全文获取类型
收费全文 | 1541篇 |
免费 | 75篇 |
国内免费 | 474篇 |
专业分类
安全科学 | 113篇 |
废物处理 | 91篇 |
环保管理 | 114篇 |
综合类 | 771篇 |
基础理论 | 294篇 |
污染及防治 | 541篇 |
评价与监测 | 52篇 |
社会与环境 | 40篇 |
灾害及防治 | 74篇 |
出版年
2024年 | 1篇 |
2023年 | 23篇 |
2022年 | 80篇 |
2021年 | 59篇 |
2020年 | 35篇 |
2019年 | 38篇 |
2018年 | 65篇 |
2017年 | 54篇 |
2016年 | 64篇 |
2015年 | 76篇 |
2014年 | 115篇 |
2013年 | 140篇 |
2012年 | 112篇 |
2011年 | 107篇 |
2010年 | 101篇 |
2009年 | 105篇 |
2008年 | 111篇 |
2007年 | 74篇 |
2006年 | 86篇 |
2005年 | 49篇 |
2004年 | 58篇 |
2003年 | 74篇 |
2002年 | 45篇 |
2001年 | 52篇 |
2000年 | 47篇 |
1999年 | 37篇 |
1998年 | 69篇 |
1997年 | 49篇 |
1996年 | 31篇 |
1995年 | 26篇 |
1994年 | 26篇 |
1993年 | 28篇 |
1992年 | 22篇 |
1991年 | 11篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
排序方式: 共有2090条查询结果,搜索用时 31 毫秒
991.
基于2015—2020年成都市国控环境监测站点逐时大气污染物监测数据,将其分为3类站点(城区、交通、背景站点),研究不同季节、不同污染水平下,各类站点细颗粒物(PM2.5)和臭氧(O3)复合污染特征及相互作用.结果表明:①成都各类站点的PM2.5超标天数和PM2.5年平均浓度总体呈下降趋势,背景站点浓度明显小于城区站点和交通站点;O3年际变化趋势呈波动性,且交通站点和背景站点的变化波动强于城区站点.②各类站点PM2.5与O3相关性在O3污染期(4—8月)和PM2.5污染期(11—次年1月)均存在显著差异,且二者在不同季节甚至呈现相反的相关性,总体趋势为夏季PM2.5-O3的相关性趋于正相关,冬季趋于负相关.③O3污染期,各类站点二次PM2.5的浓度和贡献率随光化学水平的升高而增加,而一次PM2.5日变化幅度差异不大,表现出明显的O3和PM2.5协同增长现象.④PM2.5污染期,PM2.5与O3之间并不是简单的线性关系,不同PM2.5污染程度下,各类站点O3浓度变化率昼夜波动趋势基本相同,均在12:00—13:00达到峰值,在18:00达到谷值;且随着PM2.5浓度的增加,O3浓度变化率峰值/谷值波动范围亦随之增加. 相似文献
992.
Human industrial activities have caused environmental uranium (U) pollution, resulting in uranium(VI) had radiotoxicity and chemical toxicity. Here, a cellulase-producing Penicillium fungus was screened and characterized by X-ray fluorescence (XRF), and Fourier transform infrared reflection (FT-IR), as well as by GC/MS metabolomics analysis, to study the response to uranium(VI) stress. The biomass of Penicillium decreased after exposure to 100 mg/L U. Uranium combined with carboxyl groups, amino groups, and phosphate groups to form uranium mineralized deposits on the surface of this fungal strain. The α-activity concentration of uranium in the strain was 2.57×106 Bq/kg, and the β-activity concentration was 2.27×105 Bq/kg. Metabolomics analysis identified 118 different metabolites, as well as metabolic disruption of organic acids and derivatives. Further analysis showed that uranium significantly affected the metabolism of 9 amino acids in Penicillium. These amino acids were related to the TCA cycle and ABC transporter. At the same time, uranium exhibited nucleotide metabolism toxicity to Penicillium. This study provides an in-depth understanding of the uranium tolerance mechanism of Penicillium and provides a theoretical basis for Penicillium to degrade hyper-enriched plants. 相似文献
993.
