基于BP神经网络的企业HSE管理绩效评估

提出了根据日常HSE过程考核指标,构建基于BP神经网络的评价模型,利用神经网络较强的自培训学习、模糊推理、非线性逼近及容错能力,探索日常HSE过程考核指标与HSE绩效评估之间的函数关系,获得较为满意的绩效评估结果。经过对评估模型的评价及检验,该方法具有较好的操作性和较高的准确性。     

钻井抽吸和激动压力安全系数分析

基于流体力学和波动压力理论,研究了抽吸、激动压力安全系数的计算方法,分析结果表明,抽吸、激动压力随钻井液黏度、密度、井深的增加而增大,且与钻柱上、下行速度密切相关;大井眼中抽吸、激动压力较小,小井眼抽吸、激动压力较大;地层渗透性在一定程度也会影响抽吸、激动安全系数的取值。为不同地层钻井时合理安全地设计与调整钻井液密度,减少储层伤害提供了理论基础．     

新型颗粒粉煤灰净水剂对六价铬的吸附

采用自制颗粒粉煤灰净水剂,研究其对水溶液中的六价铬离子的吸附性能和影响因素,探讨了该净水剂对六价铬的吸附机理。研究表明:颗粒粉煤灰能有效吸附水溶液中的六价铬离子;影响吸附效果的因素重要性顺序为:pH>净水剂投加量>振荡时间>温度;该净水剂对六价铬吸附与Langmuir吸附等温方程和Freundlich吸附等温方程均很吻合,属于单分子层吸附;液膜扩散起主要作用,吸附过程符合二级动力学方程。     

Investigation of carbonyl compound sources at a rural site in the Yangtze River Delta region of China

Carbonyl compounds are important intermediates in atmospheric photochemistry, but their primary sources are still not understood well. In this work, carbonyls, hydrocarbons,and alkyl nitrates were continuously measured during November 2011 at a rural site in the Yangtze River Delta region of China. Mixing ratios of carbonyls and hydrocarbons showed large fluctuations during the entire measurement. The average level for total measured volatile organic compounds during the pollution episode from 25 th to 27 th November, 2011 was 91.6 ppb, about 7 times the value for the clean period of 7th–8th, November, 2011. To preliminarily identify toluene sources at this site, the emission ratio of toluene to benzene(T/B) during the pollution episode was determined based on photochemical ages derived from the relationship of alkyl nitrates to their parent alkanes. The calculated T/B was5.8 ppb/ppb, significantly higher than the values of 0.2–1.7 ppb/ppb for vehicular exhaust and other combustion sources, indicating the dominant influence of industrial emissions on ambient toluene. The contributions of industrial sources to ambient carbonyls were then calculated using a multiple linear regression fit model that used toluene and alkyl nitrates as respective tracers for industrial emission and secondary production. During the pollution episode, 18.5%, 69.0%, and 52.9% of measured formaldehyde, acetaldehyde, and acetone were considered to be attributable to industrial emissions. The emission ratios relative to toluene for formaldehyde, acetaldehyde, and acetone were determined to be 0.10, 0.20 and0.40 ppb/ppb, respectively. More research on industrial carbonyl emission characteristics is needed to understand carbonyl sources better.     

基于本土物种的3种典型化合物急性生态效应阈值研究

预测无效应浓度(PNEC)是进行风险污染物水生态安全管理的重要依据。本研究进行了3种典型化合物五氯酚、硝基苯和氯化镉对10种我国不同营养级水生生物的24 h、48 h和96 h的急性毒性测试,根据实验结果计算了相应的急性PNEC,同时与根据美国环境保护局毒性数据库里的毒性数据计算获得的急性PNEC值,以及综合本实验结果与毒性数据库里的数据计算得到的急性PNEC值进行对比,发现通过3种数据来源获得的急性PNEC值中,硝基苯的PNEC值差异较大,由本次实验结果获得的急性PNEC值最小;其他2种化合物差异较小。这可能是由于本次实验所选的本土生物中华田螺和麦穗鱼对硝基苯比较敏感,并且数据库中硝基苯的急性致死数据较少、毒性值较大且变化范围较窄,而其他2种化合物数据量较为丰富,变化范围较宽,包括了较敏感物种的毒性数据。这表明为给我国水生生物提供一个安全可靠的保护,对于数据量较为丰富并且毒性值变化较宽的化合物(如五氯酚和氯化镉)可以直接根据数据库里的毒性数据进行PNEC值的计算;而对于毒性数据量较少、毒性值偏大且变化较窄的化合物(如硝基苯)需要进行本土敏感物种的毒性测试。     

