偶氮二甲酰胺发泡剂清洁生产评价模型

提出了针对不同工艺的偶氮二甲酰胺（ADC）发泡剂生产企业的清洁生产综合评价方案。利用逐层序关系分析法确定各指标的影响因子,采用极差标准化法对正逆向指标数据进行初步处理,使用主成分分析法对ADC发泡剂生产企业进行排名。该研究为ADC发泡剂清洁生产评价提供了一个更加客观和精确的方案。     

硅烷化改性沸石对重金属离子的吸附性能

制得一种用于重金属废水处理的新型硅烷化改性沸石吸附剂,成本低、效果显著且稳定。通过对改性沸石表征,分析了改性对沸石结构的影响。结果表明,改性一定程度降低了原沸石的晶体特征,但基本上保持了其结构组成;硅烷化改性成功地在沸石上接枝了氨基。对硅烷化沸石的特性研究,得出硅烷化沸石对Ni2+、Cu2+、Zn2+和Pb2+吸附最佳投加量为1、1、1.6和0.6 g/L,且此时对4种离子的去除率也较好;吸附动力学研究得出,其吸附过程可用二级动力学方程较好地拟合;吸附达到平衡时,4种金属离子的平衡吸附量分别为11.23、17.41、15.45和59.42 mg/g;硅烷化沸石对金属离子的吸附行为更符合Langmuir模型,为化学吸附;在酸性条件下(pH=2～6),硅烷化沸石仍保持一定的吸附能力,具有一定的耐酸性。     

Physiological and biochemical responses of rice seeds to phosphine exposure during germination

Rice seeds (Tianyou, 3618) were used to examine the physiological and biochemical responses to phosphine exposure during germination. A control (0 mg m⁻³) and four concentrations of phosphine (1.4 mg m⁻³, 4.2 mg m⁻³, 7.0 mg m⁻³ and 13.9 mg m⁻³) were used to treat the rice seeds. Each treatment was applied for 90 min once per day for five days. The germination rate (GR); germination potential (GP); germination index (GI); antioxidant enzymes, including superoxide dismutase (SOD), peroxidase (POD), and catalase (CAT); and lipid peroxidation measured through via malondialdehyde (MDA) were determined as indicators of the physiological and biochemical responses of the rice seeds to phosphine exposure. These indicators were determined once per day for five days. The results indicated that the GR, GP and GI of the rice seeds markedly decreased after phosphine exposure. The changes in the activities of the antioxidant enzymes due to the phosphine exposure were also significant. The exposure lowered the CAT and SOD activities and increased POD activity in the treated rice seeds compared with controls. The MDA content exhibited a slow increase trend with the increase of phosphine concentration. These results suggest that phosphine has inhibitory effects on seed germination. In addition, phosphine exposure caused oxidative stress in the seeds. The antioxidant enzymes could play a pivotal role against oxidative injury. Overall, the effect of phosphine on rice seeds is different from what has been reported previously for insects and mammals.     

苏里格气田回注水污染防治措施

气田污水处理后回注地层是保证气田有效开发、防止污染的有效途径。文章介绍了苏里格气田在污水回注方面通过设计、施工、运行三个阶段所采取的选择安全回注地层、优化井身结构等各种防止污染措施,有力的保护了地下水资源。     

Biosorption of uranium by chemically modified Rhodotorula glutinis

The present paper reports the biosorption of uranium onto chemically modified yeast cells, Rhodotorula glutinis, in order to study the role played by various functional groups in the cell wall. Esterification of the carboxyl groups and methylation of the amino groups present in the cells were carried out by methanol and formaldehyde treatment, respectively. The uranium sorption capacity increased 31% for the methanol-treated biomass and 11% for the formaldehyde-treated biomass at an initial uranium concentration of 140 mg/L. The enhancement of uranium sorption capacity was investigated by Fourier transform infrared (FTIR) spectroscopy analysis, with amino and carboxyl groups were determined to be the important functional groups involved in uranium binding. The biosorption isotherms of uranium onto the raw and chemically modified biomass were also investigated with varying uranium concentrations. Langmuir and Freundlich models were well able to explain the sorption equilibrium data with satisfactory correlation coefficients higher than 0.9.     

