Exposure to Selected Heavy Metals Through Water Ingestion in an Area Under the Influence of Tanneries

This study evaluated the potential toxicological risk posed to human health due to the exposure to heavy metals by water ingestion in an area affected by tanneries – the Cadeia-Feitoria hydrographic basin (Brazil). River water was collected at 10 sites, every 3 months, from July 1999 to April 2000. After acid digestion, total metal concentration was determined by inductively coupled plasma optical emission spectrometry (Cd, Cu, Cr, Ni, Zn), flame atomic absorption (Al, Fe, Pb, Mn), or cold vapor atomic absorption spectrometry (Hg). Cr(VI) was complexed with diphenyl-carbazide and detected by UV–vis spectrometry. In order to quantify the risk of exposure, the risk assessment methodology employed by the Environmental Protection Agency of the United States was applied at a screening level. The assumed scenarios included extreme exposure patterns (ingestion of untreated water, conversion of Cr(III) to Cr(VI), temporal peaks of pollution). Fe, Al, Cd, Hg, and Pb were not included in the risk analysis, since they showed a low toxicity potential or were undetected in the samples. The selected metals presented Hazard Quotients < 1, in the following order of increasing risk: Cu < Cr(III) < Zn < Ni < Mn < Cr(VI). Hazard indexes, representing the additive effect of contaminants, were also low in the basin (< 1), but comparatively increased in the lower reach of Feitoria and Cadeia Rivers. Although noncarcinogenic risk levels did not suggest possible adverse toxicological effects to the human population, a considerable deviation from background conditions was observed downstream the area where tanneries are mainly located.     

Safer management of process changes in chemical reactors

Nowadays many chemical industries are SMEs where multi-purpose batch or semi-batch reactors are commonly used. Vent sizing for realistic runaway scenario is not an easy task for such enterprises since they have usually few resources and use multi-purpose reactors with fast process turnovers. As a consequence these batch and semi-batch reactors are usually equipped with emergency relief systems sized once forever when the reactor is designed. This can lead to a large underestimation of the vent area in case of runaway reactions occurring when processes different from the ones considered for originally sizing the vent are carried out.The approach proposed in this work aims to identify the maximum reactor load leading to safe conditions even in case of runaway phenomena to be handled with the emergency relief system already installed (or even with a smaller vent area). This approach allows avoiding the change of the emergency relief system with a larger vent area (as required every time a new more hazardous process has to be carried out on existing reactors) at the price of lower plant productivity.     

Evidences of different salinization sources in the roman coastal aquifer (Central Italy)

The coastal aquifer of Rome is hosted in the Tiber River Delta depositional sequence, in a densely populated area, which was reclaimed at the end of the 19th century. Moderate salinization processes characterize this aquifer. Hydrogeological and hydrochemical surveys were carried out in October 2012 and February 2013 in the southern sector of the Delta. Hydrogeological surveys updated knowledge of groundwater morphology and a detailed conceptual hydrogeological model of the coastal aquifer was realized. Hydrochemical analyses helped to identify the salinization spatial distribution and to specify the main groundwater types. The most salinized water was not detected close to the coastline, where seawater intrusion processes would be expected, but in the inner areas. Moreover, the salinization processes resulted to be slightly marked. Results so far suggest that the source of salinization may be related more to a combination of land use and historical development of the Tiber River Delta, rather than to seawater.     

Contamination of lead (Pb) in the coastal sediments of north and south of Iran: a review study

Coastal areas of Iran are heavily affected by urbanisation, industrialisation, and maritime activities. One consequence of this environmental pressure is the contaminants accumulation, as heavy metals, into the marine ecosystem. In this review, the coastal areas in the north and south of the country were assessed for lead (Pb) contamination of, one of the most toxic metals found in the environment. All studies conducted during 2006–2016 with at least 10 specimens that reported the mean and standard deviation of Pb were considered in this review. Heterogeneity between studies was assessed using the Q and I² statistics. The Pb mean concentration overall studies was estimated to be 21.88?µg/g (95% CIs: 16.25–27.50). Random effect model showed no statistical difference in mean Pb concentration levels between south and north coasts. However, the variability in Pb mean concentrations within southern coasts was considerable and statistically significant. Moreover, the Pb concentrations in the northern coasts of Persian Gulf and Oman Sea, in south of Iran, decreased in the following order Hormozgan > Khuzestan > Sistan-VA-Balluchestan > Bushehr while in the southern coasts of Caspian Sea, in north of Iran, decreased in the order Guilan > Mazandaran > Golestan.     

A quantitative estimate of potential aluminium recovery from incineration bottom ashes

The recovery of ferrous and non ferrous metals from the bottom ashes is a common practice in the most part of Europe, both for the environmental advantages of their recycle and to avoid problems of swelling and expansion that metals can cause when bottom ashes are reused in concrete production or in road construction. This paper focuses on metal recovery from bottom ashes produced in Municipal Solid Waste (MSW) incinerators, with a particular focus on aluminium. A forecasting model was developed in order to evaluate the quantity of aluminium scraps recoverable from the bottom ashes. The model was applied to the Italian situation but its validity can be extended to other countries. Focusing on Italy, by applying conventional technologies for the separation of non-ferrous metals, the amount of aluminium potentially recoverable from bottom ashes is estimated in the range from 16,500 to 21,000 tonnes at the year 2015, and from 19,000 to 28,500 tonnes at 2020.     

Cannabis sativa L. and Brassica juncea L. grown on arsenic-contaminated industrial soil: potentiality and limitation for phytoremediation

Environmental Science and Pollution Research - Phytoremediation represents a natural method to remove contaminants from soil. The goal of this study was to investigate the potential of...     

TiO2-NPs and cadmium co-exposure: in vitro assessment of genetic and genomic DNA damage on Dicentrarchus labrax embryonic cells

Environmental Science and Pollution Research - The increased titanium dioxide nanoparticles (TiO2-NPs) spread and their interaction with organic and inorganic pollutants arouses concern for the...     

Use of naturally growing aquatic plants for wastewater purification.

This paper examines potential uses of naturally growing aquatic plants for wastewater purification. These plants enhance the removal of pollutants by consuming part of them in the form of plant nutrients. This applies to urban and agricultural wastewater, in particular, where treatment units of different sizes can be applied at the pollution source. The effectiveness of wastewater purification by different plants was tested on laboratory and pilot scales. The growth rate of the plants was related to the wastewater content in the water. Batch and semicontinuous experiments verified that the plants are capable of decreasing all tested indicators for water quality to levels that permit the use of the purified water for irrigation. This applies to biochemical oxygen demand (BOD), chemical oxygen demand, total suspended solids. pH, and turbidity. In specific cases, the turbidity reached the level of drinking water. Comparison of BOD concentrations with typical levels in water treatment facilities across the country indicates the effectiveness of water purification with plants. A major effect of treatment with plants was elimination of the disturbing smell from the wastewater. It is shown that mixtures of wastewater and polluted water from the Kishon River are amenable in varying degrees to treatment by the plants. The higher the wastewater content in the mixture, the more effective the treatment by the plants. In this context, a scheme for rehabilitation and restoration of the Kishon River is presented and technical and economical aspects of the purification technology are considered.