At present, the cyanide gold extraction process is still the main technology for gold production. Generated cyanide tailings containing highly toxic substances exhibit potential environmental risks. These tailings are in urgent need of purification treatment, especially after being classified as hazardous waste. In this study, the impacts of elution methods, operating time, tailings/water ratios, reagent types on the elution rates of cyanide were investigated. Furthermore, the composite elution ... 相似文献
994.
Dingyong Wang Yongguang Yin Shufang Zeng Xun Wang Wei Yuan Ji Luo Yong Cai Xinbin Feng Shuxiao Wang Huan Zhong Ping Li 《环境科学学报(英文版)》2022,119(9):1-10
Understanding atmospheric mercury (Hg) accumulation in remote montane forests is critical to assess the Hg ecological risk to wildlife and human health. To quantify impacts of vegetation, climatic and topographic factors on Hg accumulation in montane forests, we assessed the Hg distribution and stoichiometric relations among Hg, carbon (C), and nitrogen (N) in four forest types along the elevation of Mt. Gongga. Our results show that Hg concentration in plant tissues follows the descending order of litter > leaf, bark > root > branch > bole wood, indicating the importance of atmospheric Hg uptake by foliage for Hg accumulation in plants. The foliar Hg/C (from 237.0 ± 171.4 to 56.8 ± 27.7 µg/kg) and Hg/N (from 7.5 ± 3.9 to 2.5 ± 1.2 mg/kg) both decrease along the elevation. These elevation gradients are caused by the heterogeneity of vegetation uptake of atmospheric Hg and the variation of atmospheric Hg° concentrations at different altitudes. Organic soil Hg accumulation is controlled by forest types, topographic and climatic factors, with the highest concentration in the mixed forest (244.9 ± 55.7 µg/kg) and the lowest value in the alpine forest (151.9 ± 44.5 µg/kg). Further analysis suggests that soil Hg is positively correlated to C (r2 = 0.66) and N (r2 = 0.57), and Hg/C and Hg/N both increase with the soil depth. These stoichiometric relations highlight the combined effects from environmental and climatic factors which mediating legacy Hg accumulation and selective Hg absorption during processes of organic soil mineralization. 相似文献
995.
Qiang Zeng Pan-Pan Chen Pan Yang Chong Liu Yan-Ling Deng Qiong Luo Yu Miao Min Zhang Fei-Peng Cui Jia-Yue Zeng Tian Shi Ting-Ting Lu Da Chen Long-Qiang Wang Chun-Ping Liu Ming Jiang 《环境科学学报(英文版)》2022,120(10):30-40
Phenols have been shown to influence the cellular proliferation and function of thyroid in experimental models. However, few human studies have investigated the association between phenol exposure and thyroid cancer, and the underlying mechanisms are also poorly understood. We conducted a case-control study by age- and sex-matching 143 thyroid cancer and 224 controls to investigate the associations between phenol exposures and the risk of thyroid cancer, and further to explore the mediating role of oxidative stress. We found that elevated urinary triclosan (TCS), bisphenol A (BPA) and bisphenol S (BPS) levels were associated with increased risk of thyroid cancer (all P for trends < 0.05), and the adjusted odds ratios (ORs) comparing the extreme exposure groups were 3.52 (95% confidence interval (CI): 2.08, 5.95), 2.06 (95% CI: 1.06, 3.97) and 7.15 (95% CI: 3.12, 16.40), respectively. Positive associations were also observed between urinary TCS, BPA and BPS and three oxidative stress biomarkers measured by 8-hydroxy-2′-deoxyguanosine (8-OHdG), 8-iso-prostaglandin F2α (8-isoPGF2α) and 4-hydroxy-2-nonenal-mercapturic acid (HNE-MA), as well as between urinary 8-isoPGF2α and HNE-MA and the risk of thyroid cancer. Mediation analysis showed that urinary 8-isoPGF2α mediated 28.95%, 47.06% and 31.08% of the associations between TCS, BPA and BPS exposures and the risk of thyroid cancer, respectively (all P < 0.05). Our results suggest that exposure to TCS, BPA and BPS may be associated with increased risk of thyroid cancer and lipid peroxidation may be an intermediate mechanism. Further studies are warranted to confirm the findings. 相似文献
996.