Study on the contamination of heavy metals and their correlations in mollusks collected from coastal sites along the Chinese Bohai Sea

Mollusks living in seas can accumulate heavy metals, and may serve as excellent passive biomonitors. During a period of 1 year, bioaccumulation of As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se, and Zn was examined in nine kinds of mollusks (Rapana venosa, Neverita didyma, Scapharca subcrenata, Mytilus edulis, Amusium, Crassostrea talienwhanensis, Meretix meretrix, Ruditapes philippinarum, and Mactra veneriformis), which were collected at eight coastal sites along the Chinese Bohai Sea. Metal concentrations were directly determined by inductively coupled plasma mass spectrometer (ICP-MS). Two certified reference materials, dogfish muscle (DORM-2) and mussel (GBW 08571), were used to validate the methods, and the recoveries were within 83.72-112.30% of the certified values. Bioaccumulation of metals varied strongly among sampling sites and species. Statistical analysis (one-way ANOVA) indicated that different species examined showed different bioaccumulation of metals, and perhaps they could be used as potential biomonitors to investigate the contamination levels of heavy metals. Principal component analysis (PCA) and correlation analysis were used to study the relationships between these heavy metals. The results showed that, in nine mollusks' tissues, there are significant correlations between these elements in adjacent main group or subgroup in periodic table of elements.     

Spatial distribution and seasonal variation of polycyclic aromatic hydrocarbons (PAHs) contaminations in surface water from the Hun River, Northeast China

The objectives of this study were to investigate the levels, dispersion patterns, seasonal variation, and sources of 16 priority polycyclic aromatic hydrocarbons (16 EPA-PAHs) in the Hun River of Liaoning Province, China. Samples of surface water were collected from upstream to downstream locations, and also from the main tributaries of the Hun River in dry period, flood period, and level period, respectively. After appropriate preparation, all samples were analyzed for 16 EPA-PAHs. Total PAHs concentrations varied from 124.55 to 439.27 ng l^?1 in surface water in dry period, 1,615.75 to 5,270.04 ng l^?1 in flood period, and 2,247.42 to 7,767.9 ng l^?1 in level period. The 16 EPA-PAHs concentrations were significantly increased in the order of level period > flood period > dry period. The composition pattern of PAHs in surface water was dominated by low molecular weight PAHs, in particular two- to three-ring PAHs. In addition, two-ring PAH accounted for 39.33 to 88.27 % of the total PAHs in level period. Low molecular weight PAHs predomination together with higher levels of PAHs in flood and level period suggested a relatively recent local source of PAHs. Special PAHs ratios such as phenanthrene/anthracene and fluoranthene/pyrene indicated that under dry weather season conditions, the PAHs found in surface water were primarily from petrogenic source, while under wet weather season conditions they were from mixed source of both petrogenic inputs and combustion sources. The comparison of PAHs contamination among different types of areas in China suggested that atmospheric depositions might be the most important approaches of PAHs into water system. Although the Hun River exists low PAHs ecological risk now, potential toxic effects will be existed in the future especially in flood and level period.     

Estimation of Vegetation Coverage in Semi-arid Sandy Land Based on Multivariate Statistical Modeling Using Remote Sensing Data

The estimation of vegetation coverage is essential in the monitoring and management of arid and semi-arid sandy lands. But how to estimate vegetation coverage and monitor the environmental change at global and regional scales still remains to be further studied. Here, combined with field vegetation survey, multispectral remote sensing data were used to estimate coverage based on theoretical statistical modeling. First, the remote sensing data were processed and several groups of spectral variables were selected/proposed and calculated, and then statistically correlated to measured vegetation coverage. Both the single- and multiple-variable-based models were established and further analyzed. Among all single-variable-based models, that is based on Normalized Difference Vegetation Index showed the highest R (0.900) and R ² (0.810) as well as lowest standard estimate error (0.128024). Since the multiple-variable-based model using multiple stepwise regression analysis behaved much better, it was determined as the optimal model for local coverage estimation. Finally, the estimation was conducted based on the optimal model and the result was cross-validated. The coefficient of determination used for validation was 0.867 with a root-mean-squared error (RMSE) of 0.101. The large-scale estimation of vegetation coverage using statistical modeling based on remote sensing data can be helpful for the monitoring and controlling of desertification in arid and semi-arid regions. It could serve for regional ecological management which is of great significance.     

城市燃气管道地震安全控制演示系统

介绍了一种用于展示城市燃气管道地震安全控制系统工作机理和控制效果的演示系统。对演示系统地震阀门的原理和性能作了阐述,对演示系统的组成、工作原理和效果做了较为详细的介绍。该系统可用于科普场馆或相关单位介绍城市燃气管道地震紧急处置的原理,系统已在唐山市地震博物馆安装应用。     

生活垃圾中废旧塑料的二次分选技术

由于城市垃圾中塑料品种繁杂、质量差,回收利用十分困难,国内外对于垃圾中的废旧塑料回收利用甚少。通过技术比选,确定采用多种分选技术的优势组合,以风力分选-X射线分选-光电分选相结合的组合工艺技术,实现对主要塑料品种PO,PS,PVC,PET等的有效分离,以加大废旧塑料的回收利用,减少环境污染,提高资源利用效率。