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561.
以原子荧光法测定水中砷为例,探讨了实验室盲样考核浓度预判及稀释方法.分析了3个砷盲样考核实例,归纳了“直接稀释法”“系列稀释法”“最大稀释法”3种方法,分别适用于盲样浓度范围窄、适中、宽3种情况,检测人员可根据考核机构给定的浓度范围合理选用. 相似文献
562.
Shu-Fen Cheng Chi-Ying Lai Sheng-Jie Lin Chin-Yuan Huang 《Environmental monitoring and assessment》2014,186(1):375-382
Air-drying and oven-drying are pretreatment processes often used before testing and analyzing various soil characteristics in the laboratory. This study selected three kinds of soil, including red soil, entisol, and alluvial soil, and examined the variation of the Cr(VI) content and Cr bond forms in these soils during air-drying and oven-drying. The results show that when the soil is air-dried in natural environment, the Cr(VI) content decreases with air-drying time. On day 10 of air-drying, the Cr(VI) content in these soils is 22.8~47.9 % of the initial value. When the soil is oven-dried, the Cr(VI) concentration decays faster; on day 8, the Cr(VI) is no longer detected in these soil samples. When the Cr(VI)-contaminated soil is treated by air-drying and oven-drying, the Cr bond form converts into a more stable form. After oven-drying, the Cr mainly exists in Fe–Mn oxide form, organic bond form, and residual form. The air-drying and oven-drying pretreatment processes of soil reduce the Cr(VI) content and stabilize the Cr bond form. If the laboratory analytic results are applied to risk analysis or remediation strategy planning for chromium-contaminated soil, the toxicity, bioavailability, and mobility of Cr in soil may be underrated. 相似文献
563.
Yu-Hsiang Cheng Ben-Tzung Shiu Meng-Hsien Lin Jhih-Wei Yan 《Environmental science and pollution research international》2013,20(3):1537-1545
Information on the relationship between black carbon (BC) and particle number levels in urban areas is limited. Therefore, investigating the relationship between BC and particle number levels in different particle size ranges at an urban area is worthwhile. This study used an aethalometer and scanning mobility particle sizer to measure the levels of BC and particle number simultaneously at an urban roadside in Taipei City. Measurement results show that hourly BC levels are 0.62–8.80 μg m?3 (mean?=?3.50 μg m?3) and hourly particle number levels are 4.21?×?103–4.64?×?104 particles cm?3 (mean?=?2.00?×?104 particles cm?3) in Taipei urban area. The BC and particle number levels peak during morning (7:00–9:00) and evening (16:00–18:00) rush hours on weekdays. Low BC and particle number levels exist in the early morning hours. Time variations in BC levels are the same as those of particle number levels in this study, clearly indicating that BC and particles are likely released from the same emission source. Additionally, BC levels in the urban area are more strongly associated with ultrafine particle levels than with total particle number levels, particularly in the size range of 56–180 nm. According to measurement results, most BC in aerosols in urban areas can be in the ultrafine size range. 相似文献
564.
CASS工艺脱氮影响因素分析 总被引:4,自引:0,他引:4
针对CASS工艺脱氮的效果不够理想、效率不高、出水不够稳定的现象,对脱氮的主要影响因素曝气时间、DO、温度、λ进行了生产性试验研究,分析结果表明,曝气时间3h,D02.5mg/L是本污水厂最合理的参数控制值,曝气时间3h时NH3-N和TN的平均去除率分别为89.7%和59.7%,D02.5mg/L时NH3-N和TN的平均去除率分别为94.5%和71.3%,脱氮效果良好;温度对脱氮的效果有很明显的影响,春季的脱氮效果明显好于冬季;脱氮效果随冲水比的增高而降低,但出水均达标说明CASS工艺有良好的抗冲击负荷的能力。 相似文献
565.
Yongnian Ni Lin Wang Serge Kokot 《Journal of environmental science and health. Part. B》2013,48(4):328-335
A novel differential pulse voltammetry method (DPV) was researched and developed for the simultaneous determination of Pendimethalin, Dinoseb and sodium 5-nitroguaiacolate (5NG) with the aid of chemometrics. The voltammograms of these three compounds overlapped significantly, and to facilitate the simultaneous determination of the three analytes, chemometrics methods were applied. These included classical least squares (CLS), principal component regression (PCR), partial least squares (PLS) and radial basis function-artificial neural networks (RBF-ANN). A separately prepared verification data set was used to confirm the calibrations, which were built from the original and first derivative data matrices of the voltammograms. On the basis relative prediction errors and recoveries of the analytes, the RBF-ANN and the DPLS (D – first derivative spectra) models performed best and are particularly recommended for application. The DPLS calibration model was applied satisfactorily for the prediction of the three analytes from market vegetables and lake water samples. 相似文献
566.
Ching-Ho Lin Chin-Hsing Lai Yee-Lin Wu Ming-Jen Chen 《Atmospheric environment (Oxford, England : 1994)》2010,44(35):4364-4371
Determining the destructions of both ozone and odd oxygen, Ox, in the nocturnal boundary layer (NBL) is important to evaluate the regional ozone budget and overnight ozone accumulation. This work develops a simple method to determine the dry deposition velocity of ozone and its destruction at a polluted nocturnal boundary layer. The destruction of Ox can also be determined simultaneously. The method is based on O3 and NO2 profiles and their surface measurements. Linkages between the dry deposition velocities of O3 and NO2 and between the dry deposition loss of Ox and its chemical loss are constructed and used. Field measurements are made at an agricultural site to demonstrate the application of the model. The model estimated nocturnal O3 dry deposition velocities from 0.13 to 0.19 cm s?1, very close to those previously obtained for similar land types. Additionally, dry deposition and chemical reactions account for 60 and 40% of the overall nocturnal ozone loss, respectively; ozone dry deposition accounts for 50% of the overall nocturnal loss of Ox, dry deposition of NO2 accounts for another 20%, and chemical reactions account for the remaining 30%. The proposed method enables the use of measurements made in typical ozone field studies to evaluate various nocturnal destructions of O3 and Ox in a polluted environment. 相似文献
567.
本文讨论了氧化塘的净化污水机理和水质变化特点。提出了用于进行氧化塘水质预测的二维水质模型。探讨了氧化塘水质预测研究的发展趋势。 相似文献
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