基于偏离份额分析法的产业结构分析研究——以山东省为例

以1999—2009年为考察期,利用偏离份额分析法(SSM)分析了山东省17个城市在产业结构与区位竞争力方面的优势和劣势,并根据产业结构偏离分量和区位偏离分量的组合情况,对各地区的经济增长状况进行了定位,有助于调整各城市的产业结构,缩小城市间的经济差距。     

Source apportionment of wintertime secondary organic aerosol during the California regional PM10/PM2.5 air quality study

The UCD/CIT air quality model with the Caltech Atmospheric Chemistry Mechanism (CACM) was used to predict source contributions to secondary organic aerosol (SOA) formation in the San Joaquin Valley (SJV) from December 15, 2000 to January 7, 2001. The predicted 24-day average SOA concentration had a maximum value of 4.26 μg m^?3 50 km southwest of Fresno. Predicted SOA concentrations at Fresno, Angiola, and Bakersfield were 2.46 μg m^?3, 1.68 μg m^?3, and 2.28 μg m^?3, respectively, accounting for 6%, 37%, and 4% of the total predicted organic aerosol. The average SOA concentration across the entire SJV was 1.35 μg m^?3, which accounts for approximately 20% of the total predicted organic aerosol. Averaged over the entire SJV, the major SOA sources were solvent use (28% of SOA), catalyst gasoline engines (25% of SOA), wood smoke (16% of SOA), non-catalyst gasoline engines (13% of SOA), and other anthropogenic sources (11% of SOA). Diesel engines were predicted to only account for approximately 2% of the total SOA formation in the SJV because they emit a small amount of volatile organic compounds relative to other sources. In terms of SOA precursors within the SJV, long-chain alkanes were predicted to be the largest SOA contributor, followed by aromatic compounds. The current study identifies the major known contributors to the SOA burden during a winter pollution episode in the SJV, with further enhancements possible as additional formation pathways are discovered.     

Measurement of the surface charge of ultrafine particles from laser printers and analysis of their electrostatic force

Ultrafine particles (UFPs) released from laser printers are electrostatically charged during the working processes of the devices, and the electrostatic force can obviously influence the dynamics of the particles. Due to the measurement difficulty and scarcity of relevant research, this issue was not reported. This study tried to address this issue through experimental measurement of the surface charge of UFPs and numerical investigation on the influence of electrostatic force on the dynamics of UFPs. A test chamber was set up to collect the UFPs, and the Scanning Electron Microscope was used to observe the morphologies of the UFPs. Based on the particle diameter and surface zeta potential, the surface charge of UFPs was calculated. The measurement results gave that particle emitted from laser printers are negatively charged and the average surface charge of particle emissions for four laser printers is in a range of about ?4.16 × 10^?17 to ?6.07 × 10^?17 C (～?260 to ?379 e). This paper also discussed the influence of electrostatic force on the dynamics of UFPs. According to the numerical investigation, it was found that, in the absence of electric field, the electrostatic force has to be considered when the surface charge is larger than 1 × 10^?16 C and when the UFP is very close to the wall with a distance of less than 0.01 m. These findings will guide constructively in predicting the dispersion and deposition of particles emitted from laser printers.     

光/电Fenton牺牲阳极法降解有机污染物

采用Fe片为阳极和石墨为阴极,在可见光(λ450 nm)照射并外加电压条件下,以有机染料橙Ⅱ(orangeⅡ)及有机无色小分子2,4-二氯苯酚(2,4-dichlorophenol,DCP)为目标化合物,探讨了光/电Fenton牺牲阳极法降解有机污染物的最佳反应条件,结果表明,在电压=3 V,pH=3.0,H2O2浓度为5×10-5mol/L时,orangeⅡ的降解效果最好,反应10 h矿化率可达到78%,210 min内2,4-DCP降解率为91.4%。通过对光/电Fenton体系原位循环伏安参数测定及过氧化物酶催化反应吸光光度法和苯甲酸荧光分析法检测光/电Fenton降解orange II过程中H2O2和羟基自由基(.OH)的变化,表明orangeⅡ降解过程涉及.OH历程。     

Sensitivity of Portuguese forest fires to climatic, human, and landscape variables: subnational differences between fire drivers in extreme fire years and decadal averages

