Towards zero discharge of chromium-containing leather waste through improved alkali hydrolysis

The treatment of chromium-containing leather waste (CCLW), the major solid waste generated at the post-tanning operations of leather processing, has the potential to generate value-added leather chemicals. Various alkali and enzymatic hydrolysis were compared, and calcium oxide was found to be important for effective (but still incomplete) hydrolysis. Three possible reasons are given for the incomplete hydrolysis under alkaline conditions. Data for 19 amino acids are presented for four different treatment products. On the basis of the results, a novel three-step CCLW treatment process is proposed. The gelatin extracted in the first step is chemically modified to produce leather finishing agents. The collagen hydrolysates isolated in the second step are used as proteinic retanning agents by chemical modification. The remaining chrome cake is further hydrolyzed with acids in the third step, and the obtained chromium-containing protein hydrolysates could be used for the preparation of chromium-containing retanning agents for leather industry. The proposed three-step process provides a feasible zero discharge process for the treatment of CCLW.     

The effect of five forage species on transport and transformation of atrazine and isoxaflutole (balance) in lysimeter leachate

A field lysimeter study with bare ground and five different ground covers was established to evaluate the effect of forage grasses on the fate and transport of two herbicides in leachate. The herbicides were atrazine (ATR; 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) and isoxaflutole [IXF; 5-cyclopropyl-4-(2-methylsulfonyl-4-trifluormethyl-benzoyl)isoxazole], which has the commercial name Balance (Aventis Crop Science, Strasbourg, France). The ground covers included orchardgrass (Dactylis glomerata L.), smooth bromegrass (Bromus inermis Leyss.), tall fescue (Festuca arundinacea Schreb.), timothy (Phleum pratense L.), and switchgrass (Panicum virgatum L.). The results suggested that the total IXF (parent + metabolites) showed higher mobility than ATR and its metabolites. Differences in the timing of transport reflected the rapid degradation of IXF to the more soluble, stable, and biologically active diketonitrile (DKN) metabolite in the system. Although grass treatments did not promote the hydrolysis of DKN, they significantly reduced its transport in the leachate through enhanced evapotranspiration. Grass treatments significantly enhanced ATR degradation in the leachates and soils, especially through N dealkylation, but they did not reduce total ATR transported in the leachate. Leachate from the orchardgrass lysimeters contained the highest proportion of ATR metabolites (64.2%). Timothy and smooth bromegrass treatments also displayed a significant increase in ATR metabolites in leachate. Grass-treated lysimeters showed higher microbial biomass carbon than bare ground. For ATR treatments, the proportion of metabolites in the leachate strongly correlated with the elevated soil microbial biomass carbon in forage treatments. In contrast, DKN degradation was poorly correlated with soil microbial biomass carbon, suggesting that DKN degradation is an abiotic process.     

Retention equations of nonionic organic chemicals in soil column chromatography with methanol-water eluents

Research efforts dealing with chemical transportation in soils are needed to prevent damage to ground water. Methanol-containing solvents can increase the translocation of nonionic organic chemicals (NOCs). In this study, a general log-linear retention equation, log k' = log k'w - Sphi (Eq. [1]), was developed to describe the mobilities of NOCs in soil column chromatography (SCC). The term phi denotes the volume fraction of methanol in eluent, k' is the capacity factor of a solute at a certain phi value, and log k'w and -S are the intercept and slope of the log k' vs. phi plot. Two reference soils (GSE 17204 and GSE 17205) were used as packing materials, and were eluted by isocratic methanol-water mixtures. A model of linear solvation energy relationships (LSER) was applied to analyze the k' from molecular interactions. The most important factor determining the transportation was found to be the solute hydrophobic partition in soils, and the second-most important factor was the solute hydrogen-bond basicity (hydrogen-bond accepting ability), while the less important factor was the solute dipolarity-polarizability. The solute hydrogen-bond acidity (hydrogen-bond donating ability) was statistically unimportant and deletable. From the LSER model, one could also obtain Eq. [1]. The experimental k' data of 121 NOCs can be accurately explained by Eq. [1]. The equation is promising to estimate the solute mobility in pure water by extrapolating from lower-capacity factors obtained in methanol-water mixed eluents.     

