全文获取类型
收费全文 | 398篇 |
免费 | 6篇 |
国内免费 | 9篇 |
专业分类
安全科学 | 10篇 |
废物处理 | 18篇 |
环保管理 | 44篇 |
综合类 | 78篇 |
基础理论 | 65篇 |
污染及防治 | 136篇 |
评价与监测 | 43篇 |
社会与环境 | 14篇 |
灾害及防治 | 5篇 |
出版年
2023年 | 6篇 |
2022年 | 7篇 |
2021年 | 18篇 |
2020年 | 2篇 |
2019年 | 2篇 |
2018年 | 13篇 |
2017年 | 18篇 |
2016年 | 15篇 |
2015年 | 11篇 |
2014年 | 21篇 |
2013年 | 36篇 |
2012年 | 22篇 |
2011年 | 32篇 |
2010年 | 23篇 |
2009年 | 21篇 |
2008年 | 21篇 |
2007年 | 14篇 |
2006年 | 18篇 |
2005年 | 21篇 |
2004年 | 21篇 |
2003年 | 11篇 |
2002年 | 12篇 |
2001年 | 14篇 |
2000年 | 7篇 |
1999年 | 6篇 |
1998年 | 1篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1973年 | 2篇 |
1969年 | 1篇 |
1956年 | 2篇 |
排序方式: 共有413条查询结果,搜索用时 15 毫秒
401.
A geometric method based on Langmuir kinetics has been derived to determine adsorption and desorption kinetic constants. In the conventional procedure, either the adsorption kinetic constant (k(a)c) or desorption kinetic constant (k(d)c) is found from kinetic experiments and the other is calculated by their correlation with the equilibrium constant, i.e, k(d)c = Kcon/k(a)c, where Kcon has been known from equilibrium studies. The determined constants (Kcon, k(a)c, k(d)c), if based only on the conventional procedure, may not be accurate due to their mathematical dependence. Therefore, the objectives of this study are applying a geometric approach to directly determine Langmuir kinetic constants and describe adsorption behavior. In this approach, both adsorption kinetic constant (k(a)g) and desorption kinetic constant (k(d)g) are obtained only from data of kinetic experiments, and a geometric equilibrium constant (Kgeo) is calculated by Kgeo = k(a)g/k(d)g. The deviation between Kgeo and Kcon can prove the accuracy of k(a)g and k(d)g which were determined by this method. This approach was applicable to selenate, selenite and Mg2+ adsorption onto SiO2 regardless of whether the adsorbate formed inner- or outer-sphere complexes. However, this method showed some deviation between Kcon and Kgeo for Mn2+ adsorption because of the formation of surface Mn(II)-hydroxide clusters, which was inconsistent with the basic assumption of this method of monolayer adsorption. 相似文献
402.
Preparation of cross-linked magnetic chitosan with quaternary ammonium and its application for Cr(VI) and P(V) removal 总被引:2,自引:0,他引:2
Pollutants that exist in anionic species are issues of concern in water treatment. Compared to cationic pollutants, the removal of anionic pollutants by adsorption is more difficult because most adsorbents carry predominantly negative charges in neutral and alkaline environments. In this study, a cross-linked chitosan derivative with quaternary ammonium and magnetic properties(QM-chitosan) was prepared and employed to remove chromium(VI) and phosphorus(V)(Cr(VI) and P(V)) from aqueous environments. The QM-chitosan was characterized by Fourier transform infrared spectrometry(FT-IR),thermogravimetric analysis(TGA), energy dispersive X-ray(SEM-EDX) and zeta potential.Batch experiments show that QM-chitosan can effectively remove Cr(VI) and P(V), and the main mechanism was believed to be electrostatic interaction. A pseudosecond-order model was fitted to describe the kinetic processes of Cr(VI) and P(V) removal. The adsorption isotherms of both Cr(VI) and P(V) on the QM-chitosan were well fitted by the Langmuir isotherm equation. The saturated adsorption capacity of P(V)(2.783 mmol/g) was found to be higher than that of Cr(VI)(2.323 mmol/g), resulting from the size of the H2PO-4ions being smaller than that of the HCr O-4ions. However, the theoretical calculation and experimental results showed that QM-chitosan had a stronger affinity for Cr(VI) than P(V). The adsorption–desorption of the QM-chitosan was evaluated, and high regeneration rates were demonstrated. 相似文献
403.
