Leaching behavior of heavy metals and PAHs from MSWI bottom ash in a long-term static immersing experiment

Bottom ash is the main solid residue (in weight) which is produced by municipal solid waste incineration (MSWI) facilities. This material is composed of a mineral matrix and may be used as secondary raw material for construction purpose. However, for this specific application the leaching behavior of the environmentally relevant elements under field conditions is different from the predicted behavior based on results obtained from the standardized leaching test. Therefore, a 70-day simulative experiment has been carried out in this study to investigate the release of major heavy metals (Cu and Pb) and polycyclic aromatic hydrocarbons (PAHs) from several particle fractions of bottom ash under a static leaching condition, where bottom ash was immersed in water at different initial pH values. Results showed that: (1) the leaching behavior of Cu and Pb was much similar with that depicted by the standardized leaching tests, and fit well with the solubility-controlling mechanism; (2) the sorption mechanism on the neoformed phases may control the solubility of Pb, whereas the dissolved organic carbon (DOC) may play an important role in the solubility of Cu; and (3) the leached PAHs were degraded during the later period of leaching process.     

城区天然气配气站噪声的产生及防治

城区天然气配气站噪声超标已成为供气部门亟待解决的难题,文章分析了配气站噪声污染现状,指出噪声产生原因主要为天然气流动,供气量增长使设备超负荷运行等7个方面。分别针对现有配气站和新建、改扩建站场提出降噪措施,指出设备在额定范围内运行、气体流速控制、工艺改造等是噪声控制的重要手段。并对城区天然气配气站噪声治理的进一步研究提出了建议。     

Aging activity of DDE in dissimilar rice soils in a greenhouse experiment

A green-house study was conducted in late 2005 to investigate the aging behavior of p,p'-DDE in two types of soil, Hydragric Anthrosols (An) and Hydragric Acrisols (Ac), according to the World Reference Base (WRB) [FAO/ISRIC/ISSS. 1998. World reference base for soil resources. World soil resources reports, Rome. p. 87]. Paddy rice and dry rice were grown in submerged paddy soils and non-submerged upland soils, respectively. The concentration of extractable p,p'-DDE in fresh DDE-spiked soils was 746.2ngg(-1). During the first few weeks of the experiment, the extractability of p,p'-DDE became increasingly low as the aging period prolonged. However, certain amount of p,p'-DDE that had been captured by soil minerals and organic matter (OM) could be released and became extractable in the later period. The extractability of p,p'-DDE in submerged soils was significantly lower than that in non-submerged soil, because flooding could increase the binding of pollutants to soil particles. The plantation of both dry rice and paddy rice slowed down the aging process of p,p'-DDE. After one month's growth of rice, p,p'-DDE bound to soil particles was released and became extractable. The OM and silt content of An are higher than that of Ac, resulting in more bound residues and relative lower extractability of p,p'-DDE in An. In addition, the extractability of p,p'-DDE could be reduced by the addition of rice straw to soils.     

计算机模拟研究UO2+2在人体细胞液的形态分布

建立了由多种金属离子和小分子配体组成的多相细胞液热力学平衡模型.模拟研究了UO2 2在组织液和细胞液的形态分布及CO2-3、氨三乙酸（NTA）和乙二胺四乙酸（EDTA）浓度对细胞液中UO2 2形态分布的影响.在组织液中,正常生理pH下,当各形态UO2 2总摩尔浓度 [U]= 1.0×10-6 mol/L 或[U]=1.0×10-3 mol/L时,UO2 2均主要以[UO2(CO3)3]4-和[UO2(CO3)2]2-形态存在.在细胞液中,当[U]=1.0×10-6 mol/L时,UO2 2主要以[UO2(CO3)3]4-和[UO2(CO3)2]2-存在;当[U]=1.0×10-3 mol/L,pH为6.0～6.8时,细胞液中存在大量的固相(UO2)3(PO4)2·4H2O,当pH为6.8～7.4时,UO2 2主要以[UO2(CO3)3]4-、[UO2(CO3)2]2-和[(UO2)2CO3(OH)3]-存在.细胞液中(UO2)3(PO4)2·4H2O含量随[U]升高而增加.通过调节细胞液pH和增加细胞液CO2-3浓度均能降低其固相UO2 2配合物含量.在细胞液中增加NTA会增加(UO2)3(PO4)2·4H2O含量,当添加EDTA时会显著降低(UO2)3(PO4)2·4H2O含量.     

