全文获取类型
收费全文 | 4169篇 |
免费 | 352篇 |
国内免费 | 1398篇 |
专业分类
安全科学 | 338篇 |
废物处理 | 200篇 |
环保管理 | 383篇 |
综合类 | 2403篇 |
基础理论 | 736篇 |
污染及防治 | 1270篇 |
评价与监测 | 272篇 |
社会与环境 | 179篇 |
灾害及防治 | 138篇 |
出版年
2024年 | 18篇 |
2023年 | 102篇 |
2022年 | 205篇 |
2021年 | 194篇 |
2020年 | 195篇 |
2019年 | 158篇 |
2018年 | 185篇 |
2017年 | 222篇 |
2016年 | 223篇 |
2015年 | 220篇 |
2014年 | 300篇 |
2013年 | 424篇 |
2012年 | 363篇 |
2011年 | 368篇 |
2010年 | 310篇 |
2009年 | 320篇 |
2008年 | 300篇 |
2007年 | 269篇 |
2006年 | 240篇 |
2005年 | 198篇 |
2004年 | 128篇 |
2003年 | 159篇 |
2002年 | 116篇 |
2001年 | 97篇 |
2000年 | 100篇 |
1999年 | 78篇 |
1998年 | 79篇 |
1997年 | 61篇 |
1996年 | 64篇 |
1995年 | 46篇 |
1994年 | 34篇 |
1993年 | 28篇 |
1992年 | 36篇 |
1991年 | 11篇 |
1990年 | 18篇 |
1989年 | 9篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 4篇 |
1972年 | 1篇 |
排序方式: 共有5919条查询结果,搜索用时 15 毫秒
781.
782.
783.
煤渣填料固定化菌膜处理餐厅污水 总被引:3,自引:0,他引:3
以煤渣为填料,采用人工筛选优势菌挂膜固定化技术和直流式供水送风形式,对酒家、宾馆的餐厅污水进行生物接触氧化处理,COD和BOD的去除率可>90%,处理后排放水质可稳定达到COD≤100mg·1~(-1),BOD≤30mg·1~(-1),SS≤30mg·1~(-1),NH_3—N≤15mg·1~(-1)。推广应用结果表明,具有显著的经济效益和环境效益。 相似文献
784.
气单胞菌SH10吸附银离子机制的研究 总被引:7,自引:0,他引:7
以气单胞菌SH10为生物吸附材料,从静电吸附作用、离子交换作用、络合作用、沉淀作用几方面研究了SH10吸附Ag 过程可能存在的作用机制.结果表明,气单胞菌SH10吸附银离子依赖于静电吸附作用;吸附Ag 前后溶液中Na 、K 、Mg2 浓度的变化较小,说明吸附过程中离子交换不明显;SH10表面的羧基、氨基和脂类基团经化学屏蔽后,对Ag 的吸附量明显下降,结合红外光谱分析结果,确定酰胺基CO-NH为SH10与银离子发生络合作用的主要官能团;电镜扫描结果表明,SH10在吸附过程中可以和Ag 形成沉淀沉积在细胞表面. 相似文献
785.
经过对PH玻璃电极对比观测实验,总结其在日常观测中衰减变化规律,以及PH电极失效前所具有的特征;讨论了对现有PH观测数据进行修正的方法,并编著相关修正程序;分析日常存在的测量误差,提出提高观测精度的措施。 相似文献
786.
The environmental fate and distribution of fungicide epoxiconazole were studied by a rice paddy field model ecosystem. One week before the head-sprouting stage, rice plant was treated separately once with OPUS (tradename of epoxiconazole) 12% SC 2.1 kg ha(-1) and 1.4 kg ha(-1), respectively. Soil, water and rice plant were sampled seven days intervals nine times after application. The bioconcentration factor of epoxiconazole on mosquito fish in the ecosystem was also determined, based on the amounts of epoxiconazole content both in fish and water. This was initiated one day after the fungicide treatment, and continued for four days. In addition, the residue of epoxiconazole in rice grains was analyzed after harvest. After harvest, both planted water spinach (Ipomoea aquatica Forsk) and edible amaranth (Amaranthus mangostanüs L.) were analyzed. The results showed that epoxiconazole degraded in the local environment under the experimental conditions described. The degradation equations were in accordance with the first order kinetics. The DT50 of soil, field water and rice plant were 20-69 days, 11-20 days and 14-39 days, respectively. The bioconcentration factors of epoxiconazole on mosquito fish were 12.9 and 10.6 from 2.1 kg ha(-1) and 1.4 kg ha(-1) treatment, respectively. Residues of epoxiconazole in both rice and harvest vegetables were non-detectable. This indicates that epoxiconazole applied to rice at the recommended rates and application frequencies will not accumulate on rice grain and successive cropping vegetables. 相似文献
787.
