全文获取类型
收费全文 | 342篇 |
免费 | 29篇 |
国内免费 | 102篇 |
专业分类
安全科学 | 37篇 |
废物处理 | 28篇 |
环保管理 | 17篇 |
综合类 | 203篇 |
基础理论 | 69篇 |
污染及防治 | 70篇 |
评价与监测 | 28篇 |
社会与环境 | 13篇 |
灾害及防治 | 8篇 |
出版年
2024年 | 4篇 |
2023年 | 3篇 |
2022年 | 24篇 |
2021年 | 21篇 |
2020年 | 28篇 |
2019年 | 11篇 |
2018年 | 14篇 |
2017年 | 18篇 |
2016年 | 12篇 |
2015年 | 12篇 |
2014年 | 17篇 |
2013年 | 23篇 |
2012年 | 23篇 |
2011年 | 32篇 |
2010年 | 28篇 |
2009年 | 27篇 |
2008年 | 31篇 |
2007年 | 17篇 |
2006年 | 12篇 |
2005年 | 11篇 |
2004年 | 13篇 |
2003年 | 8篇 |
2002年 | 15篇 |
2001年 | 18篇 |
2000年 | 13篇 |
1999年 | 10篇 |
1998年 | 6篇 |
1997年 | 4篇 |
1996年 | 9篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
排序方式: 共有473条查询结果,搜索用时 515 毫秒
61.
Lian Ming Linhui Li YingXin Zhang Weiyun Lin Guanzhu Wang Sai Zhang 《Chemistry and Ecology》2014,30(1):76-86
Lab-scale experiments were conducted to investigate the effects of dissolved organic matter (DOM) on the desorption of Cd in freeze–thaw treated Cd-contaminated soils. The results indicated that DOM significantly facilitated the desorption of Cd from freeze–thaw treated soils when comparing with that of non-frozen soils. Effects of DOM on the Cd desorption were highly dependent on the soil type and contamination concentration. The maximum desorption ratios of Cd by DOM generated from straw and sludge were 15.6% and 13.65%, respectively, in brown soils, and the maximum desorption ratios reached 14.7% and 9.3%, respectively, when using black soils through the same treatment. The higher the Cd contamination concentration in soils, the higher the ratio of Cd desorption by DOM. This was because of the integrated effects of the soil properties changed by the freeze–thaw treatment and the species transformation of Cd. The characteristics of DOM, such as its concentration and properties, had shown obvious impacts on the Cd desorption by DOM. The desorption was promoted with the increased DOM concentration and the hydrophilic fraction, and lowered pH and the low-molecular-weight of DOM. 相似文献
62.
为改善聚合物材料的火灾安全性,利用二硫化钼(MoS2)的独特性能,结合纳米复合、催化成炭等设计思路,采用共沉淀法制备CeMnOx-MoS2和CeFeOx-MoS2双金属氧化物-MoS2纳米杂化物,并将其分别应用到2种典型聚合物(聚氨酯和环氧树脂)中.结果 表明:2种杂化物均匀分散在聚合物基体中,可有效延缓聚合物材料的热... 相似文献
63.
Removal of Mo(VI) from aqueous solutions was investigated using cinder modified by sulfuric acid. Various parameters such as pH, agitation time, Mo(VI) concentration, and temperature have been studied. The maximum adsorption of Mo(VI) occurred at pH between 4.0 and 6.0. Kinetic studies showed that the adsorption generally obeyed a pseudo second-order model. The activation energy was 31.4?kJ?mol?1, indicating that the adsorption process was governed mainly by interactions of physical nature. Furthermore, application of Langmuir and Freundlich isotherm models to the adsorption equilibrium data showed that the adsorption behavior obeyed the Langmuir model. The adsorption capacity was found to be 10.8?g Mo(VI)?kg?1 adsorbent. Finally, thermodynamic parameters such as ΔH 0, ΔS 0, and ΔG 0 were also evaluated, which showed that the adsorption of Mo(VI) on the treated cinder was endothermic, entropy increasing, and spontaneous. In conclusion, the sulfuric acid-modified cinder was shown to be an inexpensive, effective, and simple adsorbent for the removal of Mo(VI) from water. 相似文献
64.
探讨孕哺期全氟辛烷磺酸(PFOS)暴露对子代大鼠成年后糖代谢稳态的影响。Wistar孕鼠随机分组,自孕0天(GD0)起分别以0 mg·kg-1(对照组)、4 mg·kg-1(低剂量组)和8 mg·kg-1 (高剂量组) PFOS(以饲料中PFOS计)经口染毒至仔鼠出生后21天(PND21)断乳为止。高效液相/质谱法检测PND1、PND21和PND42时仔鼠血清PFOS含量。检测仔鼠断乳后第8周和第18周时空腹血糖和胰岛素水平计算胰岛素抵抗指数(HOMA-IR);比较仔鼠口服糖耐量及肝脏糖代谢关键酶表达水平改变。结果显示:发育期PFOS暴露导致仔鼠出现血清中PFOS蓄积,以PND21时浓度最高,在低剂量组和高剂量组中分别为(7.77±1.45) μg·mL-1和(5.09±0.57) μg·mL-1。与对照组相比,不同剂量组仔鼠在断乳前后均出现明显体重降低,并在成年后出现高胰岛素血症,但PFOS仅在雄性仔鼠中引起了血糖升高。18周龄时口服糖耐量结果显示,PFOS暴露使雄性仔鼠在该阶段出现糖耐量受损,同时造成过氧化物酶体增殖物活化受体γ协同刺激因子(PGC-1)、磷酸烯醇丙酮酸羧激酶(PEPCK)表达水平的显著增高以及葡萄糖-6-磷酸脱氢酶(G6P)表达水平的显著降低。以上结果说明PFOS孕哺期暴露可引起子代成年后糖代谢失调,有增加糖尿病患病风险可能。 相似文献
65.
