The impact on tropospheric ozone formation on the implementation of a program for mobile emissions control: a case study in São Paulo,Brazil

The main sources of reactive hydrocarbons (RHC) and nitrogen oxides (NO_x), ozone precursors, in the Metropolitan Area of São Paulo (MASP) in the southeast of Brazil are emissions from vehicles fleets. Ambient surface ozone and particulate matter concentrations are air quality problem in the MASP. This study examined the impact that implementing a control program for mobile emissions has on ozone concentrations, An episode of high surface ozone concentrations occurring in the MASP during the March 13–15, 2000 period was used as a case study that was modeled for photochemical oxidants using the California Institute of Technology/Carnegie Mellon University three-dimensional photochemical model. Different scenarios were analyzed in relationship to the implementation of the Programa Nacional de Controle de Poluição por Veículos Automotores (PROCONVE, National Program to Control Motor Vehicle Pollution). Scenario 1 assumed that all vehicles were operating within PROCONVE guidelines. Scenarios 2 and 3 considered hypothetical situations in which the PROCONVE was not implemented. Scenario 2 set the premise that vehicles were using pre-1989 technology, whereas scenario 3 allowed for technological advances. A base case scenario, in which the official emission inventory for the year 2000 was employed, was also analyzed. The CIT model results show agreement with most measurements collected during 13–15 March 2000 modeling episode. Mean normalized bias for ozone, CO, RHC and NO _x are approximately 9.0, 6.0, ?8.3, 13.0%, respectively. Tropospheric ozone concentrations predicted for scenario 2 were higher than those predicted for scenarios 1, 3 and base case. This study makes a significant contribution to the evaluation of air quality improvement and provides data for use in evaluating the economic costs of implementing a program of motor vehicle pollution control aimed at protecting human health.     

Future Trends and Mitigation Options for Energy Consumption and Greenhouse Gas Emissions in a Developing Country of the Middle East Region: a Case Study of Lebanon’s Road Transport Sector

The road transport system in Lebanon is one of the most unsustainable in the Middle East region due to, in large part, the absence of a national transportation strategy. This study proposes mitigation measures based on Lebanon’s commitments for reducing fossil fuel use and CO₂ emissions from road transport by increasing the share of fuel-efficient and hybrid electric vehicles and increasing the utilization of the existing bus service. Results show that increasing the market share of fuel-efficient vehicles to 35% in 2040 stabilizes energy use and emissions. The addition of hybrid vehicles to the first strategy, with a target of 10% market share by 2040, leads to 11% additional savings. Increasing the share of bus passenger kilometers traveled to 45% in 2040 leads to a reversal of adverse impacts. A combined strategy of all three measures leads to 63% reductions in 2040 compared to 2010, which is even superior to their cumulative savings.     

The clinical impact of the first-trimester nuchal translucency between the 95th–99th percentiles

Objectives

To evaluate the clinical significance of nuchal translucency (NT) between the 95th–99th percentile in terms of typical and atypical chromosomal abnormalities (ACAs), associated fetal congenital defects and postnatal outcome.

Methods

A retrospective cohort study of fetuses with NT between the 95th–99th percentile. Data regarding the rate of associated fetal defects, genetic abnormalities and postnatal outcome were collected.

Results

A total of 306 cases of fetuses with an NT between the 95th–99th percentiles were included. The overall rate of genetic abnormalities was 12.1% (37/306). Chromosomal abnormalities were found in 10.1% (31/306) of cases and 2% were ACA (6/306). Within this group, two were pathogenic Copy Number Variants (CNVs) and four were single gene disorders. The overall rate of fetal congenital defects was 13.7% (42/306). All ACAs were found in fetuses with congenital defects. Postnatally, a new diagnosis of a single gene disorder was made in 0.85% of cases (2/236).

Conclusions

The presence of an NT between the 95th–99th percentiles carries a 10-fold increased risk of fetal defects, representing an indication for referral for a detailed fetal anatomy evaluation. The risk of ACA is mainly related to the presence of fetal defects, irrespective of the combined test risk.     

Human factors applied to alarm panel modernization of nuclear control room

Human factors deal with issues related to humans, their behavior and the physical aspect of the environment in which they work. A control room is a complex system where operators perform plant operation using control systems and carry out monitoring and administrative responsibilities. For safe operation of industrial installation, the performance of the control room crew plays an important role. In this respect, a well designed control room is crucial for safe and efficient operation. The aim of this paper is to propose a methodological framework applied to nuclear control room evaluation, through participatory ergonomics, using operator activity analysis and human factors questionnaire as aid tools. We describe a case study in which the methodology framework was used in the evaluation process of a nuclear control room. The information gathered made possible a series of recommendation for the adequacy of the control room design, assisting in the safety assessment of the nuclear plant operation and justifying the alarm panel modernization.     

Contested sustainabilities: assessing narratives of environmental change in southeastern Turkey

This article contends that there is a need to more fully assess convergences and divergences between local environmental narratives in studies of environmental change and evaluations of sustainability. While much work has established the importance of being attentive to local knowledges, the possibility of evaluating points of overlap and dissonance between diverse narratives of change offers a particularly fruitful path for future work. Drawing on survey data and interviews related to irrigation-related changes in southeastern Turkey, narratives of environmental change offered by different actors are analysed to highlight key points of overlap and tension. Specifically, there is general agreement that degradation is occurring, even as actors disagree on the causal explanations for these changes. More revealing, narratives also share a tendency to validate techno-scientific approaches and continued state intervention, thus revealing crucial insights related to future agro-ecological possibilities in this region. Apart from offering empirical insights from a context in the Middle East where social science evaluations of environmental change and sustainability remain relatively thin, the analysis also speaks to broader theoretical and methodological concerns at the intersection of debates related to local knowledges, narrative and discursive approaches to environment, and sustainability.     