Characterizing effects of uncertainties in MSW composting process through a coupled fuzzy vertex and factorial-analysis approach

A coupled fuzzy vertex and factorial-analysis approach was developed in this study for systematically characterizing effects of uncertainties in a municipal solid waste composting process. A comprehensive composting process model was also embedded into the system framework and used to address substrate decomposition and biomass growth, as well as the interactions between moisture contents, temperatures, and oxygen concentrations. The applicability of the proposed method was verified through a custom-made pilot-scale composting system. Results from fuzzy simulation indicated that the fuzzy vertex method could effectively communicate implicit knowledge into dynamic simulations and thus provide valuable information for enhancing composting process control under uncertainty. The factorial analysis was effective in quantifying the proportion to which the uncertainty of each single or interactive effect of model parameters contributes to the overall uncertainty of the system outcomes. Thus, sensitive parameters that may lead to errors or unreasonable predictions can be determined. The proposed study system could not only be used in characterizing combined effects of uncertainties for composting processes, but was also applicable to many other environmental modelling systems.     

地下水环境中甲基叔丁基醚运移过程的动力学模型

建立了地下水环境中甲基叔丁基醚(MTBE)运移过程的变系数动力学模型,并对模型进行了验证和参数灵敏度分析.模拟结果表明,地下水流速和阻滞系数对于MTBE的运移过程影响最为显著,而水动力弥散系数的影响较小,忽略其变化不会对预测地下水环境中污染物运移的环境动力学行为造成太大误差.由此得到的结论可定量研究MTBE在地下水环境中的对流.扩散特征,还可为MTBE污染地下水的预测预报、修复治理等研究提供科学依据.     

长江沉积物中痕量氯代酚类化合物的测定

本文利用同位素稀释质谱法对长江南京段沉积物中１８种氯代酚进行了分离鉴定,结果表明,沉积物中ＣＰｓ的含量以五氯苯酚为主,     

土壤中4-溴苯胺降解动力学及其生态毒性追踪

秀谷隆是一种被广泛应用的取代脲类除草剂,其主要降解产物为４－溴苯胺（４－ＢＡ）,研究４－溴苯胺在不同土壤中的降解动力学规律,并用土壤环境指示动物弹尾目跳虫Ｃｏｌｌｅｍｂｏｌａ（Ｆｏｌｓｏｍｉａ ｃａｎｄｉｄａ）跟踪指示该化合物在进一步降解过程中的毒性,结果表明：４－溴苯胺在土壤中的降解行为可用一级反应动力学方程来较好地描述,其生态毒性明显高于母体化合物秀谷隆,该化合物在粘土中的残留量低于砂土,但毒     

江苏省一次典型沙尘污染过程分析

2021年4月16日至4月18日江苏省经历了一次受沙尘影响的重污染过程.本次过程沙源地为蒙古国中南部及中国内蒙古中西部地区,在蒙古气旋后部西北大风影响下,沙尘气团自西北向东南影响了中国多个省市和地区.江苏省自16日起逐渐受到沙尘过程影响,苏北城市ρ(PM10)从凌晨开始迅速升高,浓度最高达569μg/m3,空气质量达严...     

密云县密云水库流域坡耕地养分流失特征

于2005年和2006年连续2 a对密云水库流域坡耕地进行水土流失小区试验,并完全按照当地农民习惯进行农事管理.试验结果表明:(1)降雨后坡耕地产生的地表径流量、泥沙量随坡度增大而增加,并与坡度正弦值呈一定的线性关系;(2)坡度对雨后地表径流和泥沙中养分含量影响不明显,但对泥沙养分流失量有明显影响;(3)养分流失以泥沙携带为主要途径,且通过泥沙携带途径流失的养分量占流失养分总量的比例随坡度增加而增加;(4)水库周边区域内坡耕地流失养分的主要来源为施用于坡耕地的化学肥料.(5)调整水库流域内坡耕地的种植结构、对坡耕地实施改造以截留或减少泥沙流失和控制化学肥料投入等措施对于治理流域内农业非点源污染、保护水源地水质显得尤为迫切.