全文获取类型
收费全文 | 542篇 |
免费 | 29篇 |
国内免费 | 186篇 |
专业分类
安全科学 | 46篇 |
废物处理 | 30篇 |
环保管理 | 47篇 |
综合类 | 283篇 |
基础理论 | 116篇 |
环境理论 | 1篇 |
污染及防治 | 175篇 |
评价与监测 | 31篇 |
社会与环境 | 10篇 |
灾害及防治 | 18篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 30篇 |
2021年 | 24篇 |
2020年 | 23篇 |
2019年 | 23篇 |
2018年 | 25篇 |
2017年 | 20篇 |
2016年 | 25篇 |
2015年 | 27篇 |
2014年 | 42篇 |
2013年 | 56篇 |
2012年 | 52篇 |
2011年 | 50篇 |
2010年 | 34篇 |
2009年 | 35篇 |
2008年 | 36篇 |
2007年 | 28篇 |
2006年 | 36篇 |
2005年 | 28篇 |
2004年 | 22篇 |
2003年 | 18篇 |
2002年 | 13篇 |
2001年 | 8篇 |
2000年 | 12篇 |
1999年 | 10篇 |
1998年 | 12篇 |
1997年 | 11篇 |
1996年 | 7篇 |
1995年 | 8篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有757条查询结果,搜索用时 46 毫秒
41.
Nanoparticles in wastewater from a science-based industrial park - coagulation using polyaluminum chloride 总被引:1,自引:0,他引:1
The Hsinchu Science-based Industrial Park (HSIP) is the hi-tech manufacturing hub of Taiwan. Wastewater from the HSIP contains numerous nano-sized silicate particles whose size distributions peak at 2 and 90 nm. A 3-5 mg l(-1) as Al dose of polyaluminum chloride (PACl) was used in the field to coagulate these particles, but the removal efficiency was low. Laboratory scale tests indicated that although PACl coagulation removed 52% of the turbidity and 48% of the chemical oxygen demand (COD) from water, its effect on nano-particle removal was minimal. About 58% of the soluble COD was associated with colloidal Si particles. A light scattering test and transmission electron microscopy (TEM) demonstrated that the nano-particles agglomerated in approximately linear aggregates of sizes 100-300 nm. Prolonged contact between residual PACl and the nano-particles generated large aggregates with sizes of up to 10 microm and a fractal dimension of 2.24-2.63. The results presented herein should be of interest in the processing of "high-tech" wastewater that contains nanosized silica particles. 相似文献
42.
Yao Meng Junwei Song Lewei Zeng Yingyi Zhang Yan Zhao Xufei Liu Hai Guo Liuju Zhong Yubo Ou Yan Zhou Tao Zhang Dingli Yue Senchao Lai 《环境科学学报(英文版)》2022,34(1):104-117
We present the continuously measurements of volatile organic compounds(VOCs) at a receptor site(Wan Qing Sha, WQS) in the Pearl River Delta(PRD) region from September to November of 2017. The average mixing ratios of total VOCs(TVOCs) was 36.3 ± 27.9 ppbv with the dominant contribution from alkanes(55.5%), followed by aromatics(33.3%). The diurnal variation of TVOCs showed a strong photochemical consumption during daytime,resulting in the formation of ozone(O3). Five VOC sources were ... 相似文献
43.
为揭示湖北省PM2.5和臭氧(O3)复合污染演变特征,基于湖北省17个地市的空气质量国控点和武汉市大气超级站组分监测数据,全面分析湖北省17个地市2015—2020年PM2.5和O3的时空变化特征及相关关系,探讨PM2.5和O3协同效应的成因机理. 结果表明:①2015—2020年,湖北省PM2.5显著改善,平均降幅为4.7 μg/(m3·a),但冬季负荷仍较高,主要集中于中部地区;O3污染凸显,平均增幅为3.8 μg/(m3·a),污染集中在4—10月的暖季,东部地区最严重,近两年超标天数已与PM2.5相当. ②湖北省PM2.5和O3关联日趋密切,协同效应显著,日评价指标显示夏季二者呈显著正相关(相关系数为0.57),近两年当PM2.5浓度≤50 μg/m3时,相关系数高达0.63;冬季PM2.5浓度与Ox(O3+NO2)浓度呈正相关,尤其2020年东部城市二者相关性高达0.46,显示大气氧化性对PM2.5二次污染的重要性. ③以武汉市为例,归纳PM2.5和O3复合污染的成因,暖季低PM2.5背景下,高温、中等湿度和弱风速的气象条件以及VOCs和NOx等前体物的高浓度排放,使得受VOCs主控的光化学反应加剧,易造成O3污染,从而加强PM2.5二次生成;冬季高的大气氧化性,叠加不利气象条件,促进颗粒物的二次生成,导致重污染时PM2.5组分以硝酸盐等二次无机组分为主. 研究显示,湖北省PM2.5和O3协同控制重点为,在保持现有NOx控制力度基础上强化VOCs控制,遏制暖季和东部区域O3浓度上升,加强冬季和中部PM2.5治理. 相似文献
44.