Validation of Ucides cordatus as a bioindicator of oil contamination and bioavailability in mangroves by evaluating sediment and crab PAH records

This study is aimed at verifying the relevance of Ucides cordatus as a bioindicator of oil contamination and PAH bioavailability in mangrove sediments. For this, crabs and sediment cores were sampled from five mangroves, including an area suspected of contamination derived from an MF380 oil spillage, and analyzed for the 16 PAH in the USEPA priority list as well as for the five series of alkylated homologues. Concentrations in sediments varied from 35 microg kg-1 in the lower core layer of the control area to 33,000 microg kg-1 in the upper layer of the most contaminated area. Total PAH contents in crabs varied from 206 to 62,000 microg kg-1 and were closely correlated to that in sediments. In general, individual PAH profiles in both matrices were in good agreement. Phenanthrenes, however, were more predominant in crabs making up to 30-46% of the Total PAH. Accumulation factors found in the range of 0.7 to 35 were highly variable even after normalizing concentrations for organic carbon and lipid content. Survival in highly contaminated environment and reliable record of environmental contamination in the tissue provide evidence that U. cordatus is an excellent bioindicator for oil in mangroves.     

Influence of a Catalyst in Obtaining a Post-consumer Pet-Based Alkyd Resin that Meets Circular Economy Principles

Journal of Polymers and the Environment - The paper studied the influence of a catalyst, comparing it with its traditional counterparts, in the process of obtaining a polyethylene terephthalate...     

Sensitivity of gametes, fertilization, and embryo development of the Japanese pearl oyster, Pinctada fucata martensii, to the harmful dinoflagellate, Heterocapsa circularisquama

Blooms of the toxic dinoflagellate Heterocapsa circularisquama cause massive bivalve kills in Japan. Mariculture of the Japanese pearl oyster, Pinctada fucata martensii, is the industry most affected by these blooms, especially in Ago Bay, Mie Prefecture, where they are frequent, cause mass mortality of oysters, and overlap with their spawning season. The goal of this August 2009 study was to assess the effects of a toxic strain of H. circularisquama isolated from Ago Bay on gametes, fertilization, and embryo development of pearl oysters. Spermatozoa, eggs, spermatozoa and eggs, and fertilized eggs of pearl oysters from Ago Bay were exposed to H. circularisquama at cell densities reported during the bloom (10–10⁴ cells mL^?1) for different periods of time. The concentration of H. circularisquama, exposure duration, and their interactions all had significant effects on gamete quality, fertilization, and embryo development. The motility and swimming velocity of spermatozoa, egg viability, fertilization, and embryo development rate were significantly reduced in all concentrations, with a cell density of 10 cells mL^?1 determined to be the critical density of H. circularisquama for deleterious effects. This is the first evidence of inimical effects of an HAB species on bivalve spermatozoa upon direct exposure. Further field and laboratory studies are required to investigate the potential effects of H. circularisquama blooms on the reproduction and recruitment of Japanese pearl oysters and other bivalves.     

Environmental knowledge memory: Contribution of the DIK model

A company does not only generate goods and services which meet the requirements in terms of deadlines, costs, quality and environment, but it also generates knowledge that must be capitalized. In order for a company to benefit from the skills and competences acquired during the realization of a project, some processes of memorization prove to be necessary. This article fits in this context and aims at suggesting a knowledge capitalization model in order to create a capital of environmental knowledge.To illustrate our suggestion, we have chosen an Environmental Performance Contract (EPC) signed by tens of Algerian companies which are reputed for their pollution of the environment. Capitalizing this knowledge allows these companies to anticipate on their environmental management and to guarantee the success of the EPC.     

Study of spatial and temporal distribution of antimicrobial in water and sediments from caging fish farms by on-line SPE-LC-MS/MS

An on-line solid phase extraction liquid chromatography-tandem mass spectrometry (SPE-LC-MS/MS) method for the determination of 12 antimicrobials in sediment and surface water was developed and validated. Furthermore, the spatial and temporal antimicrobials distributions in the sediment and in the water of four fish farms located in the hydroelectric dam of Ilha Solteira Reservoir in Brazil were investigated over four seasons in three sampling sites: at the fish cages, 100 and 1,000 m downstream far from the cages. The method was performed using an Agilent Zorbax 80 SB-C8 column (9.4 × 15 mm, 5 µm) as the loading column, and the Agilent Zorbax Eclipse Plus C18 column (3.0 × 100 mm, 3.5 µm) as a separation column within a run time of 13 min. The limits of quantification were less than 9 ng·L^?1 for the antibiotics in water and 16 µg·kg^?1 in sediment; the recovery ranged from 80 to 119%, with a variation coefficient less than 11%, and the repeatability was lower than 15%. Oxytetracycline was found in the water in all sample seasons. However, florfenicol was identified in April and October 2013 and January 2014, and tetracycline was present in July 2013. Regarding the sediment, oxytetracycline and tetracycline were found in all sampling periods, but chlortetracycline was only identified in January 2014. The spatial distribution of antimicrobials showed that the main pollution source came from the fish farms. This study demonstrated that the proposed method is reliable for the monitoring of antimicrobials in water and sediments and it showed contamination in both matrices from Ilha Solteira Reservoir.