防护鞋靴有害物质限量值研究

本文对防护鞋靴有害物质限量值研究进行了阐述。参考国内外标准,设定防护鞋靴有害物质限制项目和限量值。在检测分析我国具有市场代表性的16个防护鞋靴产品中有害物质含量数据基础上,判断设定限制项目及限量值的可行性。检测结果表明我国防护鞋靴生产技术水平基本能够达到限量要求,设定的限量值可以作为制定国家标准的参考依据。     

Research status and future challenge for CO2 sequestration by mineral carbonation strategy using iron and steel slag

Environmental Science and Pollution Research - Mineral carbonation can simultaneously realize the effective treatment of CO2 and iron and steel slag; thus, it is of great significance for the low...     

Personal exposure to PM2.5-bound heavy metals associated with cardiopulmonary function in general population

Environmental Science and Pollution Research - To better understand the cardiopulmonary alterations associated with personal exposed PM2.5-bound heavy meals, we conducted a cross-sectional study in...     

In situ electron-induced reduction of NOx via CNTs activated by DBD at low temperature

• An in situ electron-induced deNO_x process with CNT activated by DBD was achieved. • Carbon atoms on CNT surface were verified to be excited by plasma in DBD-CNT system. • Reactions between NO_x and excited C result in synergistic effect of DBD-CNT system. In this study, a new in situ electron-induced process is presented with carbon nanotubes (CNTs) as a reduction agent activated by dielectric barrier discharge (DBD) for nitrogen oxide (NO_x) abatement at low temperature (<407 K). Compared with a single DBD system and a DBD system with activated carbon (DBD-AC), a DBD system with carbon nanotubes (DBD-CNT) showed a significant promotion of NO_x removal efficiency and N₂ selectivity. Although the O₂ content was 10%, the NO_x conversion and N₂ selectivity in the DBD-CNT system still reached 64.9% and 81.9% at a specific input energy (SIE) of 1424 J/L, and these values decreased to 16.8%, 31.9% and 43.2%, 62.3% in the single DBD system and the DBD-AC system, respectively. X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) were utilized to investigate surface changes in the CNTs after activation by DBD to explore the NO_x reduction abatement mechanism of this new process. Furthermore, the outlet gas components were also observed via Fourier transform infrared spectroscopy (FTIR) to help reveal the NO_x reduction mechanism. Experimental results verified that carbon atoms excited by DBD and the structure of CNTs contributed to the synergistic activity of the DBD-CNT system. The new deNO_x process was accomplished through in situ heterogenetic reduction reactions between the NO_x and carbon atoms activated by the plasma on the CNTs. In addition, further results indicated that the new deNO_x process exhibited acceptable SO₂ tolerance and water resistance.     

Kinetic analysis of anaerobic phosphorus release during biological phosphorus removal process

Enhanced biological phosphorus removal (EBPR) is a commonly used and sustainable method for phosphorus removal from wastewater. Poly-β-hydroxybutyrate (PHB), polyphosphate, and glycogen are three kinds of intracellular storage polymers in phosphorus accumulation organisms. The variation of these polymers under different conditions has an apparent influence on anaerobic phosphorus release, which is very important for controlling the performance of EBPR. To obtain the mechanism and kinetic character of anaerobic phosphorus release, a series of batch experiments were performed using the excessively aerated sludge from the aerobic unit of the biological phosphorus removal system in this study. The results showed that the volatile suspended solid (VSS) had an increasing trend, while the mixed liquid suspended sludge (MLSS) and ashes were reduced during the anaerobic phosphorus release process. The interruption of anaerobic HAc-uptake and phosphorus-release occurs when the glycogen in the phosphorus-accumulating-organisms is exhausted. Under the condition of lower initial HAc-COD, HAc became the limiting factor after some time for anaerobic HAc uptake. Under the condition of higher initial HAc-COD, HAc uptake was stopped because of the depletion of glycogen in the microorganisms. The mean ratio of Δρ _P/Δρ _PHB, Δρ _GLY/Δρ _PHB, Δρ _P/ΔCOD, was 0.48, 0.50, 0.44, and 0.92, respectively, which was nearly the same as the theoretical value. The calibrated kinetic parameters of the HAc-uptake and phosphorus-release model were evaluated as follows: Q _HAc,max was 164 mg/(g · h), Q _P,max was 69.9 mg/(g · h), K _gly was 0.005, and KCOD was 3 mg/L. An apparently linear correlation was observed between the ratio of Δρ _P/ΔCOD and pH of the solution, and the equation between them was obtained in this study.     

