Characteristics of secondary inorganic aerosol and sulfate species in size-fractionated aerosol particles in Shanghai

Sulfate, nitrate and ammonium(SNA) are the dominant species in secondary inorganic aerosol, and are considered an important factor in regional haze formation. Size-fractionated aerosol particles for a whole year were collected to study the size distribution of SNA as well as their chemical species in Shanghai. SNA mainly accumulated in fine particles and the highest average ratio of SNA to particulate matter(PM) was observed to be 47% in the fine size fraction(0.49–0.95 μm). Higher sulfur oxidation ratio and nitrogen oxidation ratio values were observed in PM of fine size less than 0.95 μm. Ion balance calculations indicated that more secondary sulfate and nitrate would be generated in PM of fine size(0.49–0.95 μm). Sulfur K-edge X-ray absorption near-edge structure(XANES) spectra of typical samples were analyzed. Results revealed that sulfur mainly existed as sulfate with a proportion(atomic basis) more than 73% in all size of PM and even higher at 90% in fine particles. Sulfate mainly existed as(NH4)2SO4 and gypsum in PM of Shanghai. Compared to non-haze days, a dramatic increase of(NH4)2SO4 content was found in fine particles on haze days only, which suggested the promoting impact of(NH4)2SO4 on haze formation. According to the result of air mass backward trajectory analysis, more(NH4)2SO4 would be generated during the periods of air mass stagnation. Based on XANES, analysis of sulfate species in size-fractionated aerosol particles can be an effective way to evaluate the impact of sulfate aerosols on regional haze formation.     

贵州施秉白云岩喀斯特区水化学和溶解无机碳稳定同位素特征

对贵州施秉白云岩喀斯特世界自然遗产地49个水点进行采样,分析地表水和地下水水化学特征及控制因素,并探讨溶解无机碳(DIC)稳定同位素的分布特征和来源.结果发现,研究区地表水和地下水p H值呈中性到碱性,溶解质较低,水中阳离子以Ca2+、Mg2+为主,阴离子以HCO-3为主,水化学类型为重碳酸-钙镁型(HCO3-Ca·Mg).北部上游页岩分布区外源水水中Cl-、NO-3、SO2-4的比重相对白云岩区喀斯特水水点的高,Si的含量也明显高于白云岩地区喀斯特水;外源水的SIc和SId值为负,而流经白云岩区后均大于0.水化学数据表明研究区水化学受降水和人为活动影响很小,Gibbs图显示水中离子组成主要受岩性的控制.研究区喀斯特地表水中δ13CDIC值变化范围为-8.27‰~-11.55‰,平均为-9.45‰,地下水的δ13CDIC值范围为-10.57‰~-15.59‰,平均为-12.04‰,地表水δ13CDIC值比地下水偏重.DIC的δ13CDIC值在杉木河支流上整体表现为河流上游相对于下游偏轻,而杉木河干流上河水DIC的δ13CDIC值的变化则比较复杂.根据同位素质量平衡,利用DIC的δ13CDIC实测值,计算了喀斯特区地下水DIC来自土壤CO2和白云岩矿物溶解的比例,计算结果为51.2%来自于土壤CO2,矿物本身的贡献约为48.8%.     

Removal of SO2 from O2-containing flue gas by activated carbon fiber (ACF) impregnated with NH3

Adsorption of SO(2) from the O(2)-containing flue gas by granular activated carbons (GACs) and activated carbon fibers (ACFs) impregnated with NH(3) was studied in this technical note. Experimental results showed that the ACFs were high-quality adsorbents due to their unique textural properties. In the presence of moisture, the desulphurization efficiency for the ACFs was improved significantly due to the formation of sulfuric acid. After NH(3) impregnation of ACF samples, nitrogen-containing functional groups (pyridyl C(5)H(4)N- and pyrrolyl C(4)H(4)N-) were detected on the sample surface by using an X-ray photoelectron spectrometer. These functional groups accounted for the enhanced SO(2) adsorption via chemisorption and/or catalytic oxidization.     

贸易协定对我国污染排放的影响后评价模型初步研究

当今世界全球化推进到一个新的阶段,全球双边/区域贸易协定的数量呈现不断上升的趋势,而贸易自由化在促进经济扩张的同时,也导致资源的大量消耗和污染排放。因此需要建立有关环境影响评价机制,及时跟踪反馈,有针对性地引导中国出口方向的转变和进口水平的提升,为落实后续的监督管理,以及我国在贸易协定谈判或协定升级谈判中处理贸易与环境问题提供决策建议。在国内外已普遍开展贸易协定环境影响预评价并忽略后评价的背景下,本文选取工业行业大气污染排放作为指标,通过整合现有的贸易协定对经济影响测算的因素剥离方法以及经济对环境影响测算的环境投入产出分析方法,初步构建贸易协定对我国工业污染排放的影响后评价模型。建议下一步:建立贸易协定环境影响评价制度,定期开展评估;积极跟踪并参与国际贸易谈判,适时向商务部门提出打造绿色贸易的建议;加强环境与贸易领域能力建设,提升我国应对环境与贸易问题的能力。     

构建新农村防震减灾规划体系的初步探讨

本文从地震灾害的破坏概况入手,结合当前新农村防震减灾规划存在的问题,揭示了新农村防震减灾规划体系要点,以供读者把握我国新农村规划建设的整体印象,在新农村规划中具有一定的理论价值和实际指导意义。     

Transaction of Marine Fishing Right： Theoretical Analysis

The difference between fishermen＇s fishing catch and the optimal fishing catch is the basic reason for the transaction of marine fishing rights （TMFR）. The effects of productive cost, non-productive cost, use-cost, transaction cost, productive revenue and non-productive revenue on the TMFR and the optimal fishing catch are analyzed. This paper draws following conclu- sions： the non-productive revenue has a positive effect on the TMFR, and other factors, such as non-productive cost, usecost and transaction cost, have a negative effect; the TMFR will promote the resource allocation; the high transaction cost may affect the implementation of TMFR.     

农业现代化、信息化与农业面源污染研究

利用2003年-2013年中国30个省份的面板数据,检验了农业现代化、信息化与农业面源污染之间的关系.研究发现,农业现代化对农业面源污染有着一定的加重作用;信息化能够有效缓解因农业现代化所导致的农业面源污染,这一现象在粮食主产省同样存在,说明信息化能够发挥减污增绿的作用;农业环境库兹涅茨曲线(EKC)也得到验证.因此,应进一步推进信息化发展,有效利用信息化对农业现代化所致农业面源污染的缓解作用,还应多措并举促进农民增收,加快农民收入越过EKC曲线拐点.     

222RN IN THE WATER DISTRIBUTION SYSTEM OF TUCSON,ARIZONA1

ABSTRACT: A study of ²²²Rn concentrations in the water distribution system of Tucson, Arizona, revealed levels of 60 to 1260 pCi/L in domestic waters. These measurements are comparable to levels of between 80 and 1400 pCi/l for ²²²Rn found in ground water samples in the North-Central Tucson basin (Kahn et al., 1994). Estimated loss of ²²²Rn due to radioactive decay during travel from the well head to the home ranges from 8 to 50 percent.