本研究以我国黄河口碱蓬湿地、九龙江口桐花树湿地、东寨港木榄湿地为研究样地,借助高通量测序技术探究这3个典型滨海湿地围垦养殖前、后土壤真菌多样性及群落结构的变化.结果表明:①不同地域湿地围垦养殖对土壤真菌群落多样性及丰富度影响表现不一致.九龙江口桐花树湿地围垦后,土壤真菌多样性及丰富度有所下降;黄河口碱蓬湿地和东寨港木榄湿地围垦后土壤真菌多样性及丰富度显著增加;②子囊菌门(Ascomycota)在湿地围垦养殖前、后土壤中均为优势真菌门,但其相对丰度在围垦后显著下降;③湿地围垦养殖改变了土壤真菌属水平群落组成,黄河口湿地围垦后,未出现翅孢壳属(Emericellopsis)、毛霉属(Mucor)、枝顶孢属(Acremonium);九龙江口和东寨港湿地围垦后,青霉属(Penicillium)相对丰度显著下降,并新增了镰刀菌属(Fusarium),九龙江口湿地围垦后还新增了链格孢属(Alternaria);④环境因子与湿地土壤真菌相对丰度存在一定程度的相关性,青霉属(Penicillium)与容重呈显著负相关(p<0.05),与pH呈显著负相关(p<0.01),与有机碳呈显著正相关(p<0.01);翅孢壳属(Emericellopsis)与容重和pH呈显著正相关(p<0.05),与有机碳呈显著负相关(p<0.01). 相似文献
66.
基于熵信息扩散理论的中国农业水旱灾害风险评估 总被引:1,自引:0,他引:1
农业水旱灾害是制约中国农业生产的重要因素。针对信息扩散理论模型存在的不足,论文构建了评估中国农业水旱灾害风险的熵信息扩散理论模型,依据1985-2013年数据资料,运用熵信息扩散理论模型对中国大陆30个省、市、自治区(重庆包含在四川中计算)的农业水旱灾害进行了风险评估,根据农业水旱灾害风险评估结果对中国农业水旱灾害风险进行了综合对比分析。评估和分析结果表明:中国面临着较大的农业水旱灾害风险压力;中国农业旱灾风险明显大于农业水灾风险;农业水旱灾害空间风险特征明显;农业水灾高中风险区域主要集中在长江中下游地区和东北地区,农业旱灾高风险区域主要集中在中国北部地区和东北地区,总体上看,中国农业水旱灾害的空间分布格局是南方地区易出现水灾,而北部地区易出现旱灾,东北地区面临水旱灾害重叠的双重压力。 相似文献
67.
蒋联 《安全.健康和环境》2008,8(12)
对206名接噪作业人员与197名非接噪作业人员进行了高血压患病率比较,结果表明接噪组明显高于非接噪组,且接噪作业人员工龄越长,高血压患病率越高。 相似文献
68.
Chiang CT Chang TK Hwang YH Su CC Tsai KY Yuan TH Lian IeB 《Environmental geochemistry and health》2011,33(5):469-476
The growing incidence of oral cancer (OC) in Taiwan has become a crucial public health concern. In particular, Changhua, a
county in central Taiwan, carries persistently high OC incidence rate, with an alarmingly high male/female ratio of OC incidence.
Previous epidemiological studies had found that the incidence is spatially correlated with the level of soil content to certain
heavy metals in the central Taiwan area. Soil and the human body both intake environmental heavy metals, which can be absorbed
through various ways. The soil metal concentration is an index of possible environmental exposure to heavy metal, and the
blood metal concentration somewhat reflects the level of the exposure on the human body. Metallic carcinogen is likely to
generate free radicals and play a role in many cancers, and many studies had reported that environmental exposure to heavy
metals is an important risk factor for developing cancer. Studies on animals showed that chronic intake of chromium (Cr) could
induce OC. This study aims to explore the association between the Cr concentration in the farm soil and in the blood of OC
patients. We recruited 79 OC patients from Changhua County, with their lifestyle being adjusted in regression analysis. The
results showed that the Cr concentration in the blood of OC patients is significantly higher than the background value, and
is positively associated with the Cr concentration in the soil surrounding their residence (p-value < 0.023). Because Changhua County is only with moderate prevalence of the known OC habitual risk factors, an environmental
factor related to heavy metal Cr exposure is suspected. Future investigations may verify the causal relation between Cr and
OC. 相似文献
69.
为了研究城市地下道路V形区段坡度构成对烟气扩散和重点排烟效果的影响,采用数值模拟手段,对V形区段内变坡点两侧不同坡度构成、排烟口的开启方式对烟气扩散和重点排烟效率的影响进行研究。研究结果表明:对于对称V形区段,采用重点排烟控制烟气相对容易,但对降低排烟道下方顶棚最高温度作用有限;针对非对称V形区段,烟气的自由扩散特性与变坡点两侧坡度差有关,增加大坡度侧的排烟口数量可以提高排烟效率,但要将烟气有效地控制在较小的范围内相对困难。实际运行中,应结合坡度的实际构成和烟气控制总目标,制定相应的排烟口开启策略。 相似文献
70.