欧盟跨界流域管理对我国水环境管理的借鉴意义

欧洲联盟在跨界流域管理方面取得了显著的成果,积累了丰富的经验,这对我国的水环境管理,尤其是跨界流域管理工作具有重要的借鉴意义。首先从立法保障、管理机构、运行机制、资金保障和公众参与等5个方面分析了欧盟跨界流域管理的经验和做法;并对我国水环境跨界管理现状进行了解析。在上述基础上,针对我国的水环境管理工作提出了3方面的建议,即：完善法律法规,明确各级政府对流域跨界断面的监管职责,充分利用市场机制,形成保护合力;制定流域综合管理规划,协调专项规划,确保跨界断面水生态保护目标的实现;鼓励公众参与,全方位促进和改善跨界流域管理工作。     

Nitrogen loss through lateral seepage in near-trench paddy fields

A near-trench paddy field experiment with five urea application rates (0-360 kg N ha(-1) in 90-kg increments) was conducted on a paddy soil in the Taihu Lake Region of China to elucidate N losses through lateral seepage during three rice (Oryza sativa L.) growing seasons. The total N (Nt), NH4(+) -N, and NO3(-) -N concentrations in the lateral seepage water increased with increasing N rates. The seasonal Nt fluxes by lateral seepage varied from 6.8 to 25.6 kg N ha(-1) for urea application rates of 90 to 360 kg N ha(-1). Lateral seepage accounted for 4.7 to 6.6% of the Nt applied, implying that lateral seepage was an important pathway of N loss from near-trench paddy fields. The cumulative N loss via lateral seepage was significantly related to N fertilization rate (P = 0.05). Floodwater level was also identified as a main factor affecting N losses via lateral seepage from paddy fields, as indicated by a positive linear relationship (R2 = 0.43) between floodwater level and daily lateral flow during the flooded period (P = 0.05). Under the conditions of these experiments, a shallow floodwater depth of 50 mm, urea application rates of 90 kg N ha(-1) or less, and no rainfall within 1 wk after N application reduced N losses by lateral seepage from paddy fields.     

云南省主体功能区综合交通运输网络建设对区域可达性影响

云南省地处我国西南边疆,随着经济的发展,交通可达性正逐渐成为该省经济发展的“瓶颈”。从可达性的概念入手,分析了目前云南省交通运输网络建设的空间格局及各类主体功区内存在的主要问题,针对各类功能区内交通运输结构中存在的问题给出了合理化建议,以期提高云南省交通的可达性。     

云南省优化开发区产业结构优化初探

优化产业结构对区域可持续发展,以及区域竞争力的提升具有重要意义。为保证区域经济又好又快的增长,优化产业结构是其关键。针对云南省优化开发区中的产业结构现状进行分析说明,指出其中的不合理之处,最后给出优化产业结构和进行产业结构内部调整的可行性建议。     

Evapotranspiration in the Meso‐Scale Forested Watersheds in Minjiang Valley,West China1

Abstract: Information on evapotranspiration (ET) can help us understand water balance, particularly in forested watersheds. Previous studies in China show that ET was relatively low (30‐40% of total precipitation) in the Minjiang Valley located in the upper reach of the Yangtze River Basin. However, this conclusion was derived from research on small‐scale watersheds (<100 km²). The objective of this paper was to present ET information on meso‐scale watersheds in the Minjiang Valley. Four meso‐scale watersheds (1,700‐5,600 km²) located in the Minjiang Valley were used to estimate ET using the water balance approach. We first generated forest vegetation variables (coniferous forest percentage, forest cover percentage, and derived forest vegetation index) using remote sensing data. Landsat 5 TM satellite images, acquired on June 26, 1994, were selected for the vegetation classification. Actual annual ET was calculated based on 11‐year estimated precipitation and measured streamflow data (1992‐2002). We also calculated potential ET (PET) using an improved Thornthwaite model for all four watersheds for the period of 1992‐1998. PET can provide additional information about potential capacity of water flux to atmosphere in the region. Seasonal (dry and rainy) PET and ET for all studied watersheds were also estimated for comparison purposes as the water balance approach, at shorter than annual scales, would likely provide inaccurate estimates of ET. The dominant vegetations in the Minjiang Valley were grasslands, conifer forests, and shrub‐lands. Our results confirmed that both ET and PET for three studied meso‐scale watersheds in the Minjiang Valley is relatively low (39.5‐43.8 and 28.2‐47.7% for ET and PET, respectively), with an exception of ET in the Yuzixi watershed being 71.1%. This result is generally consistent with previous research at small watershed scales. Furthermore, the low ET across various scales in the Minjiang Valley may be related to the unique deeply cut valley environment.     