铜锈环棱螺室内实验条件优化

铜锈环棱螺作为一种新兴的潜在生态毒理学模式生物,适宜实验条件是开展其室内毒理学研究的基础。在人为控制条件下,初步探讨了饵料、水深、底质、密度和钙离子浓度养殖条件对铜锈环棱螺成体生长的影响,并进一步对麻醉条件进行了筛选(Mg Cl2·2H2O、乙醇、丁香酚、盐酸普鲁卡因和MS-222)。结果表明:当投喂冰鲜小球藻、密度6个·L-1水体积、水深10~15cm、泥土底质并且水中钙离子浓度30 mg·L-1时,铜锈环棱螺的体重增长最为明显。麻醉效果表明,Mg Cl2·2H2O对成螺的麻醉时间短并且伤害小,可作为实验用麻醉剂首选。以上研究结果为发展以铜锈环棱螺为模式生物开展环境(生态)毒理学研究奠定了基础。     

科技创新在生态文明建设中的作用和贡献

科技创新是第一生产力,生态文明建设同样需要依靠科技创新来支撑。本文通过分析科技创新与生态文明建设的关系,定量化分析了科技进步对污染减排的重要贡献作用,识别了现阶段科技创新促进生态文明建设的主要途径,并从提高科学认识、构建指标体系、研发关键创新技术、完善政策体系、培养科技人才等方面提出未来依靠科技创新促进生态文明建设的战略对策。     

EKC analysis for studying economic growth and environmental quality: a case study in China

Compared with the extensive research on the relationship between economic growth and environmental quality in developed countries, there is a paucity of an empirical research on studying the relation for developing countries. Based upon the Environmental Kuznets Curve (EKC) theory, this paper develops regression models for investigating the relationship between economic growth and environmental quality in China. The EKC analysis based on six pollution indices is illustrated with a case study in Jiaxing of Zhejiang, China.     

Characterization of solid waste disposed at Columbia Sanitary Landfill in Missouri.

Waste sorts were conducted during each of the four quarters (or seasons) of 1996 at the City of Columbia Sanitary Landfill. A detailed physical sampling protocol was outlined. Weight fractions of 32 waste components were quantified from all geographic areas that contribute to the Columbia Sanitary Landfill using a two-way stratification method, which accounted for variations in geographical regions and seasons. Comparisons of solid waste generated between locations and seasons were conducted at the 80% confidence level. The composition of the entire waste stream was 41% paper, 21% organic, 16% plastic, 6% metal, 3% glass and 13% other waste. Paper was the largest composition and glass was the smallest composition for all geographical regions. The result of this study was also compared with a 1987 Columbia, Missouri study conducted by EIERA (1987), with studies conducted in other states such as Minnesota, Wisconsin, Oregon and with national study conducted by the USEPA (USEPA 530-R-96-001, PB96-152 160. US Environmental Protection Agency, Office of Solid Waste, Washington, DC). The results of studies from other states are different from this study due to different local conditions, different methodologies and a different scope. There was a small (5%) increase in per capita weight from 1987 to 1996. The total per capita weight in the present study was 60% greater than the national per capita weight reported by the USEPA (1996) due to that the USEPA report excluded industrial, construction and certain commercial waste. The total per capita weight agrees with the national per capita weight for municipal waste reported by Tchobanoglous (1993), which included industrial, construction and commercial sources. The geographical and seasonal effects on the waste composition are evaluated and discussed. Statistical analysis indicates that waste characteristics are different among geographical regions and seasons. The potential for waste recovery and reduction is also discussed.