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461.
A Fenton process that uses FeCl2 as the alternative catalyst was employed to deal with the biologically treated landfill leachate. Data obtained revealed that this Fenton process can provide an equivalent pollutant removal as the Fenton process that uses FeSO4 as catalyst. Central composite design (CCD) and response surface methodology (RSM) were applied to evaluate and optimize the four key factors, namely initial pH, Fe(II) dosage ([Fe2+]), H2O2/Fe(II) mole ratio ([H2O2]/[Fe2+] ratio) and reaction time, which affect the performance of the Fenton treatment. Chemical oxygen demand (COD) and color were selected as response variables. This approach provided statistically significant quadratic models, which were adequate to predict responses and to carry out optimization under the conditions studied. It was demonstrated that the interaction between initial pH and [H2O2]/[Fe2+] ratio has a significant effect on the COD removal, while the interaction between [H2O2]/[Fe2+] ratio and reaction time shows a large impact on color removal. The optimal conditions were found to be initial pH 5.9, [Fe2+] = 9.60 mmol/L, [H2O2]/[Fe2+] ratio = 2.38, reaction time = 5.52 h. Under this optimal scheme, the COD and color in the effluent were reduced to 159 mg/L and 25°, respectively, with an increase of BOD5/COD ratio from 0.05 to 0.21. 相似文献
462.
高性能纤维具有优异的理化性能,在个体防护领域有着广泛的应用。本文介绍了高性能纤维在软质防弹服领域的应用与发展,分析了其优点与缺点,并讨论了软质防弹服发展方向。 相似文献
463.
Wei Yang Fengjun Jin Chengjin Wang Chen Lv 《Frontiers of Environmental Science & Engineering》2012,6(4):559-568
The aim of this paper is to study the spatialtemporal differentiation of industrial eco-efficiency in China. Using methods based on the data envelopment analysis (DEA) model and exploratory spatial data analysis (ESDA) and data from 1985, 1995, 2005, and 2008 of 30 provinces in China, the spatial-temporal pattern changes in industrial eco-efficiency are discussed. The results show that: first, the patterns of industrial eco-efficiency are dominated by clustering of relatively low efficiency provinces; second, spatial relationships between the industrial eco-efficiencies of different provinces changed slightly throughout the period and the provinces persistently exhibit spatial concentration of relatively low industrial eco-efficiency; finally, there is an obvious trend in the polarization of industrial eco-efficiency, i.e., the higher level spatial units are concentrated in eastern China, and the lower level spatial units are mainly in western and central China. 相似文献
464.
Tetrahydrofuran (THF) is easy to volatilize and hard to biodegrade. Little is known about the influence and fate of tetrahydrofuran in the environment. The effects of THF were examined on dissolved oxygen, pH, culturable aerobic microbes (bacteria, actinomycetes, and fungi) and four selected enzymes (protease, phosphatase, amylase, and lipase) in wastewater. The wastewater containing some activated sludge was taken from the aeration basin in Sibao sewage plant in Hangzhou, China. THF at lower concentrations of enhanced aerobic respiration and higher concentrations decreased utilization of oxygen in wastewater. The short-term influence of THF on pH was not obvious, but the long-term effect was apparent. Inhibition of THF on culturable aerobic microbes rose with increasing THF concentrations but decreased with prolongation of incubation time. No effect of THF on the activity of protease, phosphatase, amylase, and lipase was found. Data indicate that lower concentrations of THF exert no marked influence on wastewater in an urban sewage plant. 相似文献
465.
Weijia Zhao Hongyun Niu Yongliang Yang Hongzhou Lv Jungang Lv Yaqi Cai 《环境科学学报(英文版)》2022,34(2):244-257
The construction of heterojunction photocatalysts for efficiently utilizing solar energy has attracted considerable attention to solve the energy crisis and reduce environmental pollution. In this study, we use the energy released from an easily-occurred exothermic chemical reaction to serve as the drive force to trigger the formation of Cd S and C3N4 nanocomposites which are successfully fabricated with cadmium nitrate and thiourea without addition of any solvents and prot... 相似文献
467.
