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981.
Strongly acidic wastewater produced in nonferrous metal smelting industries often contains high concentrations of Ni(II), which is a valuable metal. In this study, the precipitation of Ni(II) from strongly acidic wastewater using sodium dimethyldithiocarbamate (DDTC) as the precipitant was evaluated. The effects of various factors on precipitation were investigated, and the precipitation mechanism was also identified. Finally, the nickel in the precipitates was recovered following a pyrometallurgical method. The results show that, under optimised conditions (DDTC:Ni(II) molar ratio = 4:1; temperature = 25 °C), the Ni(II) removal efficiency reached 99.3% after 10 min. In strongly acidic wastewater, the dithiocarbamate group of DDTC can react with Ni(II) to form DDTCNi precipitates. Further recovery experiments revealed that high-purity NiO can be obtained by the calcination of DDTCNi precipitates, with the nickel recovery efficiency reaching 98.2%. The gas released during the calcination process was composed of NO2, CS2, H2O, CO2, and SO2. These results provide a basis for an effective Ni(II) recovery method from strongly acidic wastewater. 相似文献
982.
983.
Jiachun Yang Li Zhang Shuang Lan Quanhao Dou Shiwei Hao Yueping Wang Xiaoxuan Wang Ruoyan Zhang Yongzhen Peng 《环境科学学报(英文版)》2023,35(2):952-962
The long-term impact of fulvic acid (FA) on partial nitritation (PN) system was initially examined in this study. The obtained results revealed that the FA lower than 50 mg/L had negligible effect on the nitrite accumulation rate (NAR nearly 100%) and ammonium removal rate (ARR 56.85%), while FA over 50 mg/L decreased ARR from 56.85% to 0.7%. Sludge characteristics analysis found that appropriate FA (<50 mg/L) exposure promoted the settling performance and granulation of PN sludge by removing Bacteroidetes and accumulating Chloroflexi. The analysis of metagenomics suggested that the presence of limited FA (0-50 mg/L) stimulated the generation of NADH, which favors the denitrification and nitrite reduction. The negative impact of FA on the PN system could be divided into two stages. Initially, limited FA (50-120 mg/L) was decomposed by Anaerolineae to stimulate the growth and propagation of heterotrophic bacteria (Thauera). Increasing heterotrophs competed with AOB (Nitrosomonas) for dissolved oxygen, causing AOB to be eliminated and ARR to declined. Subsequently, when FA dosage was over 120 mg/L, Anaerolineae were inhibited and heterotrophic bacteria reduced, resulting in the abundance of AOB recovered. Nevertheless, the ammonium transformation pathway was suppressed because genes amoABC and hao were obviously reduced, leading to the deterioration of reactor performance. Overall, these results provide theoretical guidance for the practical application of PN for the treatment of FA-containing sewage. 相似文献
984.
21世纪矿产资源经济展望 总被引:6,自引:2,他引:6
简要阐明了矿产资源经济、矿产经济和矿业经济基本概念和相互关系 ,在对我国内外矿产资源特点与需求分析基础上 ,探讨了21世纪矿产资源经济的基本问题 ,提出我国21世纪的矿产资源勘查评价的科学问题。 相似文献
985.
冷凝法回收油气问题的探讨 总被引:12,自引:0,他引:12
彭国庆 《石油化工环境保护》1999,(2):30-33
着重探讨在石油化工厂中利用引进的DE4800型油气回收装置回收轻质油品装车系统油气的经济效益与社会效益 相似文献
986.
987.
采用MAP法去除垃圾渗滤液中高浓度的氨氮,通过对正交实验和单因素实验确定最佳运行条件为pH值为10.0,反应时间为60min,Mg:N:P摩尔比为1.2:1.0:1.2,此时氨氮的去除率为73.1%,出水磷的浓度为56.3mg/L. 相似文献
988.
989.
彭友德 《安全.健康和环境》2002,2(1):11-14
针对消防水系统存在的问题,进行了系统可靠性分析.从提高系统可靠性方面,提出了优化消防水系统结构,提高系统可靠性的改造方案,并论证实施后的效果. 相似文献
990.
本文在全面分析了位于北京市朝阳区劲松东口京华大厦基坑的工程地质及水文地质资料后,结合多年的工程经验,对该基坑的降水方案提出了合理的设计与施工措施,并取得了非常理想的降水效果,保证了工程的顺利完成。 相似文献