45.
Ammonium-dependent regulation of aerobic methane-consuming bacteria in landfill cover soil by leachate irrigation 总被引:1,自引:0,他引:1
The impacts of landfill leachate irrigation on methane oxidation activities and methane-consuming bacteria populations were studied by incubation of landfill cover soils with leachate and (NH4)2SO4 solution at different ammonium concentrations. The community structures and abundances of methane-oxidizing bacteria (MOB) and ammonia-oxidizing bacteria (AOB) were examined by PCRDGGE and real-time PCR. Compared with the pure (NH4)2SO4 solution, leachate addition was found to have a positive effect on methane oxidation activity. In terms of the irrigation amount, ammonium in leachate was responsible for the actual inhibition of leachate. The extent of inhibitory effect mainly depended on its ammonium concentration. The suppression of the predominant methaneconsuming bacteria, type I MOB, was responsible for the decreased methane oxidation activity by ammonium inhibition. Methaneconsuming bacteria responded diversely in abundance to ammonium. The abundance of type I MOB decreased by fivefold; type II MOB showed stimulation response of fivefold magnification upon the first addition but lessened to be lower than the original level after the second addition; the amount of AOB was stimulated to increase for 20-30 times gradually. Accumulated nitrate from nitrification strengthened the ammonium inhibition on type I and type II MOB, as a result, repetitive irrigation was unfavorable for methane oxidation. 相似文献
46.
Characterizing the optimal operation of photocatalytic degradation of BDE-209 by nano-sized TiO2 总被引:1,自引:0,他引:1
Ka Lai Chow Yu Bon Man Jin Shu Zheng Yan Liang Nora Fung Yee Tam Ming Hung Wong 《环境科学学报(英文版)》2012,24(9):1670-1678
Brominated flame retardants have been widely used in industry. There is a rapid growing public concern for their availabilities in the environment. Advanced oxidation process (AOP) is a promising and efficient technology which may be used to remove emerging chemicals such as brominated flame retardants. This project aims at investigating optimal operational conditions for the removal of BDE-209 using nano-scaled titanium(IV) oxide. The residual PBDE congeners after photocatalytical degradation of BDE-209 by TiO2 were analysed by gas chromatography-mass spectrometry (GC-MS). It was found that the degradability of BDE-209 by TiO2 was attributed to its photocatalytic activity but not the small size of the particles. The half-life of removing BDE-209 by TiO2 was 3.05 days under visible light. Tetra- and penta-BDEs were the major degraded products of BDE-209. Optimum conditions for photocatalytical degradation of BDE-209 was found to be at pH 12 (93% ± 1%), 5, 10, 20 mg/L (93.0% ± 1.70%, 91.6% ± 3.21%, 91.9% ± 0.952%, respectively), respectively of humic acid and in the form of anatase/rutile TiO2 (82% ± 3%). Hence, the efficiency of removing BDE-209 can be maximized while being cost effective at the said operating conditions. 相似文献
47.
48.
49.
50.
Chiang HL Lin KH Chen CY Choa CG Hwu CS Lai N 《Journal of the Air & Waste Management Association (1995)》2006,56(5):591-600
This study selected biosolids from a petrochemical waste-water treatment plant as the raw material. The sludge was immersed in 0.5-5 M of zinc chloride (ZnCl2) solutions and pyrolyzed at different temperatures and times. Results indicated that the 1-M ZnCl2-immersed biosolids pyrolyzed at 500 degrees C for 30 min could be reused and were optimal biosolid adsorbents for benzene adsorption. Pore volume distribution analysis indicated that the mesopore contributed more than the macropore and micropore in the biosolid adsorbent. The benzene adsorption capacity of the biosolid adsorbent was 65 and 55% of the G206 (granular-activated carbon) and BPL (coal-based activated carbon; Calgon, Carbon Corp.) activated carbons, respectively. Data from the adsorption and desorption cycles indicated that the benzene adsorption capacity of the biosolid adsorbent was insignificantly reduced compared with the first-run capacity of the adsorbent; therefore, the biosolid adsorbent could be reused as a commercial adsorbent, although its production cost is high. 相似文献