Hezhong Tian Lining Luo Xiaoxuan Bai Shuhan Liu Bobo Wu Wei Liu Yunqian Lv Zhihui Guo Shumin Lin Shuang Zhao Yan Hao Jiming Hao Kai Zhang Aihua Zheng 《环境科学学报(英文版)》2022,34(11):187-198
Particulate matter (i.e., PM1.0 and PM2.5), considered as the key atmospheric pollutants, exerts negative effects on visibility, global climate, and human health by associated chemical compositions. However, our understanding of PM and its chemical compositions in Beijing under the current atmospheric environment is still not complete after witnessing marked alleviation during 2013–2017. Continuous measurements can be crucial for further air quality improvement by better characterizing PM pollution and chemical compositions in Beijing. Here, we conducted simultaneous measurements on PM in Beijing during 2018–2019. Results indicate that annual mean PM1.0 and PM2.5 concentrations were 35.49 ± 18.61 µg/m3 and 66.58 ± 60.17 µg/m3, showing a positive response to emission controls. The contribution of sulfate, nitrate, and ammonium (SNA) played an enhanced role with elevated PM loading and acted as the main contributors to pollution episodes. Discrepancies observed among chemical species between PM1.0 and PM2.5 in spring suggest that sand particles trend to accumulate in the range of 1–2.5 µm. Pollution episodes occurred accompanied with southerly clusters and high formation of SNA by heterogeneous reactions in summer and winter, respectively. Results from positive matrix factorization (PMF) combined with potential source contribution function (PSCF) models showed that potential areas were seasonal dependent, secondary and vehicular sources became much more important compared with previous studies in Beijing. Our study presented a continuous investigation on PM and sources origins in Beijing, which provides a better understanding for further emission control as well as a reference for other cities in developing countries. 相似文献
997.
Li Ke Fan Guangsen Tian Huafeng Yuan Li Yao Yuanyuan Xiang Aimin Luo Xiaogang 《Journal of Polymers and the Environment》2021,29(10):3263-3270
Journal of Polymers and the Environment - With the advantages of excellent processability and biodegradability, polyvinyl alcohol (PVA) becomes an environmentally friendly and biocompatible... 相似文献
998.
Liang Fei Wen Yongkang Dong Xiao Wang Yiyao Pan Guangyuan Jiang Fangying Luo Huaying Jin Wenjun Wang Jun Song He 《Environmental science and pollution research international》2021,28(23):29332-29343
Environmental Science and Pollution Research - Nitrite oxidation as the second step of nitrification can become the determining step in disturbed soil systems. As a beneficial fertilization... 相似文献
999.
1000.
Wuxing Liu Yongming Luo Ying Teng Zhengao Li Lena Q. Ma 《Environmental geochemistry and health》2010,32(1):23-29
In situ bioremediation of oily sludge-contaminated soil by biostimulation of indigenous microbes through adding manure was
conducted at the Shengli oilfield in northern China. After bioremediation for 360 days, total petroleum hydrocarbon (TPH)
content was reduced by 58.2% in the treated plots compared with only 15.6% in the control plot. Moreover, bioremediation significantly
improved the physicochemical properties of the soil in the treated plot. Soil microbial counts and community-level physiological
profiling were also examined. Manure addition increased TPH degraders and polycyclic aromatic hydrocarbon (PAH) degraders
in the contaminated soil by one to two orders of magnitude. The activity and biodiversity of soil microbial communities also
increased markedly in the treated plot compared with that of the control. Finally, biotoxicity was used to evaluate the soils
and a sharp increase in the EC50 of the soil after bioremediation was observed, indicating that bioremediation had reduced
the toxicity of the soil. 相似文献