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排序方式: 共有196条查询结果,搜索用时 46 毫秒
101.
José Cavalcante Souza Vieira Camila Pereira Braga Grasieli de Oliveira Aline de Lima Leite João Vitor de Queiroz Bruna Cavecci Alis Correia Bittarello Marília Afonso Rabelo Buzalaf Luiz Fabricio Zara Pedro de Magalhães Padilha 《Environmental Chemistry Letters》2017,15(4):717-724
Bioaccumulative metals such as mercury are found in increasing amounts in fish and their consumers. In the region of the Madeira River, in the Brazilian Amazon, mercury (Hg) is a predominant contaminant in the aquatic ecosystem. There is therefore a need to find specific biomarkers of mercury toxicity in fish to monitor contaminations. Here, mercury-bound proteins were identified in the liver tissues of fishes Mylossoma duriventre and Brachyplatystoma rousseauxii. Mercury was quantified in liver tissue, pellets and protein spots by graphite furnace atomic absorption. Proteins were fractionated by two-dimensional polyacrylamide gel electrophoresis and identified by mass spectrometry with electrospray ionization. We identified nine proteins linked to mercury and that presented biomarker characteristics of mercury. Among the proteins identified, isoforms of parvalbumin, ubiquitin-40S ribosomal protein S27a, brain-specific angiogenesis inhibitor 1-associated protein 2-like protein 2 and betaine–homocysteine S-methyltransferase 1 are notable for having the molecular function of binding to metallic ions. 相似文献
102.
A System Dynamics Model for the Environmental Management of the Sepetiba Bay Watershed, Brazil 总被引:2,自引:0,他引:2
In the recent past, the Sepetiba Bay watershed, located in the Rio de Janeiro State, Brazil has experienced rapid industrial
development and population growth, as well as an increase in water pollution and environmental degradation. To analyze the
complex interrelationships among the agents affecting the Sepetibza Bay environment, a system dynamics model was developed.
The model builds on extensive studies conducted for the watershed, and simulates different hypotheses of economic growth and
of demographic expansion. Thus, it can be used as a decision support tool for the identification of investment priorities
and policy analyses under various scenarios. In order to provide a comprehensive approach to the environmental management
of the Sepetiba Bay watershed, the model had to consider only the most relevant aspects of the behavior and the key interactions
among agents operating in the watershed. In this article, the model’s structure is presented together with some of its main
results. 相似文献
103.
In this paper, a method involving on-line preconcentration with cloud point extraction for the determination of cadmium in biological samples is presented. The procedure is based on the sorption of micelles containing Cd(II) ions and the reagent 4-(5'-bromo-2'-thiazolylazo)orcinol (Br-TAO) in a minicolumn packed with polyester. The surfactant Triton X-114 was used in the formation of micelles. After sorption, the Cd(II) ions were desorbed from the minicolumn with acid eluent and determined by flame atomic absorption spectrometry. Parameters influencing the cloud point extraction were studied. The method showed a detection limit of 0.5 μg l(-1) and an enhancement factor of 27. The accuracy was tested by determination of cadmium in certified reference materials (spinach leaves 1570a and tomato leaves 1573a) from the National Institute of Standards and Technology. 相似文献
104.
Heavy metal inputs evolution to an urban hypertrophic coastal lagoon, Rodrigo De Freitas Lagoon, Rio De Janeiro, Brazil 总被引:1,自引:0,他引:1
Daniel Dias Loureiro Marcos A. Fernandez Friedrich W. Herms Luiz D. Lacerda 《Environmental monitoring and assessment》2009,159(1-4):577-588
This work discusses the temporal variation of metal concentrations in a hypertrophic coastal lagoon located in the metropolitan area of Rio de Janeiro (Brazil). The lagoon watershed includes one of the mostly densely urbanized areas of the city but without industrial activities. Six sediment cores were collected in the lagoon between May and July 2003 and analyzed for the concentration of metals (Fe, Al, Mn, Zn, Pb, Cu, Cr, and Ni). Typical sedimentation rate was calculated as being 0.75 cm year???1 and was uniform for at least the past 70 years. Therefore, the alterations in the dynamics of the lagoon caused by changes in its watershed were clearly indicated in sediment cores. The construction of an artificial canal to the sea and the increasing urbanization and soil use changes were the major factors affecting metal accumulation in the lagoon sediments. Metals typical of anthropogenic urban sources (Pb, Zn, and Cu) showed increasing loads following urbanization. 相似文献
105.
106.
