行基流分割,并对高家川基流的趋势性、持续性、多时间尺度和突变特征进行分析。最后,采用累积斜率法计算降水和人类活动对基流的贡献比例。研究表明:1956—2012 年秃尾河基流不仅具持续显著减少特征,还有22 a 和8 a 的多尺度周期变化特征和突变特征,并以1979 和1996 年为突变点。与基准期相比,1980—1996 年降水和人类活动对基流的贡献率分别为54.16%和45.84%;1997—2012 年降水和人类活动所占的比例分别为30.11%和69.89%;人为驱动力占总驱动力的比例显著上升,可以认为在全球气候变化的背景下,人类活动日益成为秃尾河基流演变的主要驱动因子。     

Sensitive crop species and appropriate bioassays for potential use in phytotoxicity assessment of Pb-contaminated soils

The present study aims to determine the phytotoxic effects of lead (Pb) on corn (Zea mays), wheat (Triticum aestivum), cucumber (Cucumis sativus), cabbage (Brassica oleracea) and lettuce (Lactuca sativa) and to identify the sensitive crop species and appropriate bioassays for potential use in phytotoxicity assessment of Pb-contaminated soil. In a laboratory experiment, Pb(NO₃)₂ was added to the background soil to obtain eight Pb treatments. The results indicate that the seed germination rate of lettuce decreases by 14.44%, 30.00% and 40.00% at 2000, 3000 and 4000 mg Pb kg^?1 soil, respectively. However, the germination of corn, wheat, cucumber and cabbage is not significantly influenced by the Pb-contaminated soil treated with all the tested concentrations. Furthermore, the root elongation is more sensitive to Pb than is seed germination. The minimum concentrations of adverse effect of maize, wheat, cucumber, cabbage and lettuce are 2000, 3000, 1300, 800 and 300 mg Pb kg^?1 soil, respectively. Moreover, dicotyledon species are more sensitive than monocotyledon species. In the genotoxicity study, the mitotic index (MI) fluctuates with an increasing Pb concentration. The micronuclei (MN) frequencies of cucumber, cabbage and lettuce exhibit a dose-dependent effect at concentrations ranging from 1300 to 4000 mg Pb kg^?1 soil. It can be concluded that lettuce is a good candidate for indicating the toxicity of Pb in soil. Root elongation and the micronucleus frequency of dicotyledon are appropriate bioassays for potential use in phytotoxicity assessment of Pb-contaminated soil.     

Enhanced methane hydrate storage using sodium dodecyl sulfate and coal

A potential solution to reduce global warming is to store greenhouse gases. Greenhouse gas storage has been recently improved using several materials and techniques. However, the actual storage capacity is slow, limited, and costly. Here, we tested the use of an accelerating agent, sodium dodecyl sulfate, and coal to produce methane hydrate for methane storage. Experiments of storing methane gas in coal samples have been carried out under high pressures, 4 or 6 MPa, and low temperature of 273.15 K. Results reveal that sodium dodecyl sulfate improved the rate up to 58.26 cm³/min and the capacity up to 179.97 volume at standard temperature and pressure per unit volume of coal. This finding shows that sodium dodecyl sulfate is efficient to accelerate the formation of methane hydrate. We also found that storage capacity increased with pressure. We conclude that our method allows a gas storage capacity higher than any other medium materials reported previously.     

·Cl引发3种环状含有NH结构有机化合物的大气转化机制及动力学

氯自由基(·Cl)的高氧化性及其内陆来源的新发现使得·Cl在评估有机污染物的大气归趋方面起着比以往更为重要的作用。含有NH_x(x=1,2)结构的有机化合物不仅是大气中一类潜在的有机污染物,也是大气中致癌性亚硝胺的前驱体—N中心自由基的重要来源。前人研究发现,·Cl与含有NH_x(x=1,2)结构的有机化合物具有独特的相互作用且其反应具有结构依赖性。目前,大多数研究只关注链状含有NH_x(x=1,2)结构有机化合物的反应,而对于环状含有NH结构有机化合物的反应研究却很少。本研究使用量子化学和动力学模拟相结合的方法研究·Cl引发3种环状含有NH结构有机化合物(吗啉(MOR)、哌啶(PIP)和吡咯烷(PYR))的大气转化机制及动力学。结果发现,·Cl夺取3种环状含有NH结构有机化合物中N—H的H原子形成N中心自由基是最可行的反应路径。在298 K和1 atm下,计算的反应速率常数分别为5.0!10-10(MOR)、5.1!10-10(PIP)和4.9!10-10(PYR) cm~3·molecule-1·s-1,且具有正的温度依附性。结合可获得的·OH引发反应的反应速率常数,评估·Cl对MOR和PIP转化的贡献分别为·OH的2.6%～26%和6.9%～69%。上述研究结果为将来建立·Cl引发含有NH_x(x=1,2)结构有机化合物反应的结构-活性关系、全面评估含有NH_x(x=1,2)结构有机化合物的大气归趋和环境风险提供数据支持。     

Occurrence and fate of PPCPs in typical drinking water treatment plants in China

Environmental Geochemistry and Health - In this study, the occurrence and removal of twenty-nine pharmaceuticals and personal care products (PPCPs) in two water treatment plants (WTPs) in China...     

超临界流体技术及其在环境保护中的应用

从超临界流体萃取、超临界水氧化、催化超临界水氧化和超临界流体色谱等四个方面介绍超临界流体技术在环境分析、环境污染治理中的应用和发展方向。     

性能化防火设计在综合商业广场中的应用

本文给出了一种性能化防火设计的典型思路,对性能化防火设计方法的主要内容和流程作了介绍,并结合某综合商业广场的工程实例,给出了该综合商业广场的防火系统设计方案.