天然水体中亚硝酸根和硝酸根的光化学研究进展

综述了近年来亚硝酸根和硝酸根 (NO-2 /NO-3 )在天然水体中的环境光化学研究进展。重点介绍了NO-2 /NO-3 光解生成活性氧 (如羟基 )的机理及其影响因素 ,探讨了NO-2 /NO-3 光解引发天然水体中有机物反应的环境意义 ,并据此提出了本领域今后的研究方向     

纤维素废弃物水热处理制H2的研究进展

水热处理为纤维素废弃物资源化应用开辟了一条新的途径,文中就水热处理技术的特点、水热条件下纤维素的降解过程进行了介绍,并着重综述了纤维素废弃物水热制H2方面的研究进展,同时对纤维素及其废弃物的水热处理和资源化研究前景进行了展望.     

2种大气SO2监测浓度换算的研究

分别用常规法和碱片法对大气ＳＯ２进行同步监测,并用相关分析讨论了２者之间的相关性,结果表明：２者呈极显著的正相关,相关系数达０．７９４（ｎ＝１１）。它们的关系可以用方程：ｙ＝０．０９０ｘ－０．０３１来表示（其中ｙ为大气ＳＯ２浓度ｍｇ／ｍ＾３,ｘ为硫酸盐化速率ＳＯ３ｍｇ／（１００ｃｍ＾２．ｄ）同时还对方程的适用性进行了分析。     

高压静电处理水对活性污泥耗氧速率的影响研究

利用活性污泥微生物膜制成ＢＯＤ生物传感器,发现在经过一定时间高压静电处理后的缓冲液中,活性污泥降解有机物的能力可提高２０％以上,同一电压不同处理时间对微生物降解影响不同。处理时间过短或过长对微生物降解能力增加的影响都不明显,不同电压达到良好处理效果所需时间不同,较低电压所需时间较长,５０００Ｖ时约需６．０ｈ（信号响应达到初始值的１２４％）,而７０００Ｖ时约为４．０ｈ,结果表明,高压静电处理并接种活     

Synthesis of porous iron hydroxy phosphate from phosphate residue and its application as a Fenton-like catalyst for dye degradation

Phosphate residue is a kind of hazardous solid waste and if not properly disposed of, could cause serious environmental contaminations. The abundant iron salt available in phosphate residue can be used to prepare photo-Fenton catalytic reagent for wastewater treatment. In this study, the phosphate residue was effectively purified by a hydrothermal recrystallization method, reaching an iron phosphate purity of 94.2%. The particles of iron phosphate were further processed with ball milling with th...     

秦皇岛市城区园林绿化系统生态效益研究

针对秦皇岛市城区园林绿化系统的现状及存在的问题,提出了提高城市园林绿化生态效益要以人为本,要节约资源,坚持生态优先的原则,并针对当前绿化存在的问题提出了多项建议和对策。     

标准溶液直读法标定电导电极常数的探讨

目前电导率测定在实验室是一个十分普遍而重要的项目,标定电极常数的方法有直接测定法和比较测定法。在直接测定法的基础上,针对现代数显电导仪的特点,设计了标准溶液直读法标定电极常数,绕过了标定过程中需要测定电导G(电阻)的步骤。该方法直观易懂,操作简单,不需要计算,省时省力,适用于所有需要调节并能读出该电极常数的电导率仪。     

以应对自然灾害为核心的应急资源投入保障机制研究

应急资源是应急管理工作的重要支撑力量,其保障能力的形成是通过应急资源投入保障机制实现的。针对以应对自然灾害为核心的应急资源投入保障机制,以应急资源投入保障机制的五大主体(中央政府、地方政府、中央部门、地方部门、社会力量)为研究枢纽,系统地梳理了我国应急资源投入保障机制的现状;结合重大案例,以保障过程的三个环节(资金筹集、资金使用和保障能力形成、监督协调)为研究线索分析当前我国应急资源投入保障机制存在的问题,并寻找出其核心症结,即缺少专门的应急资金体系支持应急管理工作和没有统一的应急管理机构;针对核心症结,进行思考并提出相应的政策建议:设立应急管理专用资金体系和建立一体化的应急管理机构。     

Treatment of discarded oil in supercritical carbon dioxide for preparation of carbon microspheres

Carbon microspheres with diameter of 1–10 μm were prepared by treatment of waste oil in a supercritical carbon dioxide (scCO₂) system. The structure and morphology of the products were characterized by X-ray diffraction, field-emission scanning electron microscopy, and Raman spectrometry. It is shown that the products consist of graphite microspheres with relatively low graphitization. The yield of solid products increased from 26.8 wt% to 42.2 wt% as the reaction temperature was raised from 530°C to 600°C. Spheres with multilayer structure could be obtained by means of subsequent vacuum annealing of the carbon microspheres at 1500°C. The formation mechanisms of carbon microspheres in the scCO₂ system and the influence of vacuum annealing on the structure are discussed in detail.     

Synthesis and Properties of <Emphasis Type="Italic">N</Emphasis>-Maleyl Chitosan-Cross-Linked Poly(Acrylic Acid-co-Acrylamide) Superabsorbents

A high-swelling superabsorbent was synthesized with biodegradable N-maleyl chitosan as cross-linker, acrylic acid (AA) and acrylamide (AM) as the monomers, ammonium peroxodisulfate–sodium bisulfite (NaHSO₃) as redox initiation system, by means of aqueous solution polymerization. The best reaction condition was based on the orthogonal experiment design. The optimal conditions on distilled water absorbency and on 0.9 wt% NaCl solution absorbency were monomer concentration 20 wt%, mole ratio of AA to (AA + AM) 60%, the neutralization degree of AA 40%, cross-linker concentration 2% and monomer concentration 25 wt%, mole ratio of AA to (AA + AM) 60%, neutralization degree of AA 50% and cross-linker concentration 1%, respectively. Factors influencing the water absorbency of superabsorbent also were investigated, by single factor experiment method. The absorbency of superabsorbents in distilled water and 0.9 wt% NaCl solution increased and then decreased with the increasing of monomer concentration, mole ratio of AA to (AA + AM) and degree of neutralization of AA. With the increasing of cross-linker concentration, the absorbency in distilled water increased and then decreased, but it decreased all the time in 0.9 wt% NaCl solution. In enzymatic degradation tests, the weight loss of superabsorbent was related to the content of cross-linker.