Cytochrome P450 (CYP450) genes play an important role in catalyzing oxidative metabolism of toxicants. Recently, CYP1 subfamily were discovered and reported in fish, however, little is known regarding the CYP2 isoforms in fish. In the present study, the cDNA fragments of CYP 1B1 and 1C1 and CYP2Aa, 2Y3, and 2K of rare minnow were cloned and exhibited a high amino acid sequence identity compared with their zebrafish orthologs. Basal expression showed CYP1C1 and CYP 2Aa expression were observed in all eight tissues analyzed (liver, gill, intestine, kidney, spleen, brain, skin, and muscle). CYP 1A, and 1B1 expression was found in all tissues except for muscle and skin. However, CYP 2Y3 was expressed in liver, spleen, intestine and muscle whereas CYP 2 K in liver, kidney and intestine. 4 and 100 μg L−1 Benzo[a]pyrene (BaP) induced patterns showed that CYP 1A, 1B1 and 1C1 expression in liver, gill, and intestine was strongly up-regulated (p < 0.05). Furthermore, CYP 2Y3 was strongly induced in liver from BaP treatments (p < 0.05). The high induction on mRNA level of CYP1s and CYP 2Y3 by BaP could be associated with catalyzing detoxification and indicated that CYP2s may also be potential biomarker to screen AHR agonist. The high responsiveness of CYP1 and 2 genes suggested Chinese rare minnow is feasible to screen and assess pollution with AHR agonist. 相似文献
468.
A newly designed electric assisted micro-electrolysis filter(E-ME) was developed to investigate its degradation efficiency for coking wastewater and correlated characteristics. The performance of the E-ME system was compared with separate electrolysis(SE) and micro-electrolysis(ME) systems. The results showed a prominent synergistic effect on COD removal in E-ME systems. Gas chromatography/mass spectrometry(GC–MS) analysis confirmed that the applied electric field enhanced the degradation of phenolic compounds.Meanwhile, more biodegradable oxygen-bearing compounds were detected. SEM images of granular activated carbon(GAC) showed that inactivation and blocking were inhibited during the E-ME process. The effects of applied voltage and initial p H in E-ME systems were also studied. The best voltage value was 1 V, but synergistic effects existed even with lower applied voltage. E-ME systems exhibited some p H buffering capacity and attained the best efficiency in neutral media, which means that there is no need to adjust p H prior to or during the treatment process. Therefore, E-ME systems were confirmed as a promising technology for treatment of coking wastewater and other refractory wastewater. 相似文献
469.
470.
The levels and distribution of organochlorine pesticides (OCPs) in sediments from the Haihe River, China 总被引:23,自引:0,他引:23
The levels and distribution patterns of the selected organochlorine pesticides (OCPs=p,p'-DDT, o,p'-DDT, p,p'-DDE, p,p'-DDD, alpha-, beta-, gamma- and delta-HCH) in surficial sediments from the Haihe River and Dagu Drainage River of Tianjin were investigated by means of gas chromatography coupled with micro-electronic capture detector (GC-microECD). Concentrations of OCPs in the sediments from the Haihe River ranged from 1.88 to 18.76ng g(-1) (mean 7.33ng g(-1)) for sum HCH, 0.32-80.18ng g(-1) (mean 15.94ng g(-1)) for sum DDT. Compared with the Haihe River, the Dagu Drainage River was much more contaminated by HCHs and DDTs, wherein sum HCH ranged from 33.24 to 141.03ng g(-1) (mean 87.74ng g(-1)) and sum DDT ranged from 3.60 to 83.49ng g(-1) with a mean value of 35.52ng g(-1). The concentration distribution of sum DDT and sum HCH was different indicated their different contamination sources. Composition analyses indicated that a recent usage or discharge of HCH and DDT into the Dagu Drainage River. 相似文献