Influence of complex reagents on removal of chromium(VI) by zero-valent iron

The removal of Cr(VI) by zero-valent iron (Fe(0)) and the effect of three complex reagents, ethylenediaminetetraacetic acid (EDTA), NaF and 1,10-phenanthroline, on this reaction were investigated using batch reactors at pH values of 4, 5 and 6. The results indicate that the removal of Cr(VI) by Fe(0) is slow at pH 5.0 and that three complex reagents play different roles in the reaction. EDTA and NaF significantly enhance the reaction rate. The zero-order rate constants at pH 5.0 were 5.44 microM min(-1) in the presence of 4mM EDTA and 0.99 micrM min(-1) in the presence of 8 mM NaF, respectively, whereas that of control was only 0.33 micrM min(-1), even at pH=4.0. This enhancement is attributed to the formation of complex compounds between EDTA/NaF and reaction products, such as Cr(III) and Fe(III), which eliminate the precipitates of Cr(III), Fe(III) hydroxides and Cr(x)Fe(1-)(x)(OH)(3) and thus reduce surface passivation of Fe(0). In contrast, 1,10-phenanthroline, a complex reagent for Fe(II), dramatically decreases Cr(VI) reduction by Fe(0). At pH=4.0, the zero-order rate constant in the presence of 1mM of 1,10-phenanthroline was 0.02 micrM min(-1), decreasing by 99.7% and 93.9%, respectively, compared with the results in the presence and absence of EDTA. The results suggest that a pathway of the reduction of Cr(VI) to Cr(III) by Fe(0) may involve dissolution of Fe(0) to produce Fe(II), followed by reduction of Cr(VI) by Fe(II), rather than the direct reaction between Cr(VI) and Fe(0), in which Fe(0) transfers electrons to Cr(VI).     

土壤总铬测定方法的改进

硝酸－－硫酸－－磷酸消解,高锰酸钾氧化,二苯碳酰二肼分光光度法检测土壤总铬是土壤总铬检测方法之一。文章在上述方法原理基础上通过实验进一步研究建立新方法。该方法检出限低0．075μg,灵敏度、准确度高,精度小于等于3％。新方法操作更科学,降低实验成本、省力、省时、准确、快捷。     

A novel model of organic waste composting in Taiwan military community

The relatively large quantities of waste generated daily in military barracks pose a significant impact on environments in this small island of Taiwan due to limited land and crowded populations. In order to find a suitable handling method to the barracks' characteristics in Taiwan, a comprehensive selection model for various barracks carrying out waste composting was established through personal interviews and questionnaire data analyses on the military barracks. From this, the basic data for this research was also built, to evaluate the experiences and management practices in these facilities. This study found that environmental responsibility and expertise are the primary concerns and considerations among all of the military units when doing waste composting. Support of the commander, organizational image and human resource/facilities are also concerns. To offer the military barracks a selection model and policy guidelines for the waste composting treatment, an itemized score evaluation standard and a selecting chart of composting recycling methods were designed by combining the practical experimental results with economic considerations, waste classification, and Delphi expert technique.     

Mineralization of C.I. Reactive Yellow 84 in aqueous solution by sonolytic ozonation

The operational parameters and mechanism of mineralization of C.I. Reactive Yellow 84 (RY84), one of the azo dyes, in aqueous solution were investigated using sonolytic ozonation (US/O(3) oxidation). Of the pseudo-first-order degradation rate constants of TOC reduction, 9.0 x 10(-4), 7.3 x 10(-3) and 1.8 x 10(-2)min(-1) were observed with US, O3, and a combination of US and O3, respectively. These results illustrate that ozonation combined with sonolysis for removal of TOC is more efficient than ozonation alone or ultrasonic irradiation alone without considering the operating costs. With the initial pH value at 10.0, the ozone dose at 4.5 g h(-1), the energy density of ultrasound at 176 W l(-1), and the initial concentration of RY84 at 100 mg l(-1), the extent of mineralization measured as TOC loss was maximized. The variation of the concentrations of related ions (oxalate, formate, acetate, NO3(-), NO2(-), NH4(+), Cl(-), and SO4(2-)) during the reaction process was monitored. Other organic intermediates detected by GC/MS were N-methyleneaniline, phthalic acid, 4-hydroxyphthalic acid, isocyanatobenzene, aniline, 4-iminocyclohexa-2,5-dien-1-one, butene diacid and urea. Based on these findings, a tentative degradation pathway was proposed.     

Biodegradation of nonylphenol polyethoxylates under Fe(III)-reducing conditions

Biodegradation behavior of nonylphenol polyethoxylates (NPEOs) under Fe(III)-reducing conditions was investigated. The study demonstrated that NPEOs could be rapidly biodegraded under Fe(III)-reducing conditions. Almost 60% of the total NPEOs were removed within three days and the maximum biodegradation rate was 34.95+/-0.84 microM d(-1). NPEOs were degraded via sequential removal of ether units under Fe(III)-reducing conditions. No nonylphenol polyethoxy-carboxylates (NPECs) were formed in this process. This ether removal process was coupled to Fe(III) reduction. Nonylphenol (NP), nonylphenol monoethoxylate (NP1EO), and nonylphenol diethoxylate (NP2EO) slightly accumulated in the anaerobic biodegradation process. The accumulation of these estrogenic metabolites led to a significant increase in the estrogenic activity during the biodegradation period. The calculated estrogenic activity reached its top on day 14 when the total concentration of these estrogenic metabolites was maximal. This is the first report of the primary biodegradation behavior of NPEOs under Fe(III)-reducing conditions. These findings are of major environmental importance in terms of the environmental behavior of NPEO contaminants in natural environment.