Copper adsorption kinetic properties in batch and fixed-bed reactors were studied in this paper. The isothermal adsorption experiments showed that the copper adsorption capacity of a granular activated carbon (Filtrasorb 200) increased when ionic strength was higher. The presence of EDTA diminished the adsorption. An intraparticle diffusion model and a fixed-bed model were successfully used to describe the batch kinetic and fixed-bed operation behaviors. The kinetics became faster when the solution pH was not controlled, implying that the surface precipitation caused some metal uptake. The external mass transfer coefficient, the diffusivity and the dispersion coefficient were obtained from the modeling. It was found that both external mass transfer and dispersion coefficients increased when the flow rate was higher. Finally effects of kinetic parameters on simulation of fixed-bed operation were conducted. 相似文献
788.
789.
Effect of photosensitizer diethylamine on the photodegradation of polychlorinated biphenyls 总被引:2,自引:0,他引:2
The objective of this study was to investigate the effect of diethylamine and xenon simulated sunlight on the photodegradation of two forms of PCBs including PCBs in transformer oil and PCB congener 138. The result of GC chromatograms illustrated the shifting pattern of higher chlorinated biphenyls in transformer oil degraded to lower chlorinated biphenyls with the extension of exposure time. The effect of diethylamine and xenon simulated sunlight was significant on the photodegradation of both PCBs in transformer oil and congener 138. The initial degradation rates of congener 138 (1.14 x 10(-9) to 4.47 x 10(-9) mol l(-1) h(-1)) were in direct proportion to the initial concentrations of congener 138 which confirmed the pseudo-first-order reaction of PCB photodegradation. The apparent quantum yields (phi) of congener 138 using diethylamine in xenon photoreactor were ranged between 2.08 x 10(-2) and 9.8 x 10(-4). PCB congeners 123, 97, 70, 67, 33, 29, 17, 12, and 9 were detected as the descendants of the photodegradation of congener 138 through dechlorination. The major pathway of congener 138 photodegradation in this study was via para-dechlorination. 相似文献
790.
Manganese uptake and accumulation by the hyperaccumulator plant Phytolacca acinosa Roxb. (Phytolaccaceae) 总被引:9,自引:0,他引:9
Xue SG Chen YX Reeves RD Baker AJ Lin Q Fernando DR 《Environmental pollution (Barking, Essex : 1987)》2004,131(3):393-399
The perennial herb Phytolacca acinosa Roxb. (Phytolaccaceae), which occurs in Southern China, has been found to be a new manganese hyperaccumulator by means of field surveys on Mn-rich soils and by glasshouse experiments. This species not only has remarkable tolerance to Mn but also has extraordinary uptake and accumulation capacity for this element. The maximum Mn concentration in the leaf dry matter was 19,300 microg/g on Xiangtan Mn tailings wastelands, with a mean of 14,480 microg/g. Under nutrient solution culture conditions, P. acinosa could grow normally with Mn supplied at a concentration of 8000 micromol/l, although with less biomass than in control samples supplied with Mn at 5 micromol/l. Manganese concentration in the shoots increased with increasing external Mn levels, but the total mass of Mn accumulated in the shoots first increased and then decreased. At an Mn concentration of 5000 micromol/l in the culture solution, the Mn accumulation in the shoot dry matter was highest (258 mg/plant). However, the Mn concentration in the leaves reached its highest value (36,380 microg/g) at an Mn supply level of 12,000 micromol/l. These results confirm that P. acinosa is an Mn hyperaccumulator which grows rapidly, has substantial biomass, wide distribution and a broad ecological amplitude. This species provides a new plant resource for exploring the mechanism of Mn hyperaccumulation, and has potential for use in the phytoremediation of Mn-contaminated soils. 相似文献