Stefano Colazza Mauro Lo Bue Daniela Lo Giudice Ezio Peri 《Die Naturwissenschaften》2009,96(8):975-981
Chemical footprints left behind by true bugs are perceived as contact kairomones by scelionid egg parasitoids. Female wasps
encountering a contaminated artificial substrate display a characteristic arrestment posture, holding the body motionless
and antennating the surface. In the system Nezara viridula (L.) and its egg parasitoid Trissolcus basalis (Wollaston), previous studies have shown that the kairomone mediating such behavior is part of N. viridula’s cuticular hydrocarbons (CHC) and furthermore that the wasp’s ability to discriminate host male and female footprints is mainly
based on the presence/absence of nonadecane (nC19). In this study, the effect of epicuticular waxes of leaves of broad bean, Vicia faba, on wasp responses to footprints of N. viridula females were investigated. Approximately 20% of T. basalis females displayed an arrestment posture when released on the adaxial leaf surfaces of broad bean plants with intact wax layer
and without host chemical contamination; whereas ∼70% of wasps displayed the arrestment posture when intact leaves were contaminated
by host female footprints. Adaxial leaf surfaces of broad bean plants dewaxed with an aqueous solution of gum arabic and afterwards
contaminated by N. viridula females induced arrestment responses in about 10% of female wasps; the same percentage of arrestment (10%) was observed when
the wasps were released on leaves contaminated by host females and subsequently dewaxed. The side of the polymer film that
was appressed to the leaf surface, peeled from the contaminated leaves, induced an arrestment posture in about 95% of observed
wasps. Scanning electron microscopy (SEM) revealed that the epicuticular waxes occurred as a film densely crystallized as
irregularly shaped platelets with spherical granules randomly distributed. These findings demonstrated that epicuticular waxes
of broad bean leaves can mediate the foraging behavior of T. basalis females by absorbing contact kairomones of the host. 相似文献
404.
Contributions of biofilm and suspended sludge to nitrogen transformation and
nitrous oxide emission in hybrid sequencing batch system 总被引:2,自引:0,他引:2
Ingwei Wayne Lo Kwang Victor Lo Don S Mavini Dean Shiskowski William Ramey 《环境科学学报(英文版)》2010,22(7):953-960
Hybrid system combines the nature of suspended growth and attached growth has been widely applied to wastewater treatment.
In this research, the contributions to N transformation and N2O emission by biofilm and suspended sludge in the hybrid sequencingbatch
reactor for a simultaneous nitrification, denitrification and phosphorus removal process were investigated. For the hybrid system,
nitrification occurred mostly in the suspended sludge, while the biofilm played the major role in denitrification. The interaction of
the biofilm and the suspended sludge in the same reactor resulted in a better overall nitrogen removal performance with simultaneous
nitrification and denitrification. However, N2O emission was the main end product of nitrogen removal for the hybrid system; while
it was N2 for the biofilm. The relative low N2O emissions from the pure biofilm and the pure suspended sludge corresponded to the
relatively high nitrate at the end of the aeration period compared with the hybrid system. 相似文献
405.
闽江河口湿地互花米草入侵机制 总被引:8,自引:0,他引:8
为了阐明湿地植物入侵的机制,选择闽江河口湿地为研究区域,通过野外采样和室内分析,对入侵种互花米草和土著种短叶茳芏根冠生物量、养分在植物体内的分配以及植物养分的生态化学计量学特征进行了测定与分析。结果表明:①互花米草根冠比季节变化范围是0.49~1.64,平均值为1.11,低于短叶茳芏(变化范围是3.11~7.95,平均值为5.29);②互花米草季节平均的氮磷养分分配顺序为叶>根>茎,而土著种短叶茳芏按照叶>茎>根的顺序分配;③互花米草叶、茎季节平均C/N和C/P均表现出高于短叶茳芏,而根则低于短叶茳芏,N/P则均表现为互花米草叶、茎、根高于短叶茳芏;④较高的地上生物量分配、同化器官(叶)和繁殖器官(根)养分分配以及C/N、C/P和N/P是互花米草得以成功入侵的主要原因之一。 相似文献
406.
