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71.
Due to the specific modes of action and application patterns of agricultural insecticides, the insecticide exposure of agricultural surface waters is characterized by infrequent and short-term insecticide concentration peaks of high ecotoxicological relevance with implications for both monitoring and risk assessment. Here, we apply several fixed-interval strategies and an event-based sampling strategy to two generalized and two realistic insecticide exposure patterns for typical agricultural streams derived from FOCUS exposure modeling using Monte Carlo simulations. Sampling based on regular intervals was found to be inadequate for the detection of transient insecticide concentrations, whereas event-triggered sampling successfully detected all exposure incidences at substantially lower analytical costs. Our study proves that probabilistic risk assessment (PRA) concepts in their present forms are not appropriate for a thorough evaluation of insecticide exposure. Despite claims that the PRA approach uses all available data to assess exposure and enhances risk assessment realism, we demonstrate that this concept is severely biased by the amount of insecticide concentrations below detection limits and therefore by the sampling designs. Moreover, actual insecticide exposure is of almost no relevance for PRA threshold level exceedance frequencies and consequential risk assessment outcomes. Therefore, we propose a concept that features a field-relevant ecological risk analysis of agricultural insecticide surface water exposure. Our study quantifies for the first time the environmental and economic consequences of inappropriate monitoring and risk assessment concepts used for the evaluation of short-term peak surface water pollutants such as insecticides.  相似文献   
72.
ABSTRACT

This paper has a quintessentially explorative character. It aims at identifying existing as well as potential (yet missing) links between the finance industry and local businesses that aspire to more sustainable economic practices. Building on the observation that green investments have been gaining weight in global investors’ strategies, we analyse how sustainable – in the most comprehensive sense of the word – green investments could ultimately be(come), when green assets are still managed according to the logic of “financialised finance”. This latter’s technologies of commodification, securitisation and derivatives-trading allegedly oppose alternative economic practices that pursue economic sustainability through social and environmental gains. In contrast, we investigate how the finance industry relates to alternative financial practices, products and organisations that offer sustainability-oriented financing services, – for example, regional banks, cooperatives and the like, – with a specific focus on green, social and solidarity businesses. Both approaches subscribe to apparently contradictory ideologies. We establish a beneficial dialogue between the opposing models of “green capitalism” and “alternative economies” so as to identify potential points of intersection. The context of Luxembourg’s local/regional economies provides a great opportunity to empirically access three levels of investigation: the private sector, the public sector and an international financial centre, a key facilitator for green finance, thus utilising insights from the concept of bricolage. Whilst supporters of Luxembourg’s emerging green finance profile recognise its positive impact on the small country’s national branding, in combination with economic stimuli, more critical commentators point to pure “green washing” effects.  相似文献   
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Prediction of chain flexibility in proteins   总被引:3,自引:0,他引:3  
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More European heritage awards  相似文献   
76.
Grazing is the main land use in semi-arid regions of the world, and sustainable management practices are urgently needed to prevent their degradation. However, how different grazing intensities affect forest density and ecosystem functions is often not sufficiently understood to allow for management adaptations that safeguard the ecosystems and their functions in the long run. We assessed the aboveground carbon stocks and plant densities along a grazing gradient in the semi-arid seasonally dry tropical forest of north-eastern Brazil (Caatinga). On 45 study plots, we analysed the aboveground carbon stocks of the vegetation and determined forest density and recruitment as well as the population structure of the most abundant tree species. Grazing intensity was accounted for based on the weight of livestock droppings and classified as low, intermediate, or high. Mean aboveground carbon stock was 15.74?±?1.92 Mg ha?1 with trees and shrubs accounting for 89% of the total amount. Grazing at high intensities significantly reduced aboveground carbon stocks of herbs but not of other plant functional types. Instead, aboveground carbon stocks of trees and shrubs were negatively related to altitude above sea level, which is a proxy for reduced water availability along with lower anthropogenic impact. The population structure of the most common tree species was characterised by abundant recruitment, irrespective of grazing, whereas the recruitment of less frequent woody species was negatively affected by grazing. Overall, our data imply that grazing and forage management need to be adapted, including the reduction of free-roaming livestock and storage of fodder, to maintain carbon storage and forest density.  相似文献   
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