Within the changing fire regimes of Portugal, the relative importance of humans and climatic variability for regional fire statistics remains poorly understood. This work investigates the statistical relationship between temporal dynamics of fire events in Portugal and a set of socioeconomic, landscape, and climatic variables for the time periods of 1980–1990, 1991–2000, and extreme fires years. For 10 of 15 districts, it was possible to observe moderate shifts in the significance of fire drivers for the first two decadal periods. For others, pronounced changes of the significance of fire drivers were found across time. Results point toward a dynamic (perhaps highly non-linear) behavior of socioeconomic and landscape fire drivers, especially during the occurrence of extreme fire years of 2003 and 2005. At country level, population density alone explained 42% of the inter-annual and inter-district deviance in number of fires. At the same temporal and spatial scale, the explanatory power of temperature anomalies proved to explain 43% of area burnt. We highlight the necessity of including a broad set of socioeconomic and landscape fire drivers in order to account for potential significance shifts. In addition, although climate does trigger broad favorable fire conditions across Portugal mainland, socioeconomic and landscape factors proved to determine much of the complex fire patterns at a subnational scale.     

给水曝气生物滤池内置粉末活性炭复合净水效果的研究

在给水曝气生物滤池内置粉末活性炭,对比分析其对各工艺单元水质净化效果的影响,确定给水曝气生物滤池内置粉末活性炭的作用与最佳投加量,研究表明,给水曝气生物滤池将活性炭截留在滤池内,大幅度提高了粉末活性炭利用率,部分未饱和粉末活性炭通过反冲洗排入后续常规处理系统,作为生物载体仍能够进一步发挥生物强化作用。当粉末活性炭的投加量为8 mg/L时,砂滤出水氨氮、CODMn、浊度和色度均值分别为：0.02 mg/L,1.82 mg/L0,.46 NTU和6度,去除率分别达到99.6%、71.2%、99.1%和80.6%,出水指标达到《生活饮用水卫生标准（》GB5749-2006）和《饮用净水水质标准（》CJ94-2005）规定的标准。与常规工艺相比,投加量降低了20%～60%。     

膜生物反应器(MBR)-反渗透(RO)工艺深度处理印染废水的实验研究

采用膜生物反应器（MBR）-反渗透（RO）工艺对印染废水进行了深度处理实验。原水经MBR系统处理后,COD去除率、ss去除率和色度去除率分别达89．9％、100％和87．5％。MBR系统处理出水进入反渗透（RO）系统进行处理,硬度去除率和除盐率分别达99．62％和99．64％,同时可进一步除去剩余的COD、色度。系统出水水质满足生产回用的要求。     

Composition analysis and application of degradation products of whole feathers through a large scale of fermentation

Purpose

Feathers are one of the most abundant bioresources. They are discarded as waste in most cases and could cause environmental pollution. On the other hand, keratin constituted by amino acids is the main component of feathers. In this article, we reported on biorefined feathers and integrants and application of degraded products.

Materials and methods

The fermentation of whole chicken feathers with Stenotrophomonas maltophilia DHHJ in a scale-up of a 5-L bioreactor was investigated in this article. The fermentation process was controlled at 0.08 MPa pressure, 2.5 L/min airflow, and 300 rpm as 100% oxygen saturation level, 40°C, and pH 7.8.

Results

Feathers were almost completely degraded in the tested fermentation reaction with the following conditions: 80 g of whole feathers in 3 L fermentation broth for 72 h, seed age of 16 h, 100 mL inoculation amount, and 50% oxygen saturation level. The degraded products contain 397.1 mg/L soluble protein that has mass weight ranging from 10 to 160 kD, 336.9 mg/L amino acids, and many kinds of metal ions. The fermentation broth was evaluated as leaf fertilizer and found to increase plant growth to 82% or 66% for two- or fourfold dilutions, respectively. In addition, in a hair care assay, the broth showed a hair protective function by increasing weight, flexibility, and strength of the treated hair.

Conclusions

The whole feathers were degraded completely by S. maltophilia DHHJ. The degraded product includes many factors to life, such as peptides, amino acids, and mineral elements. It could be applied as leaf fertilizer and hair care product.     

Combined inverse modeling approach and load duration curve method for variable nitrogen total maximum daily load development in an agricultural watershed

Purpose  

Nonpoint sources (NPS) pollution has been an important cause for water quality impairment worldwide. To take the temporal variations of both NPS pollution and in-stream attenuation into consideration, an inverse modeling approach and the load duration curve (LDC) method were combined for variable nutrient total maximum daily load (TMDL) development.     

Uptake and distribution of metals by water lettuce (<Emphasis Type="Italic">Pistia stratiotes</Emphasis> L.)

Background, aim and scope  

Water quality impairment by heavy metal contamination is on the rise worldwide. Phytoremediation technology has been increasingly applied to remediate wastewater and stormwater polluted by heavy metals.