Combining material characterization with single and multi-oxyanion
adsorption for mechanistic study of chromate removal by cationic hydrogel 总被引:1,自引:1,他引:0
Cationic hydrogel with magnetic property was synthesized via radical polymerization and its removal capacity of chromate from
contaminated water was found to be 200 mg/g. Using Fourier transform infrared spectroscopy (FT-IR) study, the mechanism of
chromate removal by hydrogel was found to be non-specific adsorption, mainly due to ion exchange, as evidenced by the positively
charged functional group, trimethyl ammonium –N+(CH3)3; in the monomer. Verifications were accordingly determined by testing
different oxyanion adsorption onto the hydrogel. The results of the chromate adsorption experiments illustrated that the amount
of chromate adsorbed was nearly equal to that of the chloride released from the hydrogel, which is part of the evidence for ion
exchange. Single and multi-oxyanion adsorption experiments were also performed, and it was demonstrated that ion removal was
species independent, but charge dependent, another characteristic of the ion exchange process. It was found that the same Langmuir
model can be applied to best fit the findings of single and multi-oxyanion adsorption, which further indicates the mechanism of chromate
removal is attributed to ion exchange. In view of the above, the background anions compete for adsorption sites with chromate,
evidenced by inhibitive chromate removal in the presence of background electrolytes in the batch studies, further echoing the ion
exchange mechanism. 相似文献
407.
Médoc V Rigaud T Motreuil S Perrot-Minnot MJ Bollache L 《Die Naturwissenschaften》2011,98(10):825-835
Although trophically transmitted parasites are recognized to strongly influence food-web dynamics through their ability to manipulate host phenotype, our knowledge of their host spectrum is often imperfect. This is particularly true for the facultative paratenic hosts, which receive little interest. We investigated the occurrence and significance both in terms of ecology and evolution of paratenic hosts in the life cycle of the fish acanthocephalan Pomphorhynchus laevis. This freshwater parasite uses amphipods as intermediate hosts and cyprinids and salmonids as definitive hosts. Within a cohort of parasite larvae, usually reported in amphipod intermediate hosts, more than 90% were actually hosted by small-sized fish. We demonstrated experimentally, using one of these fish, that they get infected through the consumption of parasitized amphipods and contribute to the parasite's transmission to a definitive host, hence confirming their paratenic host status. A better knowledge of paratenic host spectrums could help us to understand the fine tuning of transmission strategies, to better estimate parasite biomass, and could improve our perception of parasite subwebs in terms of host-parasite and predator-parasite links. 相似文献
408.
Nutrient release and sediment oxygen demand in a eutrophic land-locked embayment in Hong Kong 总被引:15,自引:0,他引:15
Tolo Harbour is a large eutrophic land-locked estuarine embayment in Hong Kong. The rapid urbanization, commercio-industrial activities and lack of legislative control around the Tolo catchment produced large quantities of untreated or partially treated municipal sewage, agricultural wastes and cottage industrial effluents which were discharged into Tolo Harbour via rivers and watercourses. Control measures were implemented to reduce the external nutrient loading into the harbour since the early 1980s. Nutrient data for the period 1982 to 1997 were analyzed for temporal trends. Over the period of observation, the total inorganic nitrogen and total phosphorus both show an increasing trend, despite a decade of efforts in reducing nutrient loading. The release rates of potentially mobile nitrogen (N) and phosphorus (P) from the sediments collected from Tolo Harbour were determined by N and P release experiments under oxic conditions. The experimental results showed that the sediment released significant amount of nutrients, especially orthophosphates and ammonia nitrogen. The maximum release rates were 15.0 and 206.0 mg/m2/day, respectively. Although the external nutrient loading has been reduced, nutrients could gradually be released back into the water column from the contaminated sediments and delay improvement of the water quality. 相似文献
409.
Abidi Samira Trabelsi Aïda Ben Hassen Boudhrioua Nourhene 《Journal of Material Cycles and Waste Management》2023,25(1):235-248
Journal of Material Cycles and Waste Management - Lemon peel waste (LPW) were pyrolysed in a laboratory fixed-bed reactor at final temperature of 300 °C, 400 °C and... 相似文献
410.
Hua Yi-di Hu Ke-man Qiu Lu-yi Dong Hong-an Ding Lei Lo Sio-Long 《Environment, Development and Sustainability》2022,24(10):12097-12130
Environment, Development and Sustainability - Exploring interaction of Beautiful China and SciTech Innovation is an important way to realize economic transformation and sustainable development in... 相似文献