氢氧化铝废渣处理含氟废水的研究

在一定条件下氢氧化铝废渣活化处理,用于处理５０ｍｇ／Ｌ的含氟废水,投加量为２‰,ｐＨ值为６￣１１,去氟率达９６％。吸附平衡浓度与吸附量关系符合Ｌａｎｇｍｕｉｒ等温式,求出２０．０℃、２５．０℃、３０．０℃时的饱和吸附量和吸附系数。其吸附速度符合鲛岛吸附动力学方程式。     

菌株NKS-3对溴氨酸脱色特性探讨

从受溴氨酸污染地筛选出菌株ＮＫＳ－ ３ ,它对溴氨酸有脱色作用。菌株生长随碳源浓度增加而旺盛,溴氨酸能刺激菌株生长。溴氨酸浓度即使达到１０００ ｍｇ／Ｌ 也能被菌株基本脱色。研究发现,盐度抑制菌生长,在含盐培养液中溴氨酸的脱色过程被抑制     

哑铃湾网箱养殖对水环境的影响

2002-04～2003-01对哑铃湾不同网箱养殖区水质和底泥的实地监测调查和分析表明,哑铃湾网箱养殖对环境的影响主要是:①使得养殖水环境中营养盐、BOD、COD、有机质和TSS增加,尤其是PO₄^3--P和NH₃-N增加更为明显;②使得底泥沉积物中N、P、硫化物、有机质等大量富集,其中富集现象最明显的是P、硫化物和NH₄-N,其次是TN和有机质.     

基于一体化监控平台的风电场智能维护系统

针对风电场监控与运行维护需求,对风电场智能维护技术的现状、发展和应用趋势进行分析,提出一个具有电网接入控制功能,集风电场电气量监控和风电机组智能维护于一体的监控平台架构,在使风电场与变电站监控系统的数据信息共享和融合的同时,实现对风电机组状态的多维度监测和预警。分析结果表明:该系统兼顾风电场接入控制和电网调度控制,实现了对风电场电气量监控和对风电机组的智能维护,从而在保障风电场可靠运行的同时,使电网安全稳定水平得到提升,电网与风电场的效益获得双贏。     

饮用水中硝酸根的催化还原研究进展

由于化肥的过度使用 ,造成地下水中硝酸盐的污染日益严重。饮用水中高浓度的硝酸盐对人类健康会产生极大的威胁。本文综述了催化还原脱除水中硝酸根的研究进展和现状 ,并对其发展趋势进行了简单的论述。     

临界区甲醇的聚碳酸酯降解研究

在间歇高压反应器中研究了聚碳酸酯在甲醇临界区域的降解行为 .降解无需借助催化剂 ,降解温度 2 2 0— 2 6 0℃ ,压力5 2 0— 8 6 7MPa ,时间 5— 4 5min ,通过GC MS与GC FID对液相产物进行了定性和定量分析 ,聚碳酸酯醇解主要产物为碳酸二甲酯 (DMC)和双酚A(BPA) .降解温度和时间为 2 4 0℃和 30min时 ,DMC和BPA的产率分别 91 75 %和 90 0 3% .通过凝胶渗透色谱 (GPC)对 2 4 0℃醇解反应的固相聚合物进行了分析 .降解初期 ,聚合物大分子发生断裂 ,PC的数均分子量 (Mn)迅速下降 ,仅有少量DMC和BPA生成 ;降解的中间阶段 ,低聚物在降解产物中的比例快速增加 ,同时DMC与BPA相应增多 ,最终PC被完全分解 .     

低渗透石化污染场地多相抽提修复效率的数值模拟

借助TOUGH3/TMVOC软件对华北地区某典型污染场地进行模型概化,模拟再现了挥发性有机化合物(VOCs)在层状低渗透性介质中的运移和分布特征;同时,设置了不同情景的多相抽提方案,分析了渗透率对多相抽提技术(MPE)去除效率的影响.结果表明,VOCs在该介质中主要以非水相液体(NAPL)相形式存在,且NAPL相饱和度...     

Coupled electrochemical methods for nitrogen and phosphorus recovery from wastewater: a review

Environmental Chemistry Letters - Declining mineral resources, high fertilizer production cost and widespread eutrophication are calling for the recovery of nitrogen and phosphorus from wastewaters...     

A new prediction method of industrial atmospheric pollutant emission intensity based on pollutant emission standard quantification

● Established a quantification method of pollutant emission standard. ● Predicted the SO₂ emission intensity of single coking enterprises in China. ● Evaluated the influence of pollutant discharge standard on prediction accuracy. ● Analyzed the SO₂ emissions of Chinese provincial and municipal coking enterprises. Industrial emissions are the main source of atmospheric pollutants in China. Accurate and reasonable prediction of the emission of atmospheric pollutants from single enterprise can determine the exact source of atmospheric pollutants and control atmospheric pollution precisely. Based on China’s coking enterprises in 2020, we proposed a quantitative method for pollutant emission standards and introduced the quantification results of pollutant emission standards (QRPES) into the construction of support vector regression (SVR) and random forest regression (RFR) prediction methods for SO₂ emission of coking enterprises in China. The results show that, affected by the types of coke ovens and regions, China’s current coking enterprises have implemented a total of 21 emission standards, with marked differences. After adding QRPES, it was found that the root mean squared error (RMSE) of SVR and RFR decreased from 0.055 kt/a and 0.059 kt/a to 0.045 kt/a and 0.039 kt/a, and theR² increased from 0.890 and 0.881 to 0.926 and 0.945, respectively. This shows that the QRPES can greatly improve the prediction accuracy, and the SO₂ emissions of each enterprise are highly correlated with the strictness of standards. The predicted result shows that 45% of SO₂ emissions from Chinese coking enterprises are concentrated in Shanxi, Shaanxi and Hebei provinces in central China. The method created in this paper fills in the blank of forecasting method of air pollutant emission intensity of single enterprise and is of great help to the accurate control of air pollutants.     

鲤鱼对2,6-二硝基甲苯的生物浓缩、消除与代谢研究

 以鲤鱼为实验生物，应用流动式摄取及释放装置，进行了2，6－二硝基甲苯（2，6－DNT）的生物浓缩与释放研究。取得了2，6－DNT在鲤鱼（全鱼）、肝及肠部的生物浓缩曲线。全鱼的浓缩曲线可以稳态（平台式）曲线描述，但是肝、肠部浓缩曲线均呈峰形。肝部峰快速下降后渐趋稳态，肠部峰下降未得稳态。峰形，肝在先，肠在后。对比2，6－DNT在全鱼及肝、肠的生物浓缩曲线，并参照报道_（1，2）指出，全鱼摄取曲线上各点所表现的浓度值为各时刻鱼体内各组织摄取化学品总重对全鱼重量的比值。肝、肠部峰形曲线预示了在肝、肠内生物浓缩过程发生了生物转化作用。对全鱼的生物浓缩过程应用单区一级动力学模型，求得BCF值与消除速率常数K₁与K₂，由K₁/K₂计算得到的BCF值与实测值相符。释放较慢，释放曲线呈双曲线形，半减期为4.8h。