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991.
氧化铈在非贵金属燃烧催化剂中热稳定性的研究 总被引:1,自引:0,他引:1
本文考察了Ce含量对提高催化剂的热稳定性的作用,并采用X-射线衍射分析Ce含量对催化剂活性组成的影响。结果表明,合适的Ce含量能够提高催化剂的热稳定性,这主要是氧化铈能够阻止NiCo2O4相的生成,而NiCo2O4的生成对本系列催化剂的燃烧活性是不利的。实验还表明,在空气气氛下有利于形成NiCo2O4相,在N2/H2O气氛中不利于NiCo2O4相的生成。 相似文献
992.
993.
This study was conducted to examine the feasibility of using a moving-bed-biofilm reactor with internal circulation through aeration for the treatment of municipal wastewater. The attached film was a mixed-microorganism consortium, which used composite-refined-diatomaceous earth as novel biomass carriers to form a diatomaceous-earth-moving-bed-biofilm-reactor (DEMBBR) process. The startup of laboratory-scale, continuous-flow reactor was successfully achieved without seeding activated sludge. The DEMBBR process removed chemical oxygen demand, total phosphorus, ammonium-nitrogen, and turbidity at the highest rate of 88.5, 83, 92.3, and 96.7%, respectively, with a hydraulic retention time of only 2.5 hours. The DEMBBR was less affected by interruption and adverse operation conditions than the conventional-activated-sludge reactor. Thus, the DEMBBR could be proposed to be a cost-effective, small-wastewater-treatment-process unit. 相似文献
994.
包埋固定化微生物法处理含油废水研究 总被引:18,自引:0,他引:18
本研究通过包埋固定化微生物法固定除油菌(Y1’菌),用于处理含油废水,并以水体中乳化油去除率为指标考察了影响乳化油降解的各种因素。选用聚乙烯醇(PVA)-海藻酸钠(SA)复配作为包埋固定化载体材料,制备成固定化微生物小球(IMB),通过实验优化了IMB制备的工艺条件。连续批次除油实验结果表明,在25-40℃,固液比1:10,HRT为6h的条件下,进水油含量在20—50mg/L,乳化油去除率可达85%-90%,出水油含量低于5mg/L。 相似文献
995.
采用投加优势菌群的水解 -混凝法对糖蜜酒精废水进行试验 ,研究投加优势菌的水解阶段的处理效果 ,同时 ,以 10 %碱式AlCl3为混凝剂 ,对水解段的出水进行混凝处理 ,并对处理条件进行研究。结果表明 ,采用投加优势菌群的水解 -混凝法工艺处理该废水 ,可以取得 5 8%的CODCr去除率 ,且可去除一定的色度 相似文献
996.
用高效分散剂碳化法从煤矸石中制备超细氢氧化铝粉体 总被引:2,自引:0,他引:2
利用煤矸石为原料制备超细氢氧化铝粉体。采用高温煅烧活化煤矸石,利用C2S晶相转变制备煤矸石自粉化料,用8%Na2CO3溶液从煤矸石自粉化料中以NaAlO2形式提取铝组分,用高效分散剂碳化法制备超细氢氧化铝粉体。研究了高效分散剂碳化法制备高纯超细氢氧化铝粉体的影响因素,找出了高效分散剂碳化法制备超细氢氧化铝粉体的最佳条件,制备出了平均粒度〈100nm、纯度〉99.9%的氢氧化铝,为煤矸石的高价值利用开辟了一条新的途径。 相似文献
997.
998.
Estimation of PAHs dry deposition and BaP toxic equivalency factors (TEFs) study at Urban, Industry Park and rural sampling sites in central Taiwan, Taichung 总被引:11,自引:0,他引:11
The concentrations of polycyclic aromatic hydrocarbons (PAHs) in gas phase and particle bound were measured simultaneously at industrial (INDUSTRY), urban (URBAN), and rural areas (RURAL) in Taichung, Taiwan. And the PAH concentrations, size distributions, estimated PAHs dry deposition fluxes and health risk study of PAHs in the ambient air of central Taiwan were discussed in this study. Total PAH concentrations at INDUSTRY, URBAN, and RURAL sampling sites were found to be 1650 +/- 1240, 1220 +/- 520, and 831 +/- 427 ng/m3, respectively. The results indicated that PAH concentrations were higher at INDUSTRY and URBAN sampling sites than the RURAL sampling sites because of the more industrial processes, traffic exhausts and human activities. The estimation dry deposition and size distribution of PAHs were also studied. The results indicated that the estimated dry deposition fluxes of total PAHs were 58.5, 48.8, and 38.6 microg/m2/day at INDUSTRY, URBAN, and RURAL, respectively. The BaP equivalency results indicated that the health risk of gas phase PAHs were higher than the particle phase at three sampling sites of central Taiwan. However, compared with the BaP equivalency results to other studies conducted in factory, this study indicated the health risk of PAHs was acceptable in the ambient air of central Taiwan. 相似文献
999.
1000.
Oxidation of TNT by photo-Fenton process 总被引:4,自引:0,他引:4
A series of photo-Fenton reactions have been performed for the degradation of 2,4,6-trinitrotoluene (TNT) in a 4.2-l reactor. The degradation reaction rate of TNT followed a pseudo-first-order behavior; and the rate constants for 2.4mW cm(-2)UV only, 2.4mW cm(-2)UV/H(2)O(2), Fenton, photo-Fenton (2.4mW cm(-2)) and photo-Fenton (4.7mW cm(-2)) were 0.002min(-1), 0.007min(-1), 0.014min(-1), 0.025min(-1) and 0.037min(-1), respectively. Increasing the intensity of UV light, and the concentrations of ferrous ions and hydrogen peroxide promoted the oxidation rate under the experimental conditions in this study. The weighting factor (f), the Fe(II)-promoted efficiency (r) and the promoted-UV light efficiency (p) were calculated to clarify their effects on the TNT oxidation. Moreover, the inhibition effect of hydroxyl radical was also observed in both Fenton and photo-Fenton oxidation when the concentration of Fe(II) were higher than 2.88mM. Solid phase micro-extraction was first applied to the separation of the organic byproducts from TNT oxidation. GC/MS was employed to identify the byproducts during the Fenton and photo-Fenton oxidation of TNT. These compounds were clarified as 1,3,5-trinitrobenzene, 1-methyl-2,4-dinitrobenzene 2,5-dinitrobenzoic acid and 1,3-dinitrobenzene. By these byproducts, the mechanisms of the methyl group oxidation, decarboxylation, aromatic ring breakage, and hydrolysis can be recognized and demonstrated. The pathway of TNT oxidation by photo-Fenton process was also proposed in this study. 相似文献