This article describes the role played by the Brazilian Audit Tribunal (Tribunal de Contas da União — TCU) in the external auditing of environmental management in Brazil, highlighting the findings of an operational audit conducted in 2007 of the federal environmental licensing process. Initially, it records the constitutional and legal framework of Brazilian environmental licensing, describing the powers and duties granted to federal, state and municipal institutions. In addition, it presents the responsibilities of the TCU in the environmental area, comparing these with those of other Supreme Audit Institutions (SAI) that are members of the International Organization of Supreme Audit Institutions (INTOSAI).It also describes the work carried out in the operational audit of the Brazilian environmental licensing process and its main conclusions and recommendations. Finally, it draws a parallel between the findings and recommendations made in Brazil with those of academic studies and audits conducted in other countries. 相似文献
107.
108.
de Carvalho Gomes F Godoy JM Godoy ML de Carvalho ZL Lopes RT Sanchez-Cabeza JA Osvath I de Lacerda LD 《Journal of environmental radioactivity》2011,102(9):871-876
Ribeira Bay is located approximately 130 km south of the city of Rio de Janeiro and receives discharges of liquid effluent from the Angra dos Reis nuclear power plant (NPP) site, where two pressurized water reactors are located. To test whether the presence of anthropogenic radionuclides in sediments in Ribeira Bay could be correlated to the NPP operations, we sampled seven sediment cores and determined accumulation rates and chronologies. Only one sediment core did not exhibit a superficial mixing layer; this sample was used for dating purposes. Cesium-137 and 207Bi were observed in this sediment profile, but their presence was associated with atmospheric fall-out rather than the nearby NPP. The exponential decay of 210Pb concentration with sediment layer depth was verified below a superficial mixing layer for all other sediment cores. Calculated accumulation rates ranged from 1.2 mm y−1 in the inner bay to 6.2 mm y−1 close to its entrance. 相似文献
109.
Ribeiro E Tauhata L dos Santos EE da Silveira Corrêa R 《Journal of environmental radioactivity》2011,102(2):145-152
This paper presents the results of the Environmental Monitoring Program for the Radioactive waste repository of Abadia de Goiás, which was originated from the accident of Goiania, conducted by the Regional Center of Nuclear Sciences (CRCN-CO) of the National Commission on Nuclear Energy (CNEN), from 1998 to 2008.The results are related to the determination of 137Cs activity per unit of mass or volume of samples from surface water, ground water, depth sediments of the river, soil and vegetation, and also the air-kerma rate estimation for gamma exposure in the monitored site.In the phase of operational Environmental Monitoring Program, the values of the geometric mean and standard deviation obtained for 137Cs activity per unit of mass or volume in the analyzed samples were (0.08 ± 1.16) Bq.L−1 for surface and underground water, (0.22 ± 2.79) Bq.kg−1 for soil, and (0.19 ± 2.72) Bq.kg−1 for sediment, and (0.19 ± 2.30) Bq.kg−1 for vegetation. These results were similar to the values of the pre-operational Environmental Monitoring Program.With these data, estimations for effective dose were evaluated for public individuals in the neighborhood of the waste repository, considering the main possible way of exposure of this population group.The annual effective dose obtained from the analysis of these results were lower than 0.3 mSv.y−1, which is the limit established by CNEN for environmental impact in the public individuals indicating that the facility is operating safely, without any radiological impact to the surrounding environment. 相似文献
110.
Plant uptake of pesticides and human health: dynamic modeling of residues in wheat and ingestion intake 总被引:2,自引:0,他引:2
Human intake of pesticide residues from consumption of processed food plays an important role for evaluating current agricultural practice. We take advantage of latest developments in crop-specific plant uptake modeling and propose an innovative dynamic model to estimate pesticide residues in the wheat-environment system, dynamiCROP. We used this model to analyze uptake and translocation of pesticides in wheat after foliar spray application and subsequent intake fractions by humans. Based on the evolution of residues in edible parts of harvested wheat we predict that between 22 mg and 2.1 g per kg applied pesticide are taken in by humans via consumption of processed wheat products. Model results were compared with experimentally derived concentrations in wheat ears and with estimated intake via inhalation and ingestion caused by indirect emissions, i.e. the amount lost to the environment during pesticide application. Modeled and measured concentrations in wheat fitted very well and deviate from less than a factor 1.5 for chlorothalonil to a maximum factor 3 for tebuconazole. Main aspects influencing pesticide fate behavior are degradation half-life in plant and time between pesticide application and crop harvest, leading to variations in harvest fraction of at least three orders of magnitude. Food processing may further reduce residues by approximately 63%. Intake fractions from residues in sprayed wheat were up to four orders of magnitude higher than intake fractions estimated from indirect emissions, thereby demonstrating the importance of exposure from consumption of food crops after direct pesticide treatment. 相似文献