全文获取类型
收费全文 | 9778篇 |
免费 | 368篇 |
国内免费 | 3542篇 |
专业分类
安全科学 | 737篇 |
废物处理 | 644篇 |
环保管理 | 859篇 |
综合类 | 5070篇 |
基础理论 | 1646篇 |
环境理论 | 2篇 |
污染及防治 | 3622篇 |
评价与监测 | 392篇 |
社会与环境 | 319篇 |
灾害及防治 | 397篇 |
出版年
2024年 | 5篇 |
2023年 | 150篇 |
2022年 | 482篇 |
2021年 | 388篇 |
2020年 | 282篇 |
2019年 | 263篇 |
2018年 | 352篇 |
2017年 | 456篇 |
2016年 | 409篇 |
2015年 | 549篇 |
2014年 | 802篇 |
2013年 | 1045篇 |
2012年 | 897篇 |
2011年 | 888篇 |
2010年 | 687篇 |
2009年 | 654篇 |
2008年 | 734篇 |
2007年 | 584篇 |
2006年 | 496篇 |
2005年 | 368篇 |
2004年 | 287篇 |
2003年 | 352篇 |
2002年 | 304篇 |
2001年 | 252篇 |
2000年 | 260篇 |
1999年 | 244篇 |
1998年 | 248篇 |
1997年 | 242篇 |
1996年 | 222篇 |
1995年 | 173篇 |
1994年 | 118篇 |
1993年 | 122篇 |
1992年 | 104篇 |
1991年 | 79篇 |
1990年 | 54篇 |
1989年 | 26篇 |
1988年 | 27篇 |
1987年 | 10篇 |
1986年 | 17篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 8篇 |
1982年 | 9篇 |
1981年 | 8篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 844 毫秒
991.
X.X. Zhang P.J. Shi L.Y. Liu Y. Tang H.W. Cao X.N. Zhang X. Hu L.L. Guo Y.L. Lue Z.Q. Qu Z.J. Jia Y.Y. Yang 《Atmospheric environment (Oxford, England : 1994)》2010,44(13):1641-1648
Based on environmental monitoring data in 93 major cities and meteorological records at 398 weather stations in China from 1981 to 2007, total suspended particle (TSP) concentration, the intensity of dustfall, and sand and dust storm frequency (Fd) were analysed. During the past 27 years, the annual average TSP concentration (CTSP) in 93 cities was 402 μg m?3. Annual average CTSP decreased from the north to the south and from inland to the coast areas with a peak value of 628.8 μg m?3 in Lanzhou. In the 1980s, 1990s and 2000s, annual average CTSP was 628.7, 319.2, and 250.1 μg m?3, respectively. Annual average intensity of dustfall (Id) was 240.5 t km?2 a?1, decreased from northern to southern China and from inland to the coast areas with the maximum value of 717.2 t km?2 a?1 in Baotou. In the 1980s, 1990s and 2000s, annual average Id was 334.8, 220.9, 146 t km?2 a?1 respectively. Annual average Id in the Loess Plateau region was commonly higher than 200 t km?2 a?1. The annual average Fd decreased from arid regions in northwestern China to humid areas in southeastern China with two sand and sand storm centers existing in Xinjiang Taklamakan Desert and western Inner Mongolia. The annual average Fd in the 1980s, 1990s, 2000s was 16, 8, 6 days respectively, decreased steadily from 18 days in 1981–5 days in 2007. Annual average Id had a positive linear relation to annual average CTSP (R2 = 0.96). Annual average Fd had a positive relation with annual average CTSP (R2 = 0.97) as well as annual average Id (R2 = 0.94). TSP was the chief pollutant influencing Air Pollution Index (API) in northern China in spring and winter seasons. Sand and dust storm might be a major factor affecting the temporal variability and spatial distribution of TSP and dustfall in China. 相似文献
992.
993.
Beilei Lei Yimeng Ma Jiazhong Li Huanxiang Liu Xiaojun Yao Paola Gramatica 《Atmospheric environment (Oxford, England : 1994)》2010,44(25):2954-2960
Accurate quantitative structure–property relationship (QSPR) models based on a large data set containing a total of 3483 organic compounds were developed to predict chemicals’ adsorption capability onto activated carbon in gas phrase. Both global multiple linear regression (MLR) method and local lazy regression (LLR) method were used to develop QSPR models. The results proved that LLR has prediction accuracy 10% higher than that of MLR model. By applying LLR method we can predict the test set (787 compounds) with Q2ext of 0.900 and root mean square error (RMSE) of 0.129. The accurate model based on this large data set could be useful to predict adsorption property of new compounds since such model covers a highly diverse structural space. 相似文献
994.