大红色基G生产中的废酸资源回收

大红色基Ｇ生产中产生的废硫酸内含硫酸达５０％，ＣＯＤ７０ｇ／Ｌ，难用常规的方法来处理。本文给出了用该废酸生产硫酸锌进而生产立德粉的方法，并用ＣＯＤ浓度作为硫酸锌质量的控制指标，氧化锌和了废硫酸后，有机会物从溶液中析了，ＣＯＤ的去除率达９９％。残存的有机物用活性炭吸附法除去。控制ＺｎＳＯ４溶液中ＣＯＤ≤６０ｍｇ／Ｌ，可制得合格的Ｂ３０１立德粉。有杉本法使硫酸资源全部回收并且无废水排放。     

Nutrients Can Enhance Phytoremediation of Copper-Polluted Soil by Indian Mustard

An orthogonally designed experiment was conducted to study the single and combined effects of N, P and K on phytoremediation of Cu-polluted soil by Indian mustard. Addition of fertilizer N and P significantly increased Indian mustard shoot yield. Two high treatments combined with N resulted in the highest yields, followed by low-P combined with N. In contrast, high P with no N gave no yield increase and K had no effect on yield of Indian mustard. Nitrogen and P increased the amount of chlorophyll in the leaves, indicating that the yield increases were due to enhanced photosynthesis. Nitrogen application had no effect on plant Cu concentrations but addition of P slightly decreased plant Cu concentrations, likely a dilution effect resulting from the increase in yield. Among the treatments, N and P applied at 100 and 200 mg kg^–1 respectively with no K application resulted in the highest Cu uptake. Thus, a combination of low N and high P produced a yield increase in Indian mustard that was more than adequate to compensate for a slight decrease in Cu concentration, resulting in the highest Cu removal from the contaminated soil.     

铝对茶叶叶片主要化学成分的影响

以茶树2个品种(雁荡毛峰和知仁早茶)为研究材料,采用溶液培养法,研究了铝对茶叶叶片主要化学成分(茶多酚、咖啡碱、氨基酸和维生素C)的影响。结果表明,水培下,10～100mg·L-1质量浓度的铝可显著提高茶多酚的质量分数,与对照相比,50mg·L-1质量浓度下雁荡毛峰茶多酚的质量分数提高了180%,知仁早茶提高了100.6%;10～50mg·L-1质量浓度的铝可提高咖啡碱、氨基酸的质量分数,但100mg·L-1质量浓度下显著降低了咖啡碱和氨基酸的质量分数,雁荡毛峰降低了5.3%、25.8%,知仁早茶降低了2%、7.2%;不同质量浓度的铝对维生素C的质量分数影响不大;低质量浓度的铝处理降低茶树的丙二醛质量分数,而高质量浓度的铝处理(100mg·L-1)提高了丙二醛质量分数。结果证明水培条件下,10～50mg·L-1铝可明显提高茶叶品质,100mg·L-1质量浓度会降低茶叶品质。     

普通小球藻和铜绿微囊藻与粘土颗粒凝聚沉降行为研究

本研究结果表明,不同的藻类和不同的粘土颗粒均使藻类与粘土颗粒的凝聚沉降发生变化。结果还表明,溶液中[Cu~(2+)]浓度超过10~(-5)mol后,加快了小球藻与高龄土的凝聚沉降。使80％以上的小球藻和高岭土在不到10min内即凝聚沉降。在最后结合实验结果讨论了利用藻类与粘土的凝聚沉降治理水体污染。     

阪神地震中地下结构和隧道的破坏现象浅析

概述了阪神地震中地铁车站和地下隧道所造成的破坏情况,说明了地下结构较之于地面结构具有更为良好的抗震性能,同时也说明在地下结构的抗震设计中应认真研究直下型地震的强地面运动破坏作用。