人工神经网络方法在资源与环境预测方面的应用

用人工神经网络方法对不同水域、不同环境因子之间非线性和不确定性的复杂关系进行学习训练并预测检验。结果表明：人工神经网络方法在模拟和预测方面 优于传统的统计回归模型,在资源与环境方面的应用是可行的。具有较强的模拟预测能力。与传统的回归模型相比,人工神经网络方法不要求监测数据具有很强的规律性,就可用后的网络模型对其进行预报,燕且预测相对误差均比回归模型预测相对误差要小,具有一定的实用性。两个实例的应用     

对铁碳处理硝基酚废水的研究

铁碳降解水中难降解有机污染物的影响因素、最佳工艺参数及处理效果;初步探讨了氧化降解污染物的作用机理;通过分析污染物降解的中间产物,提出了污染物降解的可能途径.探讨了pH、铁碳用量、温度以及锰矿物的粒径等对处理效果的影响,在最佳的工艺条件下,CODCr的去除率达到95%以上,TOC测定表明：大部分硝基酚被氧化降解为H2O和CO2.对硝基酚的降解途径主要是微电解将对硝基酚还原为对氨基酚,对氨基酚在酸性条件下被软锰矿氧化为H2O和CO2做探索性研究.     

金沙江水电资源梯级开发及其经济发展研究

金沙江流域是我国13大水电基地中水能资源蕴涵量最大的地区，但开发率相对较低。在介绍金沙江流域丰富的水电资源及其开发现状的基础上，分析了加快金沙江水电开发的可能条件和重要意义；针对开发中存在的主要问题，根据市场经济原则和具体情况提出了对策和建议。     

湖北省区域可持续发展能力综合评价

从区域可持续发展的观点出发，根据湖北省具体区域特征，通过构建湖北省区域可持续发展指标体系和评估方法，得出湖北省12个地市人口、资源、环境、经济和社会5个系统的可持续发展指数以及区域综合可持续发展指数。从总体上看，湖北省区域可持续发展水平处于偏低水平，其中武汉市是唯一具有强可持续发展能力的城市，但优势地位不明显；其它城市可持续发展5个系统均存在发展不平衡状况，且城市特色不突出。     

巢湖流域蒸发量特征及变化趋势研究

巢湖作为安徽省境内的一个重要湖泊，对安徽省生态环境起到一定的影响作用。蒸发量是影响生态环境的重要因子，在很多方面是该区生态环境的一个反映。采用了统计学方法，对巢湖流域15个蒸发点20年（1981-2000年）的资料进行了分析，初步探讨了巢湖流域的蒸发量空间分布特征与地势、气温、风速、降水量等因子的关系，以及蒸发量在1年内的变化特征和年际变化趋势，试图说明研究时段内人类活动对区域蒸发量的影响。研究表明，由于地形等因素的影响，巢湖流域的蒸发量空间分布不均衡，在研究时段内蒸发量大体呈上升趋势。     

提高节理面c和φ对岩坡开挖变形的影响

为了反映岩质边坡在节理面注浆后的变形效应,首先,通过室内试验,分析注浆前后岩体变形和破坏的全过程,以探讨其抗剪性能(粘结力c和内摩擦角φ)的变化;然后,基于理想弹塑性本构模型的Mohr-Cou-lomb准则,运用拉格朗日元数值方法(FLAC3D),对岩坡注浆前后变形效应(水平位移、垂直位移、剪应变增量)进行模拟。结果表明:注浆加固后,岩体的位移场变得均匀和连续,节理面处的较大位移受到抑制,边坡的整体性得到提高,有利于边坡的稳定性。     

减灾事业的发展和综合减灾

中国减灾事业的发展史可分3个阶段:第一阶段是新中国成立以前的几千年,减灾活动以赈灾为主,帝王“祭天求恕”,“防灾吏制”,安抚于民。清末民初1800至1949年间计发生巨灾25起,死亡4993万余人,总灾亡则近亿,年均灾亡60万人以上,这段惨痛的灾况记下了十分难得的灾情史,泣血于残野。新中国成立后,在“为人民服务”的思想指导下,为减轻灾害损失,逐步建立了气象、水利、农林、地震、海洋、地质等专业的灾害科技与减灾工程,政府并组织社会兼事抗灾、救灾、应急减灾,国家减灾实力快速增长,已取得突出减灾实效,这个阶段比第一阶段灾亡人数下降了90%以上,但年均灾亡人口仍有1.2万人左右。该阶段的工作特点是以单灾种纵向体系为主,不同灾类的监测、预报水平尚高低不一,这与成灾机理的难易程度和工作条件的强弱有关。21世纪初,随全球增温之势锐升,多类极端灾变遍及各洲,促使许多国家发动全社会人众共同探求“综合减灾”之路;我国政府已迅即开展全社会应急减灾行动,开启了“综合减灾”之先声,这是减灾事业步入第三阶段的先导。综合减灾应该是全社会相关部门和民众的统一行动。目前尚有3个问题需要弄清楚,一是多种自然灾害之间成灾机理相关性的研究,其对象是灾害群与灾害链;二是全社会减灾要素综合运作预案的优选;三是如何核算减灾投入与社会可持续发展之正、负效应关系。