随着我国煤气化技术的快速发展,气化渣的产生和排放量逐年增加.煤气化细渣的大量堆存,给当地的环境保护造成了巨大的压力,已经成为限制煤化工产业基地可持续发展急需解决的重大问题.本文针对气化细渣中残碳反应活性低和转化难度大的问题,研究了机械活化法对气化渣残碳反应动力学的影响.采用Coats-Redfern法分析了机械活化对残碳反应活化能的作用规律.结果表明,机械活化8 h,残碳燃烧反应活性显著提高,650℃下的活化能由63.2 k J·mol-1降到28.4 k J·mol-1.不添加其他化学试剂,1000℃烧制高强度轻质陶粒,其堆积密度为0.867 g·cm-3,筒压强度为7.67 MPa.相关研究可以为我国气化细渣的资源化利用提供一定的数据和技术基础. 相似文献
Journal of Material Cycles and Waste Management - Electroplating sludge contained multi-metals and organics. In previous reports, electroplating sludges were usually recycled by direct calcination... 相似文献
The concentrations of trace metals (Cd, Pb, Cu, Cr, Fe, Ni, Zn and Co) were studied in soil profiles of eight municipal waste
dump sites in Warri metropolis. The results indicate that concentrations of trace metals varied widely among the different
dumpsites and decreased with depths in a studied soil profile. The accumulation pattern for the heavy metals in the soil profiles
follows the order: Fe > Pb > Mn > Co > Cr > Zn > Ni > Cu > Cd. The concentrations of metals found in these sites was below
the Canadian remediation criteria for land for agricultural, residential and commercial/industrial purposes except for the
cadmium levels in some sites that exceeded criterion values for agricultural and residential. In such sites, remedial actions
are required before any form of chosen development can take place. The levels of heavy metals found in these dump sites were
higher than that of the control site. The examined metals showed no significant correlation with soil physicochemical properties
at the surface horizon, which is suggestive evidence that these metals arise from anthropogenic input. 相似文献
Carbon (C), nitrogen (N) and phosphorus (P) are the three most important essential elements limiting growth of primary producers. Submerged macrophytes generally absorb nutrients from sediments by root uptake. However, the C:N:P stoichiometric signatures of plant tissue are affected by many additional factors such as taxonomy, nutrient availability, and light availability. We first revealed the relative importance of taxonomy, sediment, and water column on plant C:N:P stoichiometry using variance partitioning based on partial redundancy analyses. Results showed that taxonomy was the most important factor in determining C:N:P stoichiometry, then the water column and finally the sediment. In this study, a significant positive relationship was found between community C concentration and macrophyte community biomass, indicating that the local low C availability in macrophytes probably was the main reason why submerged macrophytes declined in Yangtze floodplain shallow lakes. Based on our study, it is suggested that submerged macrophytes in Yangtze floodplain shallow lakes are primarily limited by low light levels rather than nutrient availability.
Abstract The Henry’s law constant is important in the gas-liquid mass transfer process. Apparent dimensionless Henry’s law constant, or the gas-liquid partition coefficient (K’H), for both hydrophilic (methanol, isopropyl alcohol, and acetone) and hydrophobic (toluene and p-xylene) organic compounds in deionized (DI) water, a wastewater with a maximum total dissolved organic carbon (DOC) content of 700 mg/L, and DI water mixed with a maximum activated sludge suspended solid (SS) concentration of 40,000 mg/L were measured using the single equilibrium technique at 293 K. Experimental results demonstrate that the K’H of any of the test volatile organic compounds varied among three situations. First, the K’H of the hydrophilic compounds in mixed liquor with the maximum SS concentration was 9–21% higher than those in DI water. Second, those for toluene and p-xylene were 77% and 93% lower, respectively, in the mixed liquor with the maximum SS concentration. Third, the K’H values of all of the test compounds in the wastewater were only 10% lower than those in DI water. A model was developed to relate K’H with wastewater DOC and the SS concentration in the activated sludge using an organic carbon-water partition coefficient and activated sludge-water partition coefficient as model parameters. The model was verified and model parameters for test compounds estimated. 相似文献
The critical review of norms and standards and corresponding tests to determine the compostability of biodegradable plastics,
possibly applicable also to biodegradable agricultural plastics, shows that many norms concerning testing and labelling of
compostable plastics have been established at the international level. Some of them are about plastic materials, some others
are about products like packaging. The media and conditions of testing cover mainly the conditions designed for industrial
composting facilities, and only a few concern home composting conditions. Considering that the end of life management of biodegradable
agricultural plastic products will be done at the farm to reduce the management of the waste and also its cost, only a few
of these norms are considered to be suitable for adaptation to cover also biodegradable agricultural plastic products. The
biodegradability validation criteria under composting conditions, such as the threshold percentage of biodegradation and disintegration,
the time and temperature, and the ecotoxicity, are presented for the main norms and standard testing methods. Based on these
different norms and their content, a list of specs and technical requirements that could be adapted to meet farm composting
conditions for agricultural compostable plastics is proposed. These requirements may be used as criteria for the establishment
of a new integrative norm for agricultural compostable plastics. 相似文献
1IntroductionAs a many-volcano-distributed country,China is covered with many volcanoes and lava rocks.A-mong the one-thousand-or-so volcanoes,Changbai Mountain Volcano,Wudalianchi Volcano,Tengchong Volcano and Ashikule Volcano of West Kunlun are the mostlatentcatastrophic erup-tive active volcanoes.In recent years,the activity of the earth' s crust in some volcanic areas isobviously becoming increasing violent.Butfew scholars have monitored and evaluated volcano inChina.So building VDI… 相似文献