David Widory Xiande Liu Shuping Dong 《Atmospheric environment (Oxford, England : 1994)》2010,44(30):3679-3687
Even after its being phased out in gasoline in the late 90s, lead (Pb) is still present at relatively high levels in the atmosphere of Beijing, China (0.10–0.18 μg m?3). Its origin is subject to debate as several distinct sources may contribute to the observed pollution levels. This study proposes to constrain the origin(s) of Pb and strontium (Sr) in aerosols, by coupling both Pb and Sr isotope systematics. The characterisation of the main pollution sources (road traffic, smelters, metal refining plants, coal combustion, cement factories, and soil erosion) shows that they can unambiguously be discriminated by the multi-isotope approach (206Pb/204Pb and 87Sr/86Sr). The study of total suspended particulates (TSP) and fine particles (PM2.5) from Beijing and its vicinity indicates that both size fractions are controlled by the same sources. Lead isotopes indicate that metal refining plants are the major source of atmospheric lead, followed by thermal power stations and other coal combustion processes. The role of this latter source is confirmed by the study of strontium isotopes. Occasionally, emissions from cement plants and/or input from soil alteration are isotopically detectable. 相似文献
995.
Jinzhu Ma Yongchun Liu Hong He 《Atmospheric environment (Oxford, England : 1994)》2010,44(35):4446-4453
To further understand the role of substrates on the heterogeneous reactions of polycyclic aromatic hydrocarbons, the reactions of ozone with anthracene adsorbed on different mineral oxides (SiO2, α-Al2O3 and α-Fe2O3) and on Teflon disc were investigated in dark at 20 °C. No reaction between ozone and anthracene on Teflon disc was observed when the ozone concentration was ~1.18 × 1014 molecules cm?3. The reactions on mineral oxides exhibited pseudo-first-order kinetics for anthracene loss, and the pseudo-first-order rate constant (k1,obs) displayed a Langmuir–Hinshelwood dependence on the gas-phase ozone concentration. The adsorption equilibrium constants for ozone (KO3) on SiO2-1, SiO2-2, α-Al2O3 and α-Fe2O3 were (0.81 ± 0.26) × 10?15 cm3, (2.83 ± 1.17) × 10?15 cm3, (2.48 ± 0.77) × 10?15 cm3 and (1.66 ± 0.45) × 10?15 cm3, respectively; and the maximum pseudo-first-order rate constant (k1,max) on these oxides were (0.385 ± 0.058) s?1, (0.101 ± 0.0138) s?1, (0.0676 ± 0.0086) s?1 and (0.0457 ± 0.004) s?1, respectively. Anthraquinone was identified as the main surface product of anthracene reacted with ozone. Comparison with previous research and the results obtained in this study suggest that the reactivity of anthracene with ozone and the lifetimes of anthracene adsorbed on mineral dust in the atmosphere are determined by the nature of the substrate. 相似文献
996.
997.
998.
999.
二氧化碳水合物储气特性的实验研究 总被引:2,自引:0,他引:2
利用二氧化碳水合物小型实验装置分别在恒容和恒压条件下,研究了机械搅拌对二氧化碳气体溶解的影响以及温度与水-气比对二氧化碳水合物形成和储气密度的影响。通过实验结果发现,机械搅拌对二氧化碳的溶解有非常明显的促进作用,可以在3 min内完成溶解过程,促进溶解作用好于添加剂SDS。研究还发现,反应温度越低,二氧化碳水合物的生成速率越快,总的储气量越大,而水-气比越大,储气密度越小。在实验压力3 MPa、反应温度273.55 K的条件下,1体积的水生成水合物后可储存157体积的二氧化碳。 相似文献
1000.
铁炭复配修复地下水中NO_3~--N的条件研究 总被引:2,自引:0,他引:2
采用了铁炭复配修复地下水中NO3--N,探讨了实验条件对修复效果的影响。结果表明,在pH值近中性条件(初始pH 6.42)下,反应时间为1 h时NO3--N修复率达到60.85%;Fe/C=1∶1时介质最佳用量分别为4~5 g;Fe/C=1/1.5时修复率为72.80%;反应速率在高振荡强度下大于低振荡强度;氧化铜的催化效果最好,可使修复率提高7.5个百分点。铁炭复配介质修复地下水中NO3--N是有效可行的,修复率随反应时间的增加而提高,在Fe/C=1∶1时修复率与介质用量呈正相关,无限减小Fe/C比并不能无限提高修复率,振荡强度对修复具有显著影响,低振荡强度下的修复过程较高强度存在滞后现象,并非所有金属氧化物催化剂对铁炭修复NO3--